Impact of agriculture on surface water in Ireland Part II. Prospects for the future

Agricultural activity is estimated to be responsible for only 6% (8 km) of the total length (135 km) of seriously polluted river channel, but for over 30% (294 km) of the slightly or moderately polluted length (963 km) of channel recorded to date in the state. This article examines the present sources and causes of pollution from agricultural wastes, and speculates on the likely direction of future trends. The most common sources of surface water pollution are animal manures, silage effluent, runoff from land following spreading, and fertilizers.     

Some rock magnetic properties of mid-Cretaceous basalts from Israel and India (Rajmahal traps), and their bearing on palaeointensity experiments

A wide range of rock magnetic properties have been determined from two collections of mid-Cretaceous basalts; one from Israel, the other from the Rajmahal traps in northeast India. Deuteric oxidation is rare in both collections, with titanium-rich titanomagnetite being the principal remanence carrier in most cases. There are a number of differences in rock magnetic properties between the two groups. Some of these seem to be primary, whereas others appear to be caused by hydrothermal alteration and weathering, which are more prevalent in the Indian rocks. These rocks are being used in palaeointensity experiments, from which it is hoped to determine the strength of the Earth's magnetic field during the long period of normal polarity in the mid-Cretaceous. Thellier palaeointensity experiments have been performed on two samples from each site. The degree of agreement between the two results is highly variable. The low blocking temperatures and the presence of secondary viscous components in many samples make Thellier palaeointensity experiments very difficult. A further problem is that of thermal alteration, two main types of which are observed. The first manifests itself as a large and sudden increase in partial thermoremanent magnetization (pTRM) capacity, and the second as a steady decrease in the size of pTRM with increasing temperature.     

Mid-level clouds over the Sahara in a convection-permitting regional model

Climate Dynamics - The simulation of Saharan mid tropospheric clouds is investigated with the weather research and forecasting (WRF) regional atmospheric model at convection permitting...     

The yield and isotopic composition of radiolytic H2, a potential energy source for the deep subsurface biosphere

The production rate and isotopic composition of H₂ derived from radiolytic reactions in H₂O were measured to assess the importance of radiolytic H₂ in subsurface environments and to determine whether its isotopic signature can be used as a diagnostic tool. Saline and pure, aerobic and anaerobic water samples with pH values of 4, 7, and 10 were irradiated in sealed vials at room temperature with an artificial γ source, and the H₂ abundance in the headspace and its isotopic composition were measured. The H₂ concentrations were observed to increase linearly with dosage at a rate of 0.40 ± 0.04 molecules (100 eV)⁻¹ within the dosage range of 900 to 3500 Gray (Gy; Gy = 1 J Kg⁻¹) with no indication of a maximum limit on H₂ concentration. At ∼2000 Gy, the H₂ concentration varied only by 16% across the experimental range of pH, salinity, and O₂. Based upon this measured yield and H₂ yields for α and β particles, a radiolytic H₂ production rate of 10⁻⁹ to 10⁻⁴ nM s⁻¹ was estimated for the range of radioactive element concentrations and porosities typical of crustal rocks. The δD of H₂ was independent of the dosage, pH (except for pH 4), salinity, and O₂ and yielded an αD_H2O-H2 of 2.05 ± 0.07 (αD_H2O-H2 = (D/H)_H2O to (D/H)_H2), slightly less than predicted radiolytic models. Although this radiolytic fractionation value is significantly heavier than that of equilibrium isotopic exchange between H₂ and H₂O, the isotopic exchange rate between H₂ and H₂O will erase the heavy δD of radiolytic H₂ if the age of the groundwater is greater than ∼10³ to 10⁴ yr. The millimolar concentrations of H₂ observed in the groundwater of several Precambrian Shields are consistent with radiolysis of water that has resided in the subsurface for a few million years. These concentrations are well above those required to support H₂-utilizing microorganisms and to inhibit H₂-producing, fermentative microorganisms.     

Long-range aircraft as an Arctic Oceanographic platform

Synoptic basin-wide measurements of Arctic Ocean temperature and salinity are now possible with the recent development of an expendable conductivity, temperature, and depth probe for deployment from aircraft (AXCTD). Both the P-3 Orion aircraft and the C-130 aircraft are capable of long-range, low-altitude flight and are ideal for Arctic research. Expendable profilers can be quickly deployed over vast regions from aircraft and in locations with limited ship access, but have the disadvantage of measuring only the top 1000 m and of being about an order of magnitude less accurate than a CTD cast, primarily because of noisy salinity measurements and depth-fall rate errors. We explore how to conduct an ACXTD measurement program in ice-covered seas and discuss a test of these methods conducted in the Arctic Ocean's Eurasian Basin. Long-range aircraft can significantly augment the present program of Arctic research by performing large-area surveys, continuing time series with repeat measurements, and by helping target locations for more detailed and accurate shipboard measurement.