Rotating Stratified Heterogeneous Oblate Spheroid in Newtonian Physics

By solving the Euler hydrodynamical equations we have obtained closed form solutions for the angular velocities and pressures of a three stratified non-confocal heterogeneous oblate spheroid. Limiting and particular solutions cases, such as a spheroid with N layers, a stratified spheroid with the same eccentricities, as well as confocal layered spheroids are also explicitly written down. As an application, we have numerically estimated planet Earth's outer and inner cores' ellipticities to be _o=1/413.318 and _i=1/424.616, respectively. These Earth's ellipticities values are in good agreement with those found in the literature.     

Zircon-scale insights into the history of a Supervolcano,Bishop Tuff,Long Valley,California, with implications for the Ti-in-zircon geothermometer

Zircon has the outstanding capacity to record chronological, thermal, and chemical information, including the storage history of zoned silicic magma reservoirs like the one responsible for the Bishop Tuff of eastern California, USA. Our novel ion microprobe approach reveals that Bishop zircon rims with diverse chemical characteristics surround intermediate domains with broadly similar compositions. The highest Y, REE, U, and Th concentrations tend to accompany the largest excesses in Y + REE³⁺:P beyond what can be explained by xenotime substitution in zircon. Apparent Ti-in-zircon temperatures of <720°C for zircon rims are distinctly lower than most of the range in eruption temperatures, as estimated from FeTi-oxide equilibria and zircon solubility at quench. While permissive of crystallization of zircon at near-solidus conditions, the low Ti-in-zircon temperatures are probably better explained by sources of inaccuracy in the temperature estimates. After apparently nucleating from different melts, zircons from across the Bishop Tuff compositional spectrum may have evolved to broadly similar chemical and thermal conditions and therefore it is possible that there was no significant thermal gradient in the magma reservoir at some stage in its evolution. There is also no compelling evidence for punctuated heat ± chemical influxes during the intermediate stages of zircon growth. Judging by the zircon record, the main volume of the erupted magma evolved normally by secular cooling but the latest erupted portion is characterized by a reversal in chemistry that appears to indicate perfusion of the magma reservoir by—or zircon entrainment in—a less evolved melt from the one in which the zircons had previously resided.     

Solar Rotation in the 17th century

Sunspot drawings made by Galileo Galilei in 1612 are used to derive the law of differential rotation at that time. The main interest of the work is during the time of observations, just at the beginning of telescopic observations and some decades before the Maunder Minimum (1645 – 1715), a period where the sunspots almost disappeared from the solar surface. For this purpose we have carried out careful corrections of the different sources of errors derived from the observing technique. By comparing with other results of the same century, a significant difference is only detected by comparing with data corresponding to the deep Maunder Minimum (Paris Observatory drawings). The characteristics of the solar differential rotation, and extrapolating the behavior of solar activity, did not differ before or after the Maunder Minimum. We also include an analysis of hitherto ignored sunspot drawings by N. Bion made in October and November 1672.     

Degassing of Cl, F, Li, and Be during extrusion and crystallization of the rhyolite dome at Volcán Chaitén, Chile during 2008 and 2009

We investigated the distribution of Cl, F, Li, and Be in pumices, obsidians, and crystallized dome rocks at Chaitén volcano in 2008?C2009 in order to explore the behavior of these elements during explosive and effusive volcanic activity. Electron and ion microprobe analyses of matrix and inclusion glasses from pumice, obsidian, and microlite-rich dome rock indicate that Cl and other elements were lost primarily during crystallization of the rhyolitic dome after it had approached the surface. Glass in pumice and microlite-free obsidian has 888?±?121?ppm Cl, whereas residual glass in evolved microlite-rich dome rock generally retains less Cl (as low as <100?ppm). Estimated Cl losses were likely >0.7?Mt Cl, with a potential maximum of 1.8?Mt for the entire 0.8-km³ dome. Elemental variations reflect an integrated bulk distribution ratio for Cl?>?1.7 (1.7 times more Cl was degassed or incorporated into crystals than remained in the melt). Because Cl is lost dominantly as the very last H₂O is degassed, and Cl is minimally (if at all) partitioned into microlites, the integrated vapor/melt distribution ratio for Cl exceeds 200 (200 times more Cl in the evolved vapor than in the melt). Cl is likely lost as HCl, which is readily partitioned into magmatic vapor at low pressure. Cl loss is accelerated by the change in the composition of the residual melt due to microlite growth. Cl loss also may be affected by open-system gas fluxing. Integrated vapor-melt distribution ratios for Li, F, and Be all exceed 1,000. On degassing, an unknown fraction of these volatiles could be immediately dissolved in rainwater.     

Anodic Oxidation as Green Alternative for Removing Diethyl Phthalate from Wastewater Using Pb/PbO2 and Ti/SnO2 Anodes

The electrochemical oxidation (EO) of diethyl phthalate (DEP) in aqueous solution was studied at Pb/PbO₂ and Ti/SnO₂ anode materials under galvanostatic‐experimental conditions. Results obtained clearly demonstrated that the anode plays a significant role for the optimization of the oxidation process, deciding the mechanisms and by‐products formed. DEP and by‐products of oxidation were also analyzed during various stages of the electrolysis reaction by HPLC and GC/MS techniques. Before the analysis by GC/MS technique, the samples were treated by solid phase microextraction (SPME) in order to concentrate the compounds from the reaction solution and identify all electrolysis intermediates. Current efficiencies (instantaneous current efficiency; ICE and total current efficiency; TCE) achieved during EO experiments were dependent on anode used and current density (20–40 mA cm^?2) at 40°C. The results obtained demonstrated that the environmental electrochemical methods can be a feasible alternative for the wastewater treatment containing hazardous phthalates.     

Quantifying the Morphological Print of Bedload Transport

Bedload and river morphology interact in a strong feedback manner. Bedload conditions the development of river morphology along different space and time scales; however, by concentrating the flow in preferential paths, a given morphology controls bedload for a given discharge. As bedload is a non‐linear response of shear stress, local morphology is likely to have a strong impact on bedload prediction when the shear stress is averaged over the section, as is usually done. This was investigated by comparing bedload measured in different bed morphologies (step‐pool, plane bed, riffle‐pool, braiding, and sand beds), with bedload measured in narrow flumes in the absence of any bed form, used here as a reference. The initial methodology consisted of fitting a bedload equation to the flume data. Secondly, the morphological signature of each river was studied as the distance to this referent equation. It was concluded that each morphology affects bedload in a different way. For a given average grain shear stress, the larger the river, the larger the deviation from the flume transport. Narrow streams are those morphologies that behave more like flumes; this is particularly true with flat beds, whereas results deviate from flumes to a greater extent in step‐pools. The riffle‐pool's morphology impacts bedload at different levels depending on the degree of bar development, considered here through the ratio D₈₄/D₅₀ which is used as a proxy for the local bed patchiness and morphology. In braiding rivers morphological effects are important but difficult to assess because width is dependent on transport rate. Bed morphology was found to have negligible effects in sand bed rivers where the Shields stress is usually sufficiently high to minimize the non‐linearity effects when hydraulics is averaged over the section. Copyright © 2015 John Wiley & Sons, Ltd.     

Correction to: Wind events in a subtropical coastal upwelling region as detected by admittance analysis

Ocean Dynamics - Wind dominates the ocean surface circulation in the subtropical coastal upwelling regions. Although the wind events in these regions are mostly favorable for upwelling, other types...     

Concentrations of elements and metals in sediments of the southeastern Gulf of Mexico

. This paper deals with the extent of contamination in sediments of the southeast Gulf of Mexico. The concentration of elements (SiO2, Al2O3, Fe2O3, Na2O, MgO, CaO, and K2O) and heavy metals (Cu, Cd, Zn, Co, Pb, Ag, Cr, Ni, V, and Ba) were determined. The elemental composition of sediments is influenced by the Grijalva–Usumacinta–Terminos System at the east and the Tabasco lagoon system (El Carmen–La Machona) at the west coast of the study area. Concentrations of Ni, V, and Ba were anomalously high at some sites. Oil production activities in the vicinity of the sites may be responsible for the high values. Correlations of metal concentrations to elemental composition were performed. No significant relationships between metals and elements were found for most metals (p>0.05), suggesting that metals are not significantly associated with naturally occurring aluminosilicates, iron hydroxide, and calcium carbonate minerals of sediments. Other sources such as organic matter may be contributing to the total concentration of metals. The comparison of metal content in sediments of the southeast Gulf of Mexico with metals of the other areas of the Gulf of Mexico suggests that it is relatively contaminated with Cd, Pb, and Ni. The probable causes of contamination are briefly discussed.