Sources and biogeochemical cycling of particulate selenium in the San Francisco Bay estuary

As part of a study of estuarine selenium cycling, we measured the concentration, chemical form (speciation), and distribution of particulate selenium under various river flow conditions in the North San Francisco Bay (from the Golden Gate to the Sacramento and San Joaquin Rivers). We also conducted laboratory studies on the accumulation of selenium by phytoplankton, the critical first step in the transformation of dissolved to particulate selenium. Total particulate selenium concentration in the North SF Bay was relatively constant between high and low flow periods, ranging spatially from 0.05 to 0.35 nmol l⁻¹ and comprising between 5 and 12% of the total water column selenium inventory. Mean concentrations were generally highest in the Carquinez Strait–Suisun Bay region (salinity 0–17) and lowest in Central Bay. However, selenium content of suspended particles varied with river flow, with higher content during low flow (9.76 ± 4.17 nmol g⁻¹; mean ± sd; n = 67) compared to high flow (7.10 ± 4.24 nmol g⁻¹; n = 39). Speciation analyses showed that most particulate selenium is organic selenide (45 ± 27%), with a smaller proportion (typically <30%) of adsorbed selenite + selenate and a varying proportion (35 ± 28%) of elemental selenium. Based on the amount of elemental selenium in the seston (total suspended material), we calculate that resuspension of estuarine sediments could contribute 29–100% of particulate selenium in the water column. While selenium content of SF Bay seston (>0.4 μm) is relatively unenriched compared to phytoplankton (13.6–155 nmol g⁻¹ dry weight) on a mass basis, when normalized to carbon or nitrogen, seston contains a similar selenium concentration to SF Bay sediments or phytoplankton cultures. SF Bay seston is thus comprised of selenium-rich phytoplankton and phyto-detritus, but also inorganic clay mineral particles that effectively “dilute” total particulate selenium. Selenium concentrations in algal cultures (11 species) exposed to 90 nmol l⁻¹ selenite show relatively large differences in selenium accumulation, with the diatoms, chlorophytes and cryptophytes generally having lower selenium cell content (3.8 ± 2.7 × 10⁻⁹ nmol selenium cell⁻¹) compared to the dinoflagellates (193 ± 73 × 10⁻⁹ nmol selenium cell⁻¹). Because phytoplankton are such a rich (but variable) source of selenium, their dynamics could have a profound effect on the particulate selenium inventory in the North SF Bay.     

印度东南部海岸拉梅斯沃勒姆滨外保克湾底层水特征对底栖有孔虫的影响

有孔虫生活在海洋和半咸水环境。底栖有孔虫的存在很大程度上受物理因素（深度、温度、光量、水体扰动）、化学因素（盐度、溶解氧和可用元素）和生物因素（食物供给量和底层沉积物特征）的制约。研究人员对印度东、西岸现代底栖有孔虫生态学和分布状态进行了研究。Ｎａｉｄｕ等在对Ｖｉｓａｋｈａｐａｔｎａｍ港复合体有孔虫进行分析后提出 ,可以将有孔虫作为海洋污染的指示物。ＳｒｅｅｎｉｖａｓａＲａｏ等采用Ｑ模式系数分析对尼赞伯德讷姆湾有孔虫的分布进行了研究 ,确认此区域存在４种组合 ,受不同环境条件的影响。Ｋｈａｒｅ等对门格…     

Local buckling strength of ring stiffened cylindrical shells under external pressure

The paper presents a non-linear buckling analysis of ring stiffened cylindrical shells subject to external pressure. The collapse pressure is calculated by assuming failure to occur when the material reaches a plastic stress state defined by the Ilyushin criterion. It is shown in the paper that use of the non-linear theory can reduce the estimated first yield by up to 25% in comparison to the linear buckling analysis used up to now. Comparison of predicted failure loads are in good agreement with the lower bound of test results.     

Wave diffraction through submerged flexible breakwaters

This paper presents an analytical, computationally efficient method for the wave reflection and dynamic displacement of a submerged flexible breakwater. The solution of the two-dimensional linearized hydrodynamic problem introduced is based on the eigenfunction expansion technique. The breakwater is assumed to be thin, impermeable, flexible, moored to the bed through tethers and kept in tension by means of a floating buoy at its tip. The beam structure is considered to be either clamped or hinged at the sea bed, situated in an arbitrary water depth and subjected to normal linear waves. Numerical examples presented by this method are compared with those obtained by the Boundary Integral Equation Method, presented by Williams et al. Comparisons show an excellent agreement over a wide range of parameters for the wave reflection and the dynamic displacement. Numerical results are presented, mainly to show the effect of the breakwater rigidity and the method of fixation on the wave reflection and the structural displacement over a wide range of wave frequencies.     

On the dynamics of oceanographic surface moorings

An analytical model is proposed for predicting the dynamics of instrumented oceanographic surface moorings made up of a combination of wire rope and compliant synthetic rope. The model simplifies the problem by treating only the vertical motion of the buoy and the longitudinal motion of the mooring line and attached instruments. It is demonstrated using full-scale experimental data and numerical simulations, that the simplified model captures all of the important dynamic effects and gives accurate predictions of the dynamic tension at the top of the mooring line. The model shows that the total mass and damping of the instruments and wire rope that make up the stiff upper half of the mooring are the major sources of the dynamic tension. Damping of the instruments becomes a significant factor in larger sea states, especially near the peak frequency of the wave spectrum. Elastic stretching of the wire and synthetic rope make up approximately 10% of the total response. This is based on a coefficient of friction equal to 0.003 which fits the experimental data best.