Growing season expansion and related changes in monthly temperature and growing degree days in the Inter-Montane Desert of the San Luis Valley, Colorado

Most climate change studies on high elevation ecosystems identify changes in biota, while several report abiotic factors. However, very few report expansion of the freeze-free period, or discuss monthly changes of temperature and growing degree days (GDD) during the growing season. This study provides initial data on agriculturally-related aspects of climate change during the growing season (M-J-J-A-S) in the inter-montane desert of the San Luis Valley (SLV), Colorado. Temperature data were gathered from 7 climate stations within the SLV. Based on ordinal days, the last vernal freeze is occurring (p?<?0.05) earlier at 3 stations than in prior years, ranging between 5.52 and 11.86?days during 1981–2007. Significantly-later autumnal freezes are occurring at 5 stations by 5.95–18.10?days, while expansion of the freeze-free period was significantly longer at all stations by 7.20–24.21?days. The freeze-free period averaged about 93?days prior to the 1980s, but now averages about 107?days. Increases (p?<?0.05) in daily mean, maximum, minimum temperature occurred at nearly all stations for each month. Increases in GDD₁₀, GDD_4.4 (potato) and GDD_5.5 (alfalfa) also occurred at nearly all stations for all months during 1994–2007. Higher temperatures increase the number of GDD, quickening crop growth and maturity, and potentially reducing yield and quality unless varieties are adapted to changes and water is available for the season extension and increased evapotranspiration.     

Assessment of pollution risk ascribed to Santa Margarida Military Camp activities (Portugal)

Santa Margarida Military Camp (S.M.M.C.) is the only one Portuguese military training area, including firing ranges for tactical military manoeuvres of mechanised divisions. For this reason, various negative effects on the environment were expected due to the military activities, as the Military Camp’s area is classified as a high vulnerability area to pollution of its multilayer porous aquifers. The aim of this study was to identify and characterise local/regional geochemical impacts caused by the continuing military training activities performed at S.M.M.C. in the course of 52 years. An overview of the geochemical research issues as a basis for risk assessment is presented. A special attention has been put on the quality of local and regional surface waters, shallow groundwaters and groundwaters. Local soils and sediments as well as fragments of shells and bullets were sampled and analysed. The results so far obtained, indicated that none pollution effects were a consequence of the military training activities. Till now, the geochemical signatures such as, high levels of K, Cl and NO₃ in waters, detected in particular sites, should be faced as tracers of diffuse pollution ascribed to urban waste disposal and cattle breading.     

On the tectonic origin of Iberian topography

The present-day topography of the Iberian peninsula can be considered as the result of the Mesozoic–Cenozoic tectonic evolution of the Iberian plate (including rifting and basin formation during the Mesozoic and compression and mountain building processes at the borders and inner part of the plate, during the Tertiary, followed by Neogene rifting on the Mediterranean side) and surface processes acting during the Quaternary. The northern-central part of Iberia (corresponding to the geological units of the Duero Basin, the Iberian Chain, and the Central System) shows a mean elevation close to one thousand meters above sea level in average, some hundreds of meters higher than the southern half of the Iberian plate. This elevated area corresponds to (i) the top of sedimentation in Tertiary terrestrial endorheic sedimentary basins (Paleogene and Neogene) and (ii) planation surfaces developed on Paleozoic and Mesozoic rocks of the mountain chains surrounding the Tertiary sedimentary basins. Both types of surfaces can be found in continuity along the margins of some of the Tertiary basins. The Bouguer anomaly map of the Iberian peninsula indicates negative anomalies related to thickening of the continental crust. Correlations of elevation to crustal thickness and elevation to Bouguer anomalies indicate that the different landscape units within the Iberian plate can be ascribed to different patterns: (1) The negative Bouguer anomaly in the Iberian plate shows a rough correlation with elevation, the most important gravity anomalies being linked to the Iberian Chain. (2) Most part of the so-called Iberian Meseta is linked to intermediate-elevation areas with crustal thickening; this pattern can be applied to the two main intraplate mountain chains (Iberian Chain and Central System) (3) The main mountain chains (Pyrenees and Betics) show a direct correlation between crustal thickness and elevation, with higher elevation/crustal thickness ratio for the Central System vs. the Betics and the Pyrenees. Other features of the Iberian topography, namely the longitudinal profile of the main rivers in the Iberian peninsula and the distribution of present-day endorheic areas, are consistent with the Tertiary tectonic evolution and the change from an endorheic to an exorheic regime during the Late Neogene and the Quaternary. Some of the problems involving the timing and development of the Iberian Meseta can be analysed considering the youngest reference level, constituted by the shallow marine Upper Cretaceous limestones, that indicates strong differences induced by (i) the overall Tertiary and recent compression in the Iberian plate, responsible for differences in elevation of the reference level of more than 6 km between the mountain chains and the endorheic basins and (ii) the effect of Neogene extension in the Mediterranean margin, responsible for lowering several thousands of meters toward the East and uplift of rift shoulders. A part of the recent uplift within the Iberian plate can be attributed of isostatic uplift in zones of crustal thickening.     

Inorganic synthesis of Fe–Ca–Mg carbonates at low temperature

A set of free-drift experiments was undertaken to synthesize carbonates of mixed cation content (Fe, Ca, Mg) from solution at 25 and 70 °C to better understand the relationship between the mineralogy and composition of these phases and the solutions from which they precipitate. Metastable solid solutions formed at 25 °C which are not predicted from the extrapolation of higher temperature equilibrium assemblages; instead, solids formed that were intermediary in chemical composition to known magnesite–siderite and dolomite solid solutions. A calcite–siderite solid solution precipitated at 25 °C, with the percentage of CaCO₃ in the solid being proportional to the aqueous Ca/Fe ratio of the solution, while Mg was excluded from the crystal structure except at relatively high aqueous Mg/Ca and Mg/Fe ratios and a low Ca content. Alternatively, at 70 °C Mg was the predominant cation of the solid solutions. These results are compatible with the hypothesis that the relative dehydration energies of Fe, Ca and Mg play an important role in the formation of mixed cation carbonates in nature.     

X-ray Computed Tomography study of the influence of consolidants on the hydric properties of sandstones for stone conservation studies

X-ray Computed Tomography (X-ray CT) has been used to study the petrophysical characteristics of a Jurassic sandstone from Asturias (Northern Spain) used as building stone in several monuments in the region. CT monitoring of water capillarity tests has made it possible to visualize the movement of water inside the samples, to relate this movement with texture characteristics, and to measure the height reached in successive images, thereby determining the capillary penetration coefficient; based on this coefficient, the effective capillary pore radius has also been estimated. An advantage of the use of CT is that, as the information comes from the sample interior, border effects that can be generated in the external faces can be avoided.The CT was also used to visualize how a commercial organosilicon consolidant penetrates inside the rock by means of capillarity, a usual way of consolidant application in stone restoration processes. The coefficient of capillary penetration of the product, determined on the basis of the measurements made on the tomographic images, is 53% less than that of water. The influence of rock texture characteristics on the capillarity both of the consolidant and the water was also observed.The samples underwent CT water capillarity studies before and after the consolidant application, proving that the treatment improves the rock's hydric properties. The coefficient of capillary penetration decreased by 24% following the application of the consolidant, whereas the effective pore radius decreased by more than 40%.     

Sediment resuspension in two adjacent shallow coastal lakes: controlling factors and consequences on phosphate dynamics

A combination of field measurements, modelling and laboratory experiments was used to evaluate the potential impact of sediment resuspension on phosphorus (P) dynamics. The study was carried out in two adjacent shallow coastal lakes (Lake Honda and Lake Nueva) which, due to their geographic proximity (only 200 m apart), are subject to equal meteorological forcing and represent ideal systems to study how morphometry and sediment properties relate to wind events. The focusing factors (a measure of the fluxes of sediment into the water column through resuspension) estimated by comparing settling fluxes measured in surface sediment traps with those measured in bottom traps, were significantly larger (approximately 34% larger) in Lake Honda (LH; 1.18) than in Lake Nueva (LN; 0.88). Our model estimates of resuspension fluxes (E) were also ca. 40% larger in LH than in LN, in agreement with the observed focusing factors. The larger resuspension fluxes encountered in LH, in comparison with LN, can mainly be explained by differences in lake morphometry. Still, they could arise from differences in grain size distribution or in benthic algae concentration encountered in the lake sediments. By means of adsorption experiments in the laboratory, we show that resuspension events will have different effects on P-dynamics in LH and LN. While the resuspended material from LH tends to adsorb phosphate (PO₄ ³⁻), removing it from the water column, in LN the resuspended sediments tend to increase the availability of PO₄ ³⁻ in solution. These differences arise from (1) higher concentrations of PO₄ ³⁻ in water in LH compared to LN; and (2) larger PO₄ ³⁻adsorption capacity of the LH sediments as a result of the more abundant iron oxyhydroxides and clay.     

Paleomagnetic determination of emplacement temperatures of pyroclastic deposits: an under-utilized tool

Paleomagnetic data from lithic clasts collected from Mt. St. Helens, USA, Volcán Láscar, Chile, Volcán de Colima, Mexico and Vesuvius, Italy have been used to determine the emplacement temperature of pyroclastic deposits at these localities and to highlight the usefulness of the paleomagnetic method for determining emplacement temperatures. At Mt. St. Helens, the temperature of the deposits (T _dep ) at three sites from the June 12, 1980 eruption was found to be ≥532°C, ≥509°C, and 510–570°C, respectively. One site emplaced on July 22, 1980 was emplaced at ≥577°C. These new paleomagnetic temperatures are in good agreement with previously published direct temperature measurements and paleomagnetic estimates. Lithic clasts from pyroclastic deposits from the 1993 eruption of Láscar were fully remagnetized above the respective Curie temperatures, which yielded a minimum T _dep of 397°C. Samples were also collected from deposits thought to be pyroclastics from the 1913, 2004 and 2005 eruptions of Colima. At Colima, the sampled clasts were emplaced cold. This is consistent with the sampled clasts being from lahar deposits, which are common in the area, and illustrates the usefulness of the paleomagnetic method for distinguishing different types of deposit. T _dep of the lower section of the lithic rich pyroclastic flow (LRPF) from the 472 A.D. deposits of Vesuvius was ~280–340°C. This is in agreement with other, recently published paleomagnetic measurements. In contrast, the upper section of the LRPF was emplaced at higher temperatures, with T _dep ~520°C. This temperature difference is inferred to be the result of different sources of lithic clasts between the upper and lower sections, with the upper section containing a greater proportion of vent-derived material that was initially hot. Our studies of four historical pyroclastic deposits demonstrates the usefulness of paleomagnetism for emplacement temperature estimation.     

A high-resolution Holocene record on the Southern Brazilian shelf: Paleoenvironmental implications

A high-resolution, multi-proxy record has been used to determine the environmental changes during the Holocene on the southern Brazilian shelf. Present oceanographic conditions reveal wind and freshwater input as the determinants of short-term productivity changes in the study area. Magnetic susceptibility and grain-size variations, together with proxies of productivity (organic carbon, carbon accumulation rate, Ba, Sr, and Ca content, Ba/Al, Ba/Ti, and Al/Ti ratios) were analyzed and compared with proxies of redox condition (V/Ti ratio), terrigenous input (Fe/Ca and Ti/Ca ratios), as well as other Element/Ti ratios, to evaluate the paleoceanographic and paleoclimatic changes over the period.The core covers a time interval of about 7650 years, with sedimentation rates varying from 0.025 to 0.250 cm a⁻¹, which represent time intervals of between 8 and 80 a per sample. There is a clear change in the sedimentation rate at about 2800 B.P.All grain-size and elemental results indicate the occurrence of conspicuous changes between 5200 and 5000 cal. B.P., as well as between 3000 and 2800 cal. B.P. A comparison of the results with the palynological information available from the adjacent continental areas suggests that the sedimentary changes in this last interval may be correlated with the onset of modern climatic conditions in South America, and especially, with the onset of the Plata Plume Water, a water mass that carries cold, less saline waters towards the north. However, minor changes are observed at ca. 1500 B.P. and are correlated with an increase in the atmospheric humidity. Furthermore, a time-series analysis undertaken using several proxies indicated the occurrence of Sub-Milankovitch cycles, which may be compared with those reported worldwide.     

A hot film anemometer for the Martian atmosphere

A novel design of a wind sensor for the surface of Mars is described. This sensor is to be included in the Rover Environment Monitoring Station (REMS) to be launched as a part of the Mars Science Laboratory in 2009. A 2D hot film anemometer composed of four hot points and a reference point has been conceived and implemented in the preliminary design model. It uses a closed thermal feedback loop based on thermal sigma-delta modulation. In this paper, the first results obtained in a Mars-like environment are shown, and indicate that sensitivities are expected to be in the range of 0.5 m/s and 10° in wind speed and direction.     

Climate signal in varve thickness: Lake La Cruz (Spain), a case study

Lake La Cruz is a meromictic, karstic lake with annually laminated sediment formed by summer pulses of calcite deposition. The aim of this study was to explore the potential use of the laminated sediment from Lake La Cruz as a quantitative climate proxy, by calibrating lamina thickness against instrumental climate data. Statistical analysis of the relation between lamina thickness and the meteorological dataset indicated a high correlation between calcium carbonate lamina thickness and rainfall from December to March (r  = 0.725, P < 0.01, n = 35). Winter rainfall anomalies in the area are, in turn, highly negatively correlated with the North Atlantic Oscillation index (NAO, r = −0.832; P < 0.01; n = 53). We propose a regression model to infer past winter rainfall from calcium carbonate laminae thickness. These results highlight new possibilities for paleoenvironmental research using calcite laminated sediment records as climate proxies, especially to study past rainfall variability.