Uranium Behavior in the Process of Primary Pitchblende Ores Alteration by the Post‐ore Hydrothermal Solutions: An Application to Assessment of Uranium Migration from Underground Spent Nuclear Fuel Repositories

It has been shown that the main uranium ore mineral, pitchblende (uranium dioxide), is a natural analog of synthetic uraninite (also uranium dioxide), which constitutes 96% of spent nuclear fuel (SNF). Geochronological studies of the U‐Pb isotope systems in unaltered pitchblende from the orebodies reveal that these systems remained completely closed over the entire period (approximately 135 Ma) since the formation of the deposits. The bulk of the primary uranium ores within the Streltsovskoye ore field was influenced to various degrees by post‐ore hydrothermal solutions that led to pitchblende spherulites being replaced by pseudomorphs of an amorphous phase with a U‐Si composition; this phase also re‐precipitated in veinlets proximal to the pitchblende pseudomorphs. A technique specially developed by the authors was used to carry out quantitative counts of the abundance of uranium minerals by calculating the uranium mass balance in one of the orebodies subjected to hydrothermal alteration. The calculations reveal minimal uranium loss from the orebody. Uranium liberated in the process of the pseudomorphic replacement of pitchblende was immediately fixed, in situ, in the newly formed coffinite‐like amorphous U‐Si phase as a result of the development of an efficient geochemical barrier that prevented the long‐distance migration of uranium. In assessing the long‐term safety of underground SNF repositories, the results of the present study give us confidence that SNF uraninite, in terms of the preservation of its integrity as a mineral phase, provides for the reliable long‐term isolation of uranium, transuranium elements, and fission products that are “sealed” in the uraninite matrix. In the case of the mineral transformation of the uraninite matrix by hydrothermal solutions, the liberated uranium would be efficiently immobilized by the newly formed amorphous U‐Si phase.     

A Special Issue on Data Science for Geosciences

Mathematical Geosciences -     

ON CERTAIN STATEMENTS IN “RECIDIVISM OF COMMUNICATIVE CARTOGRAPHY UNDER THE GUISE OF AUTOMATION”

Several researchers, including some affiliated with the Moscow Institute of Geodetic, Aerial Photographic, and Cartographic Engineers, an important center of geodetic and cartographic training in the USSR, continue the debate on automation in cartography featured in the preceding issue of Mapping Sciences and Remote Sensing (1986, No. 4, pp. 274–288). They advocate continuation of some of the more promising research directions outlined in Ye. Ye. Shiryayev's book, criticize certain of its ideas regarding cartographic communication, generalization, and raster digitizing, and call for increased attention to the role of the geodetic sciences in the training of cartographers. The current debate stems from lack of adequate definitions for many concepts involved with cartographic presentation, inadequate development of a theory of automation, and lack of coordination in research among concerned organizations. Translated from: Geodeziya i kartografiya, 1986, No. 7, pp. 37–42.     

Crystal chemistry of Fe3+-bearing (Mg,Fe)SiO3 perovskite: a single-crystal X-ray diffraction study

Magnesium silicate perovskite is the predominant phase in the Earth’s lower mantle, and it is well known that incorporation of iron has a strong effect on its crystal structure and physical properties. To constrain the crystal chemistry of (Mg, Fe)SiO₃ perovskite more accurately, we synthesized single crystals of Mg_0.946(17)Fe_0.056(12)Si_0.997(16)O₃ perovskite at 26 GPa and 2,073 K using a multianvil press and investigated its crystal structure, oxidation state and iron-site occupancy using single-crystal X-ray diffraction and energy-domain Synchrotron Mössbauer Source spectroscopy. Single-crystal refinements indicate that all iron (Fe²⁺ and Fe³⁺) substitutes on the A-site only, where \( {\text{Fe}}^{ 3+ } /\Upsigma {\text{Fe}}\sim 20\,\% \) based on Mössbauer spectroscopy. Charge balance likely occurs through a small number of cation vacancies on either the A- or the B-site. The octahedral tilt angle (Φ) calculated for our sample from the refined atomic coordinates is 20.3°, which is 2° higher than the value calculated from the unit-cell parameters (a = 4.7877 Å, b = 4.9480 Å, c = 6.915 Å) which assumes undistorted octahedra. A compilation of all available single-crystal data (atomic coordinates) for (Mg, Fe)(Si, Al)O₃ perovskite from the literature shows a smooth increase of Φ with composition that is independent of the nature of cation substitution (e.g., \( {\text{Mg}}^{ 2+ } - {\text{Fe}}^{ 2+ } \) or \( {\text{Mg}}^{ 2+ } {\text{Si}}^{ 4+ } - {\text{Fe}}^{ 3+ } {\text{Al}}^{ 3+ } \) substitution mechanism), contrary to previous observations based on unit-cell parameter calculations.     

First results on determination of cosmogenic 36Cl in limestone from the Yenicekale Complex in the Hittite capital of Hattusha (Turkey)

We have measured ³⁶Cl in three rock surfaces of the Yenicekale building complex in Hattusha (Bo?azköy, Turkey). Hattusha was the capital of Hittite Empire which lasted from about 1650/1600 to 1200 BC. At Yenicekale, Hittite masons flattened the summit of an outcropping limestone knoll to form an artificial platform as the foundation for a building. Next they built a circuit wall along the lateral precipices of the flattened bedrock platform. We took one sample from the limestone bedrock platform and two samples from limestone building blocks of the circuit wall for cosmogenic ³⁶Cl analysis. Calculated exposure ages are 20 ± 1 ka for the sample from the bedrock platform and 24 ± 1 ka and 52 ± 2 ka for the circuit wall blocks. These exposure ages are significantly older than the age expected based on the estimated time of construction between 3.2 ka and 3.7 ka. We conclude that the sampled surfaces contain significant inherited cosmogenic ³⁶Cl. We cannot directly determine exposure ages for the building complex based on these three samples. On the other hand we may use the measured concentrations to determine how much of the rock was removed from the platform during flattening. To this end we modeled the variation of ³⁶Cl production with depth at Yenicekale using the results from the bedrock sample. We conclude that the Hittite masons removed only around 3 m from top of the limestone block. This means that the volume of rock removed from the bedrock platform is significantly less than the volume in the circuit wall atop the platform. They did not gain enough rock from this flattening to make the building. In agreement with this, the first results of our detailed microfacies analysis indicate that many of the building blocks are not of the same facies as the underlying limestone and must have been quarried elsewhere. Although we were not able to exposure date the Yenicekale complex due to the presence of inherited ³⁶Cl, our data suggest that Hittite masons excavated (most of) the building stones not at Yenicekale, but in quarries outside of Hattusha and then transported them to the construction site. These quarries have not yet been identified.     

Numerical Simulations of Tsunami Waves and Currents for Southern Vancouver Island from a Cascadia Megathrust Earthquake

The 1700 great Cascadia earthquake (M = 9) generated widespread tsunami waves that affected the entire Pacific Ocean and caused damage as distant as Japan. Similar catastrophic waves may be generated by a future Cascadia megathrust earthquake. We use three rupture scenarios for this earthquake in numerical experiments to study propagation of tsunami waves off the west coast of North America and to predict tsunami heights and currents in several bays and harbours on southern Vancouver Island, British Columbia, including Ucluelet, located on the west coast of the island, and Victoria and Esquimalt harbours inside Juan de Fuca Strait. The earthquake scenarios are: an 1100-km long rupture over the entire length of the subduction zone and separate ruptures of its northern or southern segments. As expected, the southern earthquake scenario has a limited effect over most of the Vancouver Island coast, with waves in the harbours not exceeding 1 m. The other two scenarios produce large tsunami waves, higher than 16 m at one location near Ucluelet and over 4 m inside Esquimalt and Victoria harbours, and very strong currents that reach 17 m/s in narrow channels and near headlands. Because the assumed rupture scenarios are based on a previous earthquake, direct use of the model results to estimate the effect of a future earthquake requires appropriate qualification.     

Palaeolimnological evidence for recent climatic change in lakes from the northern Urals, arctic Russia

The recent sediments from two deep arctic lakes, Mitrofanovskoe and Vanuk-ty, situated in the permafrost belt within the Bolshezemelskaya Tundra in the northern Ural region, were studied for diatoms, chironomids, spheroidal carbonaceous particles and stable lead isotopes. The magnitudes and rates-of-change in diatom and chironomid assemblages were numerically estimated. Instrumental climate records were used to assess statistically the amount of variance in diatom and chironomid data explained by temperature. August and September air temperatures have a statistically significant effect on diatom composition at both lakes. At Mitrofanovskoe Lake, major compositional changes in diatom and chironomid assemblages occurred at the turn of the 20th century and might be related to the regional increase in temperature. Chironomid-inferred air temperature also increased by approximately 1 °C since the early 1900s. At both lakes diatom compositional changes, coincident with the increase in June and September temperatures, also occurred in the late 1960s. These compositional changes are correlated with the increase in diatom production, sediment organic content and diatom species richness, and are likely to be a diatom response to the lengthening of the growing season. These changes are also correlated with the circum-Arctic temperature increase from the 1960s. A chironomid response to the late 1960s temperature increase was less pronounced at both lakes. Pollution levels are relatively low and pollution history is unrelated to ecological changes. Both lead isotopes and spheroidal carbonaceous particles show a clear atmospheric pollution signal, peaking in the 1980s.     

Combating desertification in the Negev: dryland agriculture vs. dryland urbanization

The Negev region occupies nearly two-third of Israel's land area (21,671 km²) but hosts less than 9% of its 6.5 million strong population. Until recently, the process of desertification did not affect the Negev profoundly. This was mainly due to large-scale afforestation programs, restrictions imposed on grazing, and large water subsidies from the less arid part of the country to its more arid part. However, there are some indications that the process of desertification in the Negev has already started and may accelerate in the future. In light of this trend, the efficient long-term strategy for the Negev's development is essential. The present study compares two alternative strategies of the Negev's future development: agricultural expansion vs. urbanization path. Two basic criteria—the minimization of adverse environmental impacts and economic feasibility—are used for the evaluation. The urbanization path is found to be preferable. Since agriculture and livestock grazing are the major contributors to desertification, replacing them with urban development may lessen the risk of desertification in the future. In contrast, urban development, if properly planned and regulated, may reduce the spatial extent of the area affected by agricultural development, and thus minimize the anthropogenic impact on the desert environment. Economic reason is also important: While even in the future, agricultural production in the Negev may remain limited due to economic considerations, urban development may justify the often-large investment required for the provision of fresh water.     

The 1994 Shikotan earthquake tsunamis

The 1994 Shikotan earthquake was one of the greatest earthquakes in recent years with a magnitude ofM _s 8.0. A tsunami survey was conducted by Russian and U.S. geophysicists from October 16–30, 1994, less than two weeks after the earthquake. The survey results and a numerical hindcast simulation are reported. Tsunami focusing effect at locations supposedly sheltered by the island chain is discussed. Based on the obtained data, tsunamis which attacked Shikotan Island are characterized as long waves (the order of 10–20 min wave period) with a positive leading wave. Possible consequences of the positive leading wave form are discussed in relation to the observed minimal destruction of beach vegetation and relatively small transport of marine sediment onto the shore. The high-quality tide-gage record in Malokurilskaya Bay indicates the occurrence of a 53 cm subsidence at the site.