Reversibility of radiocaesium sorption on illite

Adsorption of trace amounts of radiocaesium on NH₄-, K-, and Na-saturated Fithian illite and subsequent desorption by 1 M NH₄ showed that a substantial amount of radiocaesium (44%, 46%, and 91% for NH₄-, K-, and Na-illite, respectively) cannot be desorbed after only 5 min of adsorption. Our results suggest that this instantaneous fixation is caused by the collapse of the frayed edges of the clay mineral and the relatively high concentration of radiocaesium building up in solution in the batch desorption experiments. Consequently, commonly applied high-NH₄ extractions underestimate truly exchangeable amounts of radiocaesium in soils and sediments containing illitic clay minerals. The rate of desorption of trace amounts of radiocaesium from the solids using high NH₄ or Cs concentrations has a half-life of about 2 yr, reflecting radiocaesium desorption from (partially) collapsed interlayers. Extraction of radiocaesium from illite after 5 min of contact time with a Cs-selective adsorbent or a 1 × 10^-6 M CsCl solution shows that 100% of the bound radiocaesium is readily available. The desorption rate in the presence of a Cs-selective adsorbent has a half-life of about 0.2 yr. Desorption of radiocaesium from illite using different ammonium concentrations shows that radiocaesium partitioning follows reversible ion-exchange theory if the NH₄ concentration is below 1 × 10^-4 M, and sufficient time (weeks) is allowed for the reaction to proceed. Thus, radiocaesium sorption reversibility in the natural environment is much higher than generally assumed, and equilibrium solid/liquid partitioning may be assumed for the long-term modelling of radiocaesium mobility in the natural environment. In the particular case of anoxic freshwater sediments with very high NH₄ concentrations in the pore waters (up to several mmol.L^-1), collapse of the frayed edges of illite may occur, influencing radiocaesium partitioning. If collapse occurs before radiocaesium adsorbs to illite, high caesium sorption reversibility as measured by high-NH₄ extraction can be expected because further collapse of the frayed edges during the extraction procedure will be limited. This effect has indeed been observed earlier in the extraction of radiocaesium from anoxic freshwater sediments with high-NH₄ solutions and was as yet unexplained.     

Ecological quality assessment of small estuaries from the Portuguese coast based on fish assemblages indices

The importance of establishing the ecological quality of estuarine systems has been widely acknowledged and led to the development of several fish community-based multimetric indices. Nevertheless, a question rose about the accuracy of these tools when natural disturbance is acting upon the organization of the systems’ communities. Four multimetric indices were used to examine their ability to differentiate the ecological status of five small estuarine systems (southern Portugal), and also to test if they reflected the level of anthropogenic pressures. Fish assemblages from Mira, Odeceixe and Aljezur (in the Southwest coast), Gilão and Bensafrim (in the South coast) estuaries were sampled seasonally for one year, and anthropogenic sources of pressure were identified and quantified. We found that although the applied indices provided information on ecological condition differentiation among systems, they are unable to explain different classes of ecological status in systems with equivalent pressure levels.     

Granite ages within the Archaean Pilbara Block,Western Australia

Within the Pilbara Block of Western Australia, a complex of migmatite, gneissic and foliated granite near Marble Bar is intruded by a stock of younger massive granite (the Moolyella Granite) with which swarms of tin‐bearing pegmatites are associated. The age of the older granite has been determined by the Rb‐Sr method as 3,125 ± 366 m.y., and that of the Moolyella Granite as 2,670 ± 95 m.y. Initial Sr⁸⁷/Sr⁸⁶ ratios suggest that the older granite is close to primary crustal material, but that the Moolyella Granite consists of reworked material. It probably formed by partial remelting of the older granite.     

GIS-based determination of the mean long-term groundwater recharge in Lower Saxony

This paper presents the findings of a collaborative research project of the Geological Survey of Lower Saxony (NLfB) and the Programme Group Systems Analysis and Technology Evaluation (STE) of Research Centre Jülich on the GIS-based determination of the mean long-term groundwater recharge in Lower Saxony using high-resolution digital data (Dörhöfer and others 2001). The model calculations were performed on the basis of the water-balance model GROWA (Kunkel and Wendland 2002) with a spatial resolution of 100x100 m². The accuracy of the calculated groundwater recharge values for the period 1961–1990 was verified on the basis of data from gauging stations and displayed a good agreement between observed runoff values and model results.     

Surface and deep water response to rapid climate changes at the Western Iberian Margin

Rapid climate changes at the onset of the last deglaciation and during Heinrich Event H4 were studied in detail at IMAGES cores MD95-2039 and MD95-2040 from the Western Iberian margin. A major reorganisation of surface water hydrography, benthic foraminiferal community structure, and deepwater isotopic composition commenced already 540 years before the Last Isotopic Maximum (LIM) at 17.43 cal. ka and within 670 years affected all environments. Changes were initiated by meltwater spill in the Nordic Seas and northern North Atlantic that commenced 100 years before concomitant changes were felt off western Iberia. Benthic foraminiferal associations record the drawdown of deepwater oxygenation during meltwater and subsequent Heinrich Events H1 and H4 with a bloom of dysoxic species. At a water depth of 3380 m, benthic oxygen isotopes depict the influence of brines from sea ice formation during ice-rafting pulses and meltwater spill. The brines conceivably were a source of ventilation and provided oxygen to the deeper water masses. Some if not most of the lower deep water came from the South Atlantic. Benthic foraminiferal assemblages display a multi-centennial, approximately 300-year periodicity of oxygen supply at 2470-m water depth. This pattern suggests a probable influence of atmospheric oscillations on the thermohaline convection with frequencies similar to Holocene climate variations. For Heinrich Events H1 and H4, response times of surface water properties off western Iberia to meltwater injection to the Nordic Seas were extremely short, in the range of a few decades only. The ensuing reduction of deepwater ventilation commenced within 500–600 years after the first onset of meltwater spill. These fast temporal responses lend credence to numerical simulations that indicate ocean–climate responses on similar and even faster time scales.     

Movement and Home Ranges of Dugongs Around the Lease Islands, East Indonesia

Abstract. Four individual dugongs Dugong dugong , MÜLLER, 1776 were tracked with buoyant, tethered. conventional and satellite radio transmitters. The dugongs three adult females and one immature male were encircled with a net at a catch site near Haruku Island, East Indonesia, and tracked for between 41 and 285 days. The animals showed individualistic patterns of movement, moving between 2 and 3 core areas, travelling between 17 and 65 km from the site of capture. One adult female spent most of the time at two distinct inshore seagrass beds separated by about 17 km; she made five trips between the two sites. Two other females made separate trips to two distinct sites, one of them returning to the catch site at Haruku Island. The immature male journeyed between two areas about 65 km apart. completing the journey in four days. The patterns of movement confirmed a practice of regular recropping of restricted grazing swards by small, loose feeding assemblages rather than fixed herds with a strong social bond. Mean home ranges covered 4.1 km² 50% harmonic mean and 43.4 km² 95% harmonic mean.     

Dynamical Properties of a Sample of Ellipticals

On the basis of Jeans equations we study some dynamical properties of a sample of E galaxies considered as oblate and prolate spheroids. Although the results emphasize the anisotropy as the dominant dynamical factor both for oblate and prolate configurations, the sample contains some oblate galaxies apparently isotropic consistent with full rotational support. Comparisons of the mass-to-luminosity ratios obtained from our models with ratios derived from recent evolutionary synthesis models do not seem to leave room for nonluminous matter within the ranges (of the order of one de Vaucouleurs' radius) of the kinematical observations. Such comparisons suggest that a flatter than the classical Salpeter IMF would lead to better agreement with the dynamical results obtained within the framework of our models.     

Variability over time in the sources of South Portuguese Zone turbidites: evidence of denudation of different crustal blocks during the assembly of Pangaea

This study combines geochemical and geochronological data in order to decipher the provenance of Carboniferous turbidites from the South Portuguese Zone (SW Iberia). Major and trace elements of 25 samples of graywackes and mudstones from the Mértola (Visean), Mira (Serpukhovian), and Brejeira (Moscovian) Formations were analyzed, and 363 U-Pb ages were obtained on detrital zircons from five samples of graywackes from the Mira and Brejeira Formations using LA-ICPMS. The results indicate that turbiditic sedimentation during the Carboniferous was marked by variability in the sources, involving the denudation of different crustal blocks and a break in synorogenic volcanism. The Visean is characterized by the accumulation of immature turbidites (Mértola Formation and the base of the Mira Formation) inherited from a terrane with intermediate to mafic source rocks. These source rocks were probably formed in relation to Devonian magmatic arcs poorly influenced by sedimentary recycling, as indicated by the almost total absence of pre-Devonian zircons typical of the Gondwana and/or Laurussia basements. The presence of Carboniferous grains in Visean turbidites indicates that volcanism was active at this time. Later, Serpukhovian to Moscovian turbiditic sedimentation (Mira and Brejeira Formations) included sedimentary detritus derived from felsic mature source rocks situated far from active magmatism. The abundance of Precambrian and Paleozoic zircons reveals strong recycling of the Gondwana and/or Laurussia basements. A peri-Gondwanan provenance is indicated by zircon populations with Neoproterozoic (Cadomian-Avalonian and Pan-African zircon-forming events), Paleoproterozoic, and Archean ages. The presence of late Ordovician and Silurian detrital zircons in Brejeira turbidites, which have no correspondence in the Gondwana basement of SW Iberia, indicates Laurussia as their most probable source.     

A Burst with Double Radio Spectrum Observed up to 212 GHz

We study a solar flare that occurred on 10 September 2002, in active region NOAA 10105, starting around 14:52 UT and lasting approximately 5 minutes in the radio range. The event was classified as M2.9 in X-rays and 1N in Hα. Solar Submillimeter Telescope observations, in addition to microwave data, give a good spectral coverage between 1.415 and 212 GHz. We combine these data with ultraviolet images, hard and soft X-ray observations, and full-disk magnetograms. Images obtained from Ramaty High Energy Solar Spectroscopic Imager data are used to identify the locations of X-ray sources at different energies, and to determine the X-ray spectrum, while ultraviolet images allow us to characterize the coronal flaring region. The magnetic field evolution of the active region is analyzed using Michelson Doppler Imager magnetograms. The burst is detected at all available radio frequencies. X-ray images (between 12 keV and 300 keV) reveal two compact sources. In the 212 GHz data, which are used to estimate the radio-source position, a single compact source is seen, displaced by 25″ from one of the hard X-ray footpoints. We model the radio spectra using two homogeneous sources, and we combine this analysis with that of hard X-rays to understand the dynamics of the accelerated particles. Relativistic particles, observed at radio wavelengths above 50 GHz, have an electron index evolving with the typical soft–hard–soft behavior.     

The impact of dust on the scaling properties of galaxy clusters

We investigate the effect of dust on the scaling properties of galaxy clusters based on hydrodynamic N -body simulations of structure formation. We have simulated five dust models plus radiative cooling and adiabatic models using the same initial conditions for all runs. The numerical implementation of dust was based on the analytical computations of Montier & Giard. We set up dust simulations to cover different combinations of dust parameters that make evident the effects of size and abundance of dust grains. Comparing our radiative plus dust cooling runs with a purely radiative cooling simulation, we find that dust has an impact on cluster scaling relations. It mainly affects the normalization of the scalings (and their evolution), whereas it introduces no significant differences in their slopes. The strength of the effect critically depends on the dust abundance and grain size parameters as well as on the cluster scaling. Indeed, cooling due to dust is effective in the cluster regime and has a stronger effect on the 'baryon driven' statistical properties of clusters such as   L _X– M , Y – M , S – M   scaling relations. Major differences, relative to the radiative cooling model, are as high as 25 per cent for the   L _X– M   normalization, and about 10 per cent for the Y – M and S – M normalizations at redshift zero. On the other hand, we find that dust has almost no impact on the 'dark matter driven'   T _mw– M   scaling relation. The effects are found to be dependent in equal parts on both dust abundances and grain size distributions for the scalings investigated in this paper. Higher dust abundances and smaller grain sizes cause larger departures from the radiative cooling (i.e. with no dust) model.