Pyrite oxidation inhibition by a cross-linked lipid coating

The effect of a diacetylene-containing phospholipid on the oxidation of pyrite, FeS₂, was investigated. Earlier work reported by our research group showed that the adsorption of l,2-bis(10,12-tricosadiynoyl)-sn-glycero-3-phosphocholine on pyrite suppressed the extent of its oxidation by about 75% over a specific time period. Results presented here show that the pre-exposure to UV radiation of this lipid after sorption onto pyrite results in a 90% suppression. Attenuated total reflection (ATR) Fourier transform infra-red spectroscopy (FTIR) suggests that the UV irradiation of the lipid does not result in degradation of the adsorbed layer. It is believed that the UV exposure results in the cross-linking and polymerization of the adsorbed phospholipid into a relatively impermeable barrier that separates the pyrite from the aqueous phase. The results of this study might have implications for the protection of pyrite from oxidation in the environment.     

Sulfur geochemistry of hydrothermal waters in Yellowstone National Park,Wyoming, USA. III. An anion-exchange resin technique for sampling and preservation of sulfoxyanions in natural waters

A sampling protocol for the retention, extraction, and analysis of sulfoxyanions in hydrothermal waters has been developed in the laboratory and tested at Yellowstone National Park and Green Lake, NY. Initial laboratory testing of the anion-exchange resin Bio-Rad™ AG1-X8 indicated that the resin was well suited for the sampling, preservation, and extraction of sulfate and thiosulfate. Synthetic solutions containing sulfate and thiosulfate were passed through AG1-X8 resin columns and eluted with 1 and 3 M KCl, respectively. Recovery ranged from 89 to 100%. Comparison of results for water samples collected from five pools in Yellowstone National Park between on-site IC analysis (U.S. Geological Survey mobile lab) and IC analysis of resin-stored sample at SUNY-Stony Brook indicates 96 to 100% agreement for three pools (Cinder, Cistern, and an unnamed pool near Cistern) and 76 and 63% agreement for two pools (Sulfur Dust and Frying Pan). Attempts to extract polythionates from the AG1-X8 resin were made using HCl solutions, but were unsuccessful. Bio-Rad™ AG2-X8, an anion-exchange resin with weaker binding sites than the AG1-X8 resin, is better suited for polythionate extraction. Sulfate and thiosulfate extraction with this resin has been accomplished with KCl solutions of 0.1 and 0.5 M, respectively. Trithionate and tetrathionate can be extracted with 4 M KCl. Higher polythionates can be extracted with 9 M hydrochloric acid. Polythionate concentrations can then be determined directly using ion chromatographic methods, and laboratory results indicate recovery of up to 90% for synthetic polythionate solutions using AG2-X8 resin columns.     

Upward-thickening patterns and lateral continuity of Permian sand-rich turbidite channel fills, Laingsburg Karoo, South Africa

Abstract Analysis of extensive exposures of the Permian Laingsburg Formation, Karoo basin, South Africa, have enabled a detailed reconstruction of the base of slope stratigraphy and palaeoenvironments in a deep-water system characterized by a very narrow grain-size range (fine sandstone). The deposits include an ≈ 4 km wide and 80 m thick channel complex, fringed by sandy sheet deposits that extend laterally for at least 6 km across depositional strike. Within the channel complex, individual channel fills are marked by shallow basal erosion surfaces draped by thin, parallel-stratified beds of very fine sandstone and siltstone, interpreted as flow tails to largely bypassing flows. These thin beds are overlain by 0·4 to 5 m thick beds of structureless, fine-grained sandstone that represent the majority of the channel fills. The basal packages may be partially to completely removed by localized scour in the axial zone of the channel complex but can be mapped laterally into overbank areas where they thicken and are dominated by rippled fine sandstones with intercalated siltstones. Axial confinement resulted from subtle topography on the basin floor, whereby the lower, dense parts of the initially erosive and bypassing flows were partially confined in the lows and the more dilute, slower moving upper parts of the flows deposited sheet-like successions across slightly elevated overbank areas. The narrow grain-size distribution prohibited the formation ofcoarse-grained residual bypass deposits during the initial phases of channel formation. With decreasing magnitude, later flows became more depositional, filling remaining axial depressions with thick-bedded structureless sandstone. The smaller volumes of late-stage sediment were more axially focused, producing local scour-and-fill features and starvation of the overbank areas. Resulting grain-size vertical profiles are complex. The basal flow tail packages and overlying massive deposits form a thickening and slightly coarsening-upward trend in the channel fills. The overbank deposits show a thinning- and fining-upward profile as a result of less bypass plus late-stage starvation of sand. Application of traditional deep-water facies models could therefore potentially lead to erroneous interpretations of the channel complex as a prograding lobe and the overbank sheets as channel-fills.     

Surface water/groundwater interaction in the Piora Aquifer,Switzerland: evidence from dye tracing tests

Results of seven dye tracing tests done from 1993–1997 to investigate the extent to which lakes and surface water interact with the underlying Triassic Piora Aquifer, Switzerland, are reported here. Two of the dye tracing tests showed that groundwater flows in the Piora Aquifer from the Piora Valley to springs in the adjacent Santa Maria Valley, and even further east to the di Campo Valley considerably outside of the Piora Valley surface water divide. Lake Ritom located in the Piora Valley loses water only to the Canaria Valley outside of the lake's surface-water watershed at the lake's western margin when lake levels are above 1,835 m above sea level. Dye tracing tests show that a major sinkhole in the Piora Valley, Calderoni Sinkhole, is located precisely on the water divide where subsurface flow in the Piora Valley and surface water diverge and move in opposite directions. The dye tracing results also showed no hydraulic connection between surface water in the Piora Valley and the famous Pertusio Spring, located in the upper Santa Maria Valley. Only a small amount of dye from the two dye tracing tests done in 1993 and 1997 entered an exploratory gallery built to test the viability of the AlpTransit tunnel, being built in competent rock under the Triassic Piora Aquifer, effectively perched above. Electronic Publication     

Stability Analysis of the Climate-Vegetation System in the Northern High Latitudes

The stability of the climate-vegetation system in the northern high latitudesis analysed with three climate system models of different complexity: A comprehensive 3-dimensional model of the climate system, GENESIS-IBIS, and two Earth system models of intermediate complexity (EMICs), CLIMBER-2 andMoBidiC. The biogeophysical feedback in the latitudinal belt 60–70° N, although positive, is not strong enough to support multiple steady states: A unique equilibriumin the climate-vegetation system is simulated by all the models on a zonal scale for present-day climate and doubled CO₂ climate.EMIC simulations with decreased insolation also reveal a unique steady state. However, the climate sensitivity to tree cover, T_F, exhibits non-linear behaviour within the models. For GENESIS-IBIS and CLIMBER-2, T_F islower for doubled CO₂ climate than for present-day climate due to a shorter snow season and increased relative significance ofthe hydrological effect of forest cover. For the EMICs, T_F is higher for low tree fraction than for high treefraction, mainly due to a time shift in spring snow melt in response to changes in tree cover. The climate sensitivity to tree coveris reduced when thermohaline circulation feedbacks are accounted for in the EMIC simulations. Simpler parameterizations of oceanic processes have opposite effects on T_F: T_F is lower in simulations with fixed SSTs and higher in simulations with mixed layer oceans. Experiments with transient CO₂ forcing show climate and vegetation not in equilibrium in the northern high latitudes at the end of the 20thcentury. The delayed response of vegetation and accelerated global warming lead to rather abrupt changes in northern vegetation cover in the first halfof the 21st century, when vegetation cover changes at double the present day rate.     

Simulation of Surface Air Temperature by GCMs,Statistical Downscaling and Weather Generator: Higher-Order Statistical Moments

The third and fourth statistical moments, that is, skewness and kurtosis, are compared for daily maximum temperature in summer and daily minimum temperature in winter between observations, outputs of two global climate models, four versions of statistical downscaling, and weather generator. The comparison is performed at six stations in central Europe. None of the simulation models can be considered as superior to the others. Causes of a good correspondence with and differences from observations are identified e.g. in the treatment of physics in the models, imperfections in physical parameterizations, or a linear transfer of properties from predictors onto predictands in statistical downscaling.     

The most-cited works in Geomorphology

We conducted a review and analysis of the references cited in articles published (1995–2004) in the journal Geomorphology and also solicited comments from the authors of the most-cited works on their major influences. Of the 31,696 unique works cited in the journal, only 22 were referenced at least 20 times, with the vast majority (92%) cited only once or twice. We divided the citations into the 10 most-cited books (i.e., complete volumes) and 10 most-cited papers (i.e., journal articles, book chapters, reports). A total of 23 different researchers were responsible for the 20 works, with one (Wolman) being an author or co-author of a quarter of them. Seven of the ten most-cited papers were based on work in the USGS in the mid-twentieth century, indicating a particularly fruitful time of geomorphic research and a particularly important cohort of scientists. Based on our citation analysis and author commentaries, we suggest that classic works in geomorphology are most likely to be those that provide useful knowledge and those that incorporate interdisciplinary perspectives.     

Climate Change Impacts and Adaptation Strategies in Spring Barley Production in the Czech Republic

The crop model CERES-Barley was used to assess the impacts of increased concentration of atmospheric CO₂ on growth and development of the most important spring cereal in Central and Western Europe, i.e., spring barley, and to examine possible adaptation strategies. Three experimental regions were selected to compare the climate change impacts in various climatic and pedological conditions. The analysis was based on multi-year crop model simulations run with daily weather series obtained by stochastic weather generator and included two yield levels: stressed yields and potential yields. Four climate change scenarios based on global climate models and representing 2 × CO₂ climate were applied. Results: (i) The crop model is suitable for use in the given environment, e.g., the coefficient of determination between the simulated and experimental yields equals 0.88. (ii) The indirect effect related to changed weather conditions is mostly negative. Its magnitude ranges from ?19% to +5% for the four scenarios applied at the three regions. (iii) The magnitude of the direct effect of doubled CO₂ on the stressed yields for the three test sites is 35–55% in the present climate and 25–65% in the 2 × CO₂ climates. (iv) The stressed yields would increase in 2 × CO₂ conditions by 13–52% when both direct and indirect effects were considered. (v) The impacts of doubled CO₂ on potential yields are more uniform throughout the localities in comparison with the stressed yields. The magnitude of the indirect and direct effects ranges from ?1 to ?9% and from +31 to +33%, respectively. Superposition of both effects results in 19–30% increase of the potential yields. (vi) Application of the earlier planting date (up to 60 days) would result in 15–22% increase of the yields in 2 × CO₂ conditions. (vii) Use of a cultivar with longer vegetation duration would bring 1.5% yield increase per one extra day of the vegetation season. (viii) The initial water content in the soil water profile proved to be one of the key elements determining the spring barley yield. It causes the yields to increase by 54–101 kg.ha^?1 per 1% increase of the available soil water content on the sowing day.     

Subsurface structure under a basaltic monogenetic volcano near the active Atera fault

In this study, we examined the subsurface structure in the vicinity of the active Atera fault beneath at least one monogenetic volcano that forms the Sakashita body of the Ueno basalts, central Japan. Microgravity and seismic reflection surveys over an area of about 3×3 km (horizontal)×1 km (vertical from surface) revealed that (1) a low-density body interpreted as the damaged zone of the Atera fault reaches a depth more than 200 m below sea level; and (2) a weak zone of crust that may exist about 1.5 km southwest of the Atera fault in a direction parallel to it. By combining the shape of the Sakashita body and (2), we propose that a dyke extending in a NW–SE direction with several vent alignments in the same direction may exist along this weak zone. This suggests that the studied area was governed in the NW–SE compressional and NE–SW extensional stress field when the Sakashita body formed.