Do CRISTA Experiment/Campaign Data Represent a Typical Situation or Not?

Data from four A3 radio wave circuits in central Europe are used to analyse the representativeness of the ionization and gravity wave activity pattern in the lower ionosphere (85 – 100 km) in the CRISTA experiment interval (3 – 12 November 1994) for the given conditions. It has been found that the CRISTA experiment interval was run under conditions, which are highly representative both of October – November 1994 and autumn, low-moderate solar activity, the descending phase of solar cycle conditions, i.e. CRISTA measurements may be considered to provide values identical with, or close to climatological values (at least for central Europe, h = 85 – 100 km).     

Factors that contributed to recent eutrophication of two Slovenian mountain lakes

Increased eutrophication was recently observed in the 5th (5J) and 6th (6J) Triglav Lakes, two remote Slovenian mountain lakes. Sediment phosphorus (P) pools were analysed and potential external P sources affecting the lakes (atmospheric deposition, terrestrial export and nearby hut) evaluated, to assess the effects of internal and external changes on the lakes. A sequential extraction procedure was used to quantify five P fractions from the sediments: adsorbed (NH₄Cl–P), redox-sensitive (BD–P), aluminium- (NaOH–P) and calcium- (HCl–P) bound, and refractory organic (Res–P) P. Total phosphorus (TP) contents in surface sediment of 5J and 6J were 1430 and 641 µg P g^?1 dry weight sediment (dw), respectively. TP varied with depth in 5J sediments, but displayed no discernible pattern, whereas it decreased steadily downcore in 6J. Contents of all P forms were distinctly higher in 5J than 6J, but their rank order and relative abundances were similar in the two lakes. Res–P was the most abundant P fraction, followed by HCl–P. Together, the two P forms accounted for nearly 80 and 90% of TP in 5J and 6J sediments, respectively. BD–P and NaOH–P were less abundant, with each fraction accounting for 3 to 9% of TP, whereas NH₄Cl–P was least abundant. Atmospheric deposition and terrestrial export were substantial sources of P for the lakes. Delivery of the former was estimated to be at least 7.5 mg P m^?2 yr^?1 and the latter around 20 mg P m^?2 yr^?1. We concluded that P was not retained in the catchment effectively, likely because of only slightly acidic soil pH (5.9), relatively low aluminium content and high organic matter content (53%) in soils, resulting in higher vulnerability of the studied lakes to eutrophication. The mountain hut could also be a significant source of P for the lakes. Each year, it could potentially contribute ~12 kg of soluble P to the environment, but the true impact of the hut on lake trophic status remains unclear.     

Morphometric and geological conditions for sediment accumulation in the Udava River,Outer Carpathians,Slovakia

The accumulation of sediment in river channels is a phenomenon that is not only influenced by the channel morphology, but also by the physical and geographical characteristics and the endogenous and exogenous processes taking place in the catchment. This paper presents an analysis of the impact the changes in lithological conditions have on the morphological and morphometric parameters of the Udava River channel and their relation to the channel accumulation forms representative of the river’s longitudinal profile as well as of its planform. Results document when accumulation forms occur and what is their spatial distribution within the longitudinal and cross-sectional river profiles. More resistant structures created sections with a lower degree of sedimentation, while in depression segments the degree of sedimentation was higher. With the increase in longitudinal slope, the impact of channel width on the average channel bar size increased. Also a difference in the accumulation was observed between the left and right bank which could be possibly explained by the impact of Coriolis force.     

Ozone structure over the equatorial Andes from balloon-borne observations and zonal connection with two tropical sea level sites

In this paper we present first-time measurements of ozone profiles from a high altitude station in Quito, Ecuador (0.19°S, 78.4°W, and 2391 masl) taken from June 2014 to September 2015. We interpret ozone observations in the troposphere, tropopause, and stratosphere through a zonal comparison with data from stations in the Atlantic and Pacific (Natal and San Cristobal from the SHADOZ network). Tropospheric ozone concentrations above the Andes are lower than ozone over San Cristobal and Natal for similar time periods. Ozone variability and pollution layers are also reduced in the troposphere above the Andes. We explain these differences in terms of reduced contributions from the boundary layer and from horizontal transport. In the tropical tropopause layer, ozone is well-mixed up to near the cold point tropopause level. In this regard, our profiles do not show constraints to deep mixing above 14 km, as has been consistently observed at other tropical stations. Total column ozone and stratospheric column ozone are comparable among the three sites. However, the contribution of tropospheric column ozone to total column ozone is significantly lower above the Andes. Our comparisons provide a connection between observations from tropical stations in equatorial South America separated by the wide continental mass. Identified differences in ozone throughout the atmospheric column demonstrate the global benefit of having an ozone sounding station at the equatorial Andes in support of global monitoring networks.     

Trends in the characteristics of the annual and semiannual variations observed in the radio wave absorption in the lower ionosphere

The continuous increase in concentration of greenhouse gases in the atmosphere is expected to cool higher levels of the atmosphere. There is some direct and indirect experimental evidence of long-term trends in temperature and other parameters in the mesosphere and lower thermosphere (MLT). Here we look for long-term trends in the annual and semiannual variations of the radio wave absorption in the lower ionosphere, which corresponds to the MLT region heights. Data from central and southeastern Europe are used. A consistent tendency to a positive trend in the amplitude of the semiannual wave appears to be observed. The reality of a similar tendency in the amplitude of the annual wave is questionable in the sense that the trend in the amplitude of the annual wave is probably induced by the trend in the yearly average values of absorption. The phases of both the annual and semiannual waves display a forward tendency, i.e. shift to an earlier time in the year. A tentative interpretation of these results in terms of changes of the seasonal variation of temperature and wind at MLT heights does not contradict the trends observed in those parameters.     

The BanskáŠtiavnica ore district: relationship between metallogenetic processes and the geological evolution of a stratovolcano

The Banská?tiavnica ore district is in the central zone of the largest stratovolcano in the Central Slovakia Neogene Volcanic Field, which is situated at the inner side of the Carpathian arc over the Hercynian basement with the Late Paleozoic and Mesozoic sedimentary cover. Volcanic rocks of the High-K orogenic suite are of the Badenian through Pannonian age (16.5–8.5?Ma). Their petrogenesis is closely related to subduction of flysch belt oceanic basement underneath the advancing Carpathian arc and to back-arc extension processes. The stratovolcano includes a large caldera 20?km in diameter and a late-stage resurgent horst in its centre, exposing a basement and extensive subvolcanic intrusive complex. The following stages have been recognized in the evolution of the stratovolcano: (1)?formation of a large pyroxene/hornblende-pyroxene andesite stratovolcano; (2)?denudation, emplacement of a diorite intrusion; (3) emplacement of a large granodiorite bell-jar pluton within the basement; (4) emplacement of granodiorite/quartz-diorite porphyry stocks and dyke clusters around the pluton; (5) caldera subsidence and its filling by biotite-hornblende andesite volcanics, emplacement of quartz-diorite porphyry sills and dykes at the subvolcanic level; (6)?renewed activity of andesites from dispersed centres on slopes of the volcano; (7) uplift of a resurgent horst accompanied by rhyolite volcanics and granite porphyry dykes. The following types of ore deposits (mineralizations) have been identified in the Banská?tiavnica ore district: 1. Quartz-pyrophyllite-pyrite high-sulphidation system at ?obov, related to the diorite intrusion. 2. Magnetite skarn deposits and occurrences?at contacts of the granodiorite pluton with Mesozoic carbonate rocks. Magnetite ores occur as lenses in the calcic skarns. 3.?Stockwork/disseminated base metal deposit along an irregular network of fractures in apical parts of the granodiorite pluton and in remnants of basement rocks. Mineral paragenesis is simple, with leading sphalerite and galena and minor chalcopyrite and pyrite. In overlying andesites the mineralization is accompanied by metasomatic quartzites and argillites with pyrophyllite, kaolinite, illite and pyrite. 4. Porphyry/skarn copper deposits and occurrences related to granodiorite/quartz-diorite porphyry dyke clusters and stocks around the granodiorite intrusion. The mineralized zone is represented by accumulations of chalcopyrite in exo- and endo-skarns, usually of the magnesian type affected by serpentinization. Besides chalcopyrite, pyrhotite, minor bornite, chalcosite, tennantite and magnetite, rare molybdenite and gold are present. The alteration pattern around productive intrusions includes an external zone of propylitization, a zone of argillitic alteration (kaolinite – illite – pyrite) and an internal zone of phyllic alteration (quartz – sericite – pyrite). Biotitization is rare and limited to porphyry intrusions. 5. Intrusion related “mesothermal” gold deposit in an andesitic environment just above the granodiorite intrusion. Gold of high fineness with base metal mineralization is contained in brecciated and/or banded quartz veins of subhorizontal orientation, parallel to the surface of granodiorite pluton. At least the first phase of mineralization is older than quartz-diorite porphyry sills, which separate granodiorite and blocks of mineralized andesite. 6. Hot spring type advanced argillic systems in the caldera filling. Silicites and opalites accompanied by kaolinite, alunite and pyrite grade downward into smectite dominated argillites. 7. Vein type epithermal precious/base metal deposits and occurrences as a result of the long lasting interaction among structural evolution of the resurgent horst and evolving hydrothermal system, extensive intrusive complex and deep seated siliceous magma chamber serving as heat and magmatic fluid source. Three types of epithermal veins occur in a zonal arrangement: (a) base metal veins ± Au with transition to Cu?±?Bi mineralization at depth in the east/central part of the horst, (b)?Ag – Au veins with minor base metal mineralization and (c) Au – Ag veins located at marginal faults of the horst. Isotopic composition of oxygen and hydrogen in hydrothermal fluids indicate mixing of magmatic and meteoric component (with generally increasing proportion of meteoric component towards younger mineralization periods?). Veins are accompanied by zones of silicification, adularization and sericitization, indicating a low sulphidation environment. 8.?Replacement base metal mineralization of a limited extent in the Mesozoic carbonate rocks next to sulphide rich epithermal base metal veins.     

Geophysical evidence of the Eastern Marginal Fault of the Cheb Basin (Czech Republic)

The western part of the Bohemian Massif hosts an intersection of two regional fault zones, the SW-NE trending Oh?e/Eger Graben and the NNW-SSE trending Mariánské Lázně Fault, which has been reactivated several times in the geological history and controlled the formation of the Tertiary Cheb Basin. The broader area of the Cheb Basin is also related to permanent seismic activity of M_L 3+ earthquake swarms. The Eastern Marginal Fault of the Cheb Basin (northern segment of the Mariánské Lázně Fault) separates the basin sediments and underlying granites in the SW from the Kru?né Hory/Erzgebirge Mts. crystalline unit in the NE. We describe a detailed geophysical survey targeted to locating the Eastern Marginal Fault and determining its geometry in the depth. The survey was conducted at the Kopanina site near the Nový Kostel focal zone, which shows the strongest seismic activity of the whole Western Bohemia earthquake swarm region. Complex geophysical survey included gravimetry, electrical resistivity tomography, audiomagnetotellurics and seismic refraction. We found that the rocks within the Eastern Marginal Fault show low resistivity, low seismic velocity and density, which indicates their deep fracturing, weathering and higher water content. The dip of the fault in shallow depths is about 60° towards SW. At greater depths, the slope turns to subvertical with dip angle of about 80°. Results of geoelectrical methods show blocky fabric of the Cheb Basin and deep weathering of the granite bedrock, which is consistent with geologic models based on borehole surveys.     

Zinc-rich and copper-bearing amphiboles from sulfide-free ore occurrences of the Pelagonian Massif,Republic of North Macedonia

Mineralogy and Petrology - This paper describes specific features of isomorphism of unusual amphiboles containing up to 23 wt% ZnO and up to 1.3 wt% CuO from sulfide-free...     

Optimum size and density of surface grid arrays for retrieving accurate shear-tensile fracturing of microearthquakes

Surface arrays became an important tool for monitoring the induced seismicity in hydraulic fracturing experiments and for assessing the impact of fluid injection on the fracturing process of microearthquakes. The layout of sensors plays a key role in this task because it controls the accuracy of event locations and retrieved seismic moment tensors. We simulate various configurations of grid sensor arrays characterized by a different number of sensors, array span, sensor spacing, depth of sources and various shear/tensile source mechanisms of events. The moment tensor inversion is carried out using synthetically calculated P-wave amplitudes with added random noise. A bias in the solutions is evaluated by errors in the double-couple percentage of inverted moment tensors because the double-couple errors inform us about the sensitivity of the network to detect the shear/tensile fracturing mode of induced microearthquakes. The results show that the accuracy of the double-couple percentage is mostly controlled by the offset-to-depth ratio R defined as the ratio of half of the network size to the event depth. The optimum value of R is in the range of 0.75–1.5 irrespective of the type of the focal mechanism. If 121 (11 × 11) sensors are distributed in a regular grid and recorded data are characterized by a 10% random noise, the double-couple error is less than 6%. This error increases, if R is not optimum or if the number of sensors is reduced. However, even sparse arrays with 49 (7 × 7) or 16 (4 × 4) sensors can yield a reasonable accuracy, provided the surface grid arrays are designed to have an optimum size.