Petrography and geochemistry of Jurassic sandstones from the Jhuran Formation of Jara dome,Kachchh basin,India: Implications for provenance and tectonic setting

Sandstones of Jhuran Formation from Jara dome, western Kachchh, Gujarat, India were studied for major, trace and rare earth element (REE) geochemistry to deduce their paleo-weathering, tectonic setting, source rock characteristics and provenance. Petrographic analysis shows that sandstones are having quartz grains with minor amount of K-feldspar and lithic fragments in the modal ratio of Q ₈₉:F ₇:L ₄. On the basis of geochemical results, sandstones are classified into arkose, sub-litharenite, wacke and quartz arenite. The corrected CIA values indicate that the weathering at source region was moderate to intense. The distribution of major and REE elements in the samples normalized to upper continental crust (UCC) and chondrite values indicate similar pattern of UCC. The tectonic discrimination diagram based on the elemental concentrations and elemental ratios of Fe₂O₃ + MgOvs. TiO₂, SiO₂ vs. log(K₂O/Na₂O), Sc/Cr vs. La/Y, Th–Sc–Zr/10, La–Th–Sc plots Jhuran Formation samples in continental rift and collision settings. The plots of Ni against TiO₂, La/Sc vs. Th/Co and V–Ni–Th ?10 reveals that the sediments of Jhuran Formation were derived from felsic rock sources. Additionally, the diagram of (Gd/Yb) _N against Eu/Eu ^? suggest the post-Archean provenance as source possibly Nagar Parkar complex for the studied samples.     

Age of nephrite-bearing dikes of the Uzunkyr Belt (South Urals): Local U-Pb isotope analysis of zircon and Sr-Nd isotope data of rock-forming minerals

Through local U-Pb isotope analysis of zircon and Sir-Need data on rock-forming minerals, the age of nephrite-bearing monzonite-diorite dikes of the Uzunkyr Belt has been determined. The derived datings coincide with known geological events that took place in the Phanerozoic on the territory of the South Urals. Xenogenic zircons prove the participation of the Upper Ordovician units in the tectonic structure of the studied area. Devonian zircons are associated with assimilation of subvolcanic rocks which are middle and basic in composition and whose formation time correlates with the appearance of the subduction zone with the Magnitogorsk island arc above it. Early Carboniferous datings indicate the relationship between dike formation and formation of the continental arc-shaped structure to which the Syrostan massif (monzodiorite-granite formation) belongs. The age range of the Uzunkyr nephrite-bearing dikes coincides with that of intrusives (350–336 Ma) of the Magnitogorsk Belt, where formation of gabbro series was also changed by formation of subalkali and alkali igneous rocks. According to the analogous data on zircon datings from metamorphic rocks of the Il’menogorskii Complex, the given territory later evolved as a whole.     

Effect of core porosity on stability and run-up of breakwaters

The commonly used formulae like Hudson's [(1959), Laboratory investigations of rubblemound breakwaters. WES report, Vicksburg], Iribarren's or Vander meer's [(1988), Rockslopes and gravel beaches under wave attack. Ph.D. thesis, Delft University of Technology, The Netherlands], do not give us the design cross section of a rubblemound breakwater for varying core porosity values. The paper presents the results of the experimental study carried out to compute the effects of core porosity on the stability and run-up characteristics of rubblemound breakwaters. Regular waves were made to attack the structure, with different core porosity values in a normal direction. The porosity of the armour and the secondary layers was neglected. It was observed that as core porosity increased the stability also increased considerably within the limits of the experimental data values. This may be due to large inflow and energy dissipation within the core of the structure. The run-up on the rubblemound slope was found to decrease with the increase in the porosity for the same reason.     

Polar stratospheric clouds from satellite observational data

The spectral aerosol-extinction coefficients (SAECs) obtained from SAGE III measurements are used to study the physical and integral microphysical characteristics of polar stratospheric clouds (PSCs). Different criteria for PSC identification from SAEC measurements are considered and analyzed based on model and field measurements. An intercomparison of them is performed, and the agreement and difference of the results obtained with the use of different criteria are shown. A new criterion is proposed for PSC identification, which is based on the estimate of how close the measured vector of the spectral attenuation coefficient is to a model distribution of the PSC ensemble. On the basis of different criteria, cases of PSCs are isolated from all SAGE III observations (over 30000). All selection criteria lead to a qualitatively and quantitatively similar space-time distribution of the regions of PSC localization. The PSCs observed in the region accessible to SAGE III measurements are localized in the latitudinal zones 65°–80° in the Northern Hemisphere and 45°–60° in the Southern Hemisphere during the winter-spring period. In the Northern Hemisphere, PSCs are observed within the longitudinal zone 120° W–100° E with the maximum frequency of PSC observation in the vicinity of the Greenwich meridian. In the Southern Hemisphere, the region of PSC observation is almost the same in longitude but with a certain shift in the maximum frequency of PSC observation to the west. This maximum is observed in the vicinity of 40°W, and the region of usual PSC observation is the neighborhood of 60° of the maximum’s longitude. The physical parameters of PSCs are estimated: the mean heights of the lower and upper boundaries of PSCs are 19.5 and 21.9 km, respectively, and the mean cloud temperature is 191.8 K. The integral microphysical parameters of PSCs are estimated: the total surface of NAT particles S _NAT = 0.41 μm²/cm³; the total volume of NAT particles V _NAT = 1.1 μm³/cm³; and, for all aerosol and cloud particles together, S is 2.9 ± 1.5 at a standard deviation of 2.7 μm²/cm³ and V is 2.8 ± 1.5 at a standard deviation of 4.2 μm³/cm³. A high frequency of PSC occurrence and high values of S and V in PSCs both for all particles and for NAT particles have been noted in January–February 2005 as compared to the rest of the period of SAGE III measurements for 2002–2005.     

A site-specific study on the measurement of sorption coefficients for radionuclides

A study on the potential of geological media from the vicinity of the mining site in Tummalapalle region of Andhra Pradesh in India for retardation of radionuclide migration in groundwater was conducted. The studies included the measurement of sorption coefficients for six radionuclides, uranium, thorium, lead, bismuth, radium and polonium, between two groundwater simulants and two site-specific samples of geological media. Initial parametric studies involving chemical composition, pH, calcium carbonate and organic carbon contents of both geological media and ground water simulants were carried out. Significant differences in sorption coefficients were observed as a result of varying pH, calcium carbonate and presence of trace quantities of organic contents in simulant solutions. For example, uranium has a hundred fold lower distribution coefficient in the case of simulant solution having higher carbonate content. Similarly, in the case of the geological media having higher calcium carbonate and organic carbon contents, higher distribution coefficients were obtained for all radionuclides. Among the six radionuclides studied thorium showed the largest and radium the smallest distribution coefficient values for the soil samples assessed. The site-specific sorption coefficients will be used for contaminant transport study.     

A verification framework for interannual-to-decadal predictions experiments

Decadal predictions have a high profile in the climate science community and beyond, yet very little is known about their skill. Nor is there any agreed protocol for estimating their skill. This paper proposes a sound and coordinated framework for verification of decadal hindcast experiments. The framework is illustrated for decadal hindcasts tailored to meet the requirements and specifications of CMIP5 (Coupled Model Intercomparison Project phase 5). The chosen metrics address key questions about the information content in initialized decadal hindcasts. These questions are: (1) Do the initial conditions in the hindcasts lead to more accurate predictions of the climate, compared to un-initialized climate change projections? and (2) Is the prediction model’s ensemble spread an appropriate representation of forecast uncertainty on average? The first question is addressed through deterministic metrics that compare the initialized and uninitialized hindcasts. The second question is addressed through a probabilistic metric applied to the initialized hindcasts and comparing different ways to ascribe forecast uncertainty. Verification is advocated at smoothed regional scales that can illuminate broad areas of predictability, as well as at the grid scale, since many users of the decadal prediction experiments who feed the climate data into applications or decision models will use the data at grid scale, or downscale it to even higher resolution. An overall statement on skill of CMIP5 decadal hindcasts is not the aim of this paper. The results presented are only illustrative of the framework, which would enable such studies. However, broad conclusions that are beginning to emerge from the CMIP5 results include (1) Most predictability at the interannual-to-decadal scale, relative to climatological averages, comes from external forcing, particularly for temperature; (2) though moderate, additional skill is added by the initial conditions over what is imparted by external forcing alone; however, the impact of initialization may result in overall worse predictions in some regions than provided by uninitialized climate change projections; (3) limited hindcast records and the dearth of climate-quality observational data impede our ability to quantify expected skill as well as model biases; and (4) as is common to seasonal-to-interannual model predictions, the spread of the ensemble members is not necessarily a good representation of forecast uncertainty. The authors recommend that this framework be adopted to serve as a starting point to compare prediction quality across prediction systems. The framework can provide a baseline against which future improvements can be quantified. The framework also provides guidance on the use of these model predictions, which differ in fundamental ways from the climate change projections that much of the community has become familiar with, including adjustment of mean and conditional biases, and consideration of how to best approach forecast uncertainty.     

Programme of the Galactic meridian: Star counts and Galactic models 2. Distribution of absolute proper motions

A comparison of the observed distribution of absolute proper motions with a kinematical model of the Galaxy is presented. Proper motions with respect to galaxies were obtained for about 40 000 stars along the main Galactic meridian and in two fields near the North Galactic pole (programme MEGA). The Galaxy is considered as composed of the disk (main sequence and disk red giants), the thick disk and spheroid populations. For each subsystem, spatial velocity components and their dispersions were computed. The distribution of kinematical parameters were modelled for stars located in different directions of the Galaxy.     

The Mars oxidant experiment (MOx) for Mars '96

The MOx instrument was developed to characterize the reactive nature of the martian soil. The objectives of MOx were: (1) to measure the rate of degradation of organics in the martian environment; (2) to determine if the reactions seen by the Viking biology experiments were caused by a soil oxidant and measure the reactivity of the soil and atmosphere: (3) to monitor the degradation, when exposed to the martian environment, of materials of potential use in future missions; and, finally, (4) to develop technologies and approaches that can be part of future soil analysis instrumentation. The basic approach taken in the MOx instrument was to place a variety of materials composed as thin films in contact with the soil and monitor the physical and chemical changes that result. The optical reflectance of the thin films was the primary sensing-mode. Thin films of organic materials, metals, and semiconductors were prepared. Laboratory simulations demonstrated the response of thin films to active oxidants.     

Electrodialytic remediation of CCA-treated waste wood in pilot scale

When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m³ wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As.