Charge distribution on the atmospheric aerosol over the North Atlantic and the Indian Ocean

The distribution of electric charge on the marine aerosol was determined near the sea surface of the Indian Ocean and the North Atlantic during the final stage of the Snellius II-expedition. Mean values for small ion concentrationsn ⁺=455 cm^–3 andn ^–=340 cm^–3 were found over the Atlantic, whilen ⁺=310 andn ^–=250 cm^–3 were the mean values over the Indian Ocean. The ration ⁺/n^– increased from 1.2 to 2.0 with decreasing wind velocity. At wind velocities below 5 m/s 75% of the net space charge near the ocean surface was found to be carried by small ions.     

Crustal complexity in the Lachlan Orogen revealed from teleseismic receiver functions

There is an ongoing debate about the tectonic evolution of southeast Australia, particularly about the causes and nature of its accretion to a much older Precambrian core to the west. Seismic imaging of the crust can provide useful clues to address this issue. Seismic tomography imaging is a powerful tool often employed to map elastic properties of the Earth's lithosphere, but in most cases does not constrain well the depth of discontinuities such as the Mohorovi?i? (Moho). In this study, an alternative imaging technique known as receiver function (RF) has been employed for seismic stations near Canberra in the Lachlan Orogen to investigate: (i) the shear-wave-velocity profile in the crust and uppermost mantle, (ii) variations in the Moho depth beneath the Lachlan Orogen, and (iii) the nature of the transition between the crust and mantle. A number of styles of RF analyses were conducted: H-K stacking to obtain the best compressional–shear velocity (V _P /V _S) ratio and crustal thickness; nonlinear inversion for the shear-wave-velocity structure and inversion of the observed variations in RFs with back-azimuth to investigate potential dipping of the crustal layers and anisotropy. The thick crust (up to 48 km) and the mostly intermediate nature of the crust?mantle transition in the Lachlan Orogen could be due to the presence of underplating at the base of the crust, and possibly to the existing thick piles of Ordovician mafic rocks present in the mid and lower crust. Results from numerical modelling of RFs at three seismic stations (CAN, CNB and YNG) suggest that the observed variations with back-azimuth could be related to a complex structure beneath these stations with the likelihood of both a dipping Moho and crustal anisotropy. Our analysis reveals crustal thickening to the west beneath CAN station which could be due to slab convergence. The crustal thickening may also be related to the broad Macquarie volcanic arc, which is rooted to the Moho. The crustal anisotropy may arise from a strong N–S structural trend in the eastern Lachlan Orogen and to the preferred crystallographic orientation of seismically anisotropic minerals in the lower and middle crust related to the paleo-Pacific plate convergence.     

A record of accelerated erosion in the recent sediments of Blelham Tarn in the English Lake district

Two frozen cores from Blelham Tarn were subsampled and measured using mineral magnetic, loss-on-ignition (LOI), radiometric, granulometric and diatom analyses. A detailed chronology was established using varves, radioisotopes and diatoms. This has enabled an accurately dated reconstruction of sedimentation over the past forty years. Despite a large increase in lake productivity, evidence suggests that the observed exponential increase in sedimentation rates can be attributed to erosion within the catchment. The predominant sediment source has been identified as surface soil. A comparison between the trend of accelerated sedimentation and the record of increased sheep stocking density for the area within which the most of the catchment lies, as well as observations of contemporary surface processes within the catchment, both suggest that much of the recent erosion is a direct response to increased pressure from sheep grazing.     

Incremental Growth of Plains-Type (Compactional) Folds in a Cratonic Environment as Revealed by the Sedimentary Sequence

The enigma of the origin and development of plains-type folds, as they were christened in the early 20th Century, essentially has been solved. The folds, a considerable distance from the tectonic disturbance, were formed by draping of sediments over differentially displaced Precambrian basement fault blocks. These Precambrian basement fault blocks controlled the location, size, and shape of the folds. Forces were transmitted through the rigid basement causing readjustment along the indigenous fracture/fault pattern formed much earlier. In the U.S. Midcontinent, the crystalline basement is overlain by a thin veneer of sediments, and once the structures were formed, they continued to develop as evidenced by features in the overlying sediments. As the stress was transmitted through the basement and then relaxed, the fault blocks moved differentially in concert to these outside forces. Sediment compaction and nondeposition over structural topographic highs reacted accordingly to form the features as seen today. To determine the structural history, structural closure on different horizons on the anticline is plotted in their appropriate stratigraphic position at depth. This gives a compaction line for each tectonically coherent segment. Similar segments show a relatively straightline with offsets at major unconformities indicating breaks in the continuum. It is at these breaks that the section can be stretched until the compaction line matches as a continuum with the resulting gap giving the approximate amount of missing section for that part of the rock column. Conversely, the amount of closure on a structure at depth for each line segment can be estimated by extrapolating downward in that segment. This technique to determine depth of burial and thus the amount of missing stratigraphic section from well data at numerous locations has been compared with estimates made by other methods and the results are similar. Where no other data are available or for quick estimates, then, it is proposed that this approach will give reasonable results and that the values can be used as a constraint in basin modeling.     

Ammonia-water ice laboratory studies relevant to outer Solar System surfaces

Although water- and ammonia-ices have been observed or postulated as important components of the icy surfaces of planetary satellites in the outer Solar System, significant gaps exist in our knowledge of the spectra and behavior of such mixtures under astrophysical conditions. To that end, we have completed low-temperature spectroscopic studies (1-20 μm) of water-ammonia mixtures, with an emphasis on features in the near-IR, a region which is accessible to ground-based observations. The influences of composition, formation temperature, thermal- and radiation-processing, and phase (crystalline or amorphous) of the components were examined. Spectra of both pure NH₃ and H₂O-NH₃ icy mixtures with ratios from 0.7 to 57 were measured at temperatures from 10 to 120 K. Conditions for the formation and thermal stability of the ammonia hemihydrate (2NH₃⋅H₂O) and the ammonia monohydrate (NH₃⋅H₂O) have been examined. Band positions of NH₃ in different H₂O-ices and major band positions of the hydrates were measured. We report spectral shifts that depend on concentration and temperature. The radiation-induced amorphization of the hemihydrate was observed and the radiation destruction of NH₃ in H₂O-ices was measured. Implications of these results for the formation, stability, and detection of ammonia on outer satellite surfaces are discussed.     

Lambert problem solution in the hill model of motion

The goal of this paper is obtaining a solution of the Lambert problem in the restricted three-body problem described by the Hill equations. This solution is based on the use of pre determinate reference orbits of different types giving the first guess and defining the sought-for transfer type. A mathematical procedure giving the Lambert problem solution is described. This procedure provides step-by-step transformation of the reference orbit to the sought-for transfer orbit. Numerical examples of the procedure application to the transfers in the Sun–Earth system are considered. These examples include transfer between two specified positions in a given time, a periodic orbit design, a halo orbit design, halo-to-halo transfers, LEO-to-halo transfer, analysis of a family of the halo-to-halo transfer orbits. The proposed method of the Lambert problem solution can be used for the two-point boundary value problem solution in any model of motion if a set of typical reference orbits can be found.     

A mapping of the electron localization function for the silica polymorphs: evidence for domains of electron pairs and sites of potential electrophilic attack

The electron localization function, η, evaluated for first-principles geometry optimized model structures generated for quartz and coesite, reveals that the oxide anions are coordinated by two hemispherically shaped η-isosurfaces located along each of the SiO bond vectors comprising the SiOSi angles. With one exception, they are also coordinated by larger banana-shaped isosurfaces oriented perpendicular to the plane centered in the vicinity of the apex of each angle. The hemispherical isosurfaces, ascribed to domains of localized bond-pair electrons, are centered ～0.70 Å along the bond vectors from the oxide anions and the banana-shaped isosurfaces, ascribed to domains of localized nonbonding lone-pair electrons, are centered ～0.60 Å from the apex of the angle. The oxide anion comprising the straight SiOSi angle in coesite is the one exception in that the banana-shaped isosurface is missing; however, it is coordinated by two hemispherically shaped isosurfaces that lie along the bond vectors. In the case of a first-principles model structure generated for stishovite, the oxide anion is coordinated by five hemispherically shaped η-isosurfaces, one located along each of the three SiO bond vectors (ascribed to domains of bonding-electron pairs) that are linked to the anion with the remaining two (ascribed to domains of nonbonding-electron pairs) located on opposite sides of the plane defined by three vectors, each isosurface at a distance of ～0.5 Å from the anion. The distribution of the five isosurfaces is in a one-to-one correspondence with the distribution of the maxima displayed by experimental Δρ and theoretical ??²ρ maps. Isosurface η maps calculated for quartz and the (HO) ₃ SiOSi(OH) ₃ molecule also exhibit maxima that correspond with the (3,?3) maxima displayed by distributions of ??²ρ. Deformation maps observed for the SiOSi bridges for the silica polymorphs and a number of silicates are similar to that calculated for the molecule but, for the majority, the maxima ascribed to lone-pair features are absent. The domains of localized nonbonding-electron pair coordinating the oxide anions of quartz and coesite provide a basis for explaining the flexibility and the wide range of the SiOSi angles exhibited by the silica polymorphs with four-coordinate Si. They also provide a basis for explaining why the SiO bond length in coesite decreases with increasing angle. As found in studies of the interactions of solute molecules with a solvent, a mapping of η-isosurfaces for geometry-optimized silicates is expected to become a powerful tool for deducing potential sites of electrophilic attack and reactivity for Earth materials. The positions of the features ascribed to the lone pairs in coesite correspond with the positions of the H atoms recently reported for an H-doped coesite crystal.     

Video cathodoluminescence microscopy of diagenetic cements and its applications

Diagenetic studies of sedimentary rocks using cold cathodoluminescence (CL) microscopy have been severely limited because of the very low intensity of visible luminescent emissions, which required long photographic exposure times, and because of the difficulty in obtaining quantitative data from CL observations. The solution to this problem is to fit the microscope with a high-sensitivity digital colour video camera linked to a computer with image enhancement and image analysis software. The new technique described in this paper:

• produces digital CL images of consistent high quality, both quickly and cheaply;

• controls the capture and editing of CL images, to reveal detailed textural information even from minerals exhibiting low level luminescence such as quartz;

• acquires quantitative information on pore systems and the abundance of cement zones from CL images.

Examples are presented to demonstrate the high quality of images produced in this way and the range of uses to which the new technique can be applied. The ability to image exactly the same field of view in both plane polarised light and CL is a particular advantage. Image analysis techniques have been developed to give a statistical characterisation of both pore systems and cement phases that infill them. The abundance of contrasting cement zones seen in CL can be measured and the abundance of cement phases can be mapped across a reservoir. The history of porosity occlusion can be reconstructed quantitatively and integrated with burial history and hydrocarbon migration. Porosity can be measured accurately and, since the technique obtains data on pore geometry as well as abundance, the pore system can be characterised by pore size distributions and pseudo-capillary pressure curves. This also opens the possibility of estimating permeability from thin sections.     

Temporal Variability of Total Ozone in the Asian Region Inferred from Ground-Based and Satellite Measurement Data

This paper reports investigation data on the temporal variability of total ozone content (TOC) in the Central Asian and Tibet Plateau mountain regions obtained by conventional methods, as well as by spectral, cross-wavelet, and composite analyses. The data of ground-based observation stations located at Huang He, Kunming, and Lake Issyk-Kul, along with the satellite data obtained at SBUV/SBUV2 (SBUV merged total and profile ozone data, Version 8.6) for 1980–2013 and OMI (Ozone Monitoring Instrument) and TOU (Total Ozone Unit) for 2009–2013 have been used. The average relative deviation from the SBUV/SBUV2 data is less than 1% in Kunming and Issyk-Kul for the period of 1980–2013, while the Huang He Station is characterized by an excess of the satellite data over the ground-based information at an average deviation of 2%. According to the Fourier analysis results, the distribution of amplitudes and the periods of TOC oscillations within a range of over 14 months is similar for all series analyzed. Meanwhile, according to the cross-wavelet and composite analyses results, the phase relationships between the series may considerably differ, especially in the periods of 5–7 years. The phase of quasi-decennial oscillations in the Kunming Station is close to the 11-year oscillations of the solar cycle, while in the Huang He and Issyk-Kul stations the TOC variations go ahead of the solar cycle.