Mineralogy and fluid inclusion study of polymetallic veins in the Madjarovo ore field,Eastern Rhodope,Bulgaria

Summary The formation of the Madjarovo polymetallic ore deposit is closely related to Paleogene magmatism of intermediate character represented by subvolcanic and volcanic rocks. Six stages of vein type mineralization were established: 1. quartz-pyrite-chalcopyrite with Bi-sulphosalts; 2. quartz-hematite-chlorite with gold; 3. quartz-galena-sphalerite; 4. quartz-barite-chalcedony with Sb-sulphosalts; 5. quartz-arsenic sulphosalts; 6. calcite-siderite. Ag-bearing galena and Fe-poor sphalerite are the main minerals. Galena of early formation is Bi-bearing, while in late stages it carries more Sb. Gold was found in two generations in different parageneses. The early gold is Ag-poor and related to hematite, while the late one is Ag-rich and closely associated with quartz and sulphosalts. Three groups of sulphosalts were established: Se-bearing Bi-sulphosalts; Sb-sulphosalts, a part of them Cl-bearing, and As-sulphosalts with more or less Ag. Fluid inclusion data obtained in quartz, amethyst, sphalerite and barite from several representative ore veins show formation temperatures in the range of 370° to 150°C for different stages of mineralization. Evidence of boiling fluids suggests pressures of 70 to 180 bars which correspond to an average depth of mineralization near 1.000 m. The low salinities of the fluids (a/v 3.5 eq. wt% NaCI) indicate influx of meteoric waters during mineralization. On the basis of mineralogical and fluid inclusion data physicochemical conditions and source of the ore forming fluids are discussed.

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Mineralogie und Flüssigkeitseinschlüsse in polymetallischen Erzgngen der Lagerstätte Madjarovo, Ost-Rhodopen, Bulgarien

Zusammenfassung Die Bildung der polymetallischen Lagerstätte Madjarovo war eng verknüpft mit einem Paläogenen Magmatismus von intermediärem Charakter, der durch Subvulkanite und Vulkanite repräsentiert wird. Es wurden sechs Bildungsstadien der Gangvererzung festgestellt: 1. Quarz-Pyrit-Chalcopyrit mit Bi-Sulfosalzen; 2. Quarz-Hämatit-Chlorit mit Gold; 3. Quarz-Galenit-Sphalerit; 4. Quarz-Baryt-Chalzedon mit Sb-Sulfosalzen; 5. Quarz-As-Sulfosalze; 6. Calcit-Siderit. Ag-führender Galenit und Fe-armer Sphalerit sind die Hauptminerale. Früh gebildeter Galenit is Bi-haltig, während Galenite der späteren Bildungsstadien mehr Sb führen. Gold wurde in zwei Generationen in unterschiedlichen Paragenesen gefunden. Das Früh-Gold (Ag-arm) ist verknüpft mit Hämatit, während das Spät-Gold (Ag-reich) mit Quarz und Sulfosalzen eng assoziiert ist. Es wurden drei Gruppen von Sulfosalzen festgestellt: Se-führende Bi-Sulfosalze; Sb-Sulfosalze, die z.T. Cl-führend sind, und As-Sulfosalze mit mehr oder weniger Ag-Gehalten. Flüssigkeitseinschlüsse in Quarz, Amethyst, Sphalerit und Baryt aus mehreren repräsentativen Erzgängen zeigen Bildungtemperaturen von 370°–150°C für unterschiedliche Mineralisationsstadien. Siedende Lösungen weisen auf einen Druckbereich von 70–180 Bar hin, der einer durchschnittlichen Bildungstiefe von 1.000 m entspricht. Die durchweg niedrige Salinität der Lösungen (durchschnittlich 3.5. Gew.% NaCl äq.) wird auf einen Zufluß von meteorischen Wässern während der Mineralisation zurückgeführt. Auf der Basis der mineralogischen Ergebnisse und der Daten fluider Einschlüse werden die physikochemischen Bedingungen und die Herkunft der Erzlösungen diskutiert.

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With 4 Figures     

Stable isotope study of carbonate-cemented rocks from the Pobitite Kamani area,north-eastern Bulgaria

The Precipitation of carbonate cements in the Pobitite Kamani area (Lower Eocene) began during early diagenesis of sediments. There is evidence, however, that calcite is still forming today.The negative ¹³C values to –29.2 suggest that the carbonate formed during degradation of ¹²C-enriched organic matter (perhaps partly from oxidation of methane). The ¹⁸O values of –0.9 to –1.6 reflect the marine origin of the early diagenetic carbonate cements. Most of the carbonates, however, formed during late diagenesis (at approximately 1300 m burial depth) and/or recently (after uplift) from percolating groundwaters. These carbonates have an isotopic composition characteristic of carbonates which precipitated from meteoric waters under normal sedimentary temperatures in isotopic equilibrium with ¹²C-enriched soil carbon dioxide.     

Late Quaternary palaeolimnology of a tropical marl lake: Wallywash Great Pond,Jamaica

Wallywash Great Pond (17° 57 N, 77° 48 W, 7 m a.s.l.) is the largest perennial lake in Jamaica. It occupies a fault trough within the karstic White Limestone. The Great Pond is a hardwater lake with a pH of 8.2–8.6 and an alkalinity of 3.6–3.9 meq 1^–1. Its chemistry is strongly influenced by the spring discharge from the limestone. The lake water is subject to degassing, evaporation and bicarbonate assimilation by submerged plants and algae, resulting in marl precipitation. A 9.23 m core (WGP2), taken from a water depth of 2.8 m, was analysed for magnetic susceptibility, loss-on-ignition, carbonate content, mole % MgCO₃ in calcite, and stable isotopes in the fine carbonate fraction. The chronology is based on ten¹⁴C and four U/Th dates. Four main sediment types alternate in the core: marl; organic, calcareous mud; organic mud or peat; and earthy, brown, calcareous mud. The marls represent periods of wet/warm climate during sea-level highstands and the organic deposits, shallower, swampy conditions. In contrast, the brown, calcareous muds were laid down when the lake was dry or ephemeral. The last interglacial (120 000- 106 000 yr BP) is represented by three distinct marl units. After a dry interval, stable, wet/warm conditions set in from 106 000 to 93 000 yr BP. A dry/cool climate prevailed between 93 000 and at least 9500 yr BP. Three subsequent cycles of alternating wet and dry conditions culminated in flooding of the basin by the Black River during the late Holocene. These recent events cannot be accurately dated by¹⁴C due to significant and temporally-variable inputs of dead carbon from the springs.     

Stability of outer planetary orbits around binary stars: A comparison of Hill's and Laplace's stability criteria

A comparison is made between the stability criteria of Hill and that of Laplace to determine the stability of outer planetary orbits encircling binary stars. The restricted, analytically determined results of Hill's method by Szebehely and co-workers and the general, numerically integrated results of Laplace's method by Graziani and Black are compared for varying values of the mass parameter =m ₂/(m ₁+m ₂). For 00.15, the closest orbit (lower limit of radius) an outer planet in a binary system can have and still remain stable is determined by Hill's stability criterion. For >0.15, the critical radius is determined by Laplace's stability criterion. It appears that the Graziani-Black stability criterion describes the critical orbit within a few percent for all values of .     

Experimental testing of relativistic effects,variability of the gravitational constant and topography of Mercury surface from radar observations 1964–1989

The new analysis of radar observations of inner planets for the time span 1964–1989 is described. The residuals show that Mercury topography is an important source of systematic errors which have not been taken into account up to now. The longitudinal and latitudinal variations of heights of Mercury surface were found and an approximate map of equatorial zone |?|≤120° was constructed. Including three values characterizing global nonsphericity of Mercury surface into the set of parameters under determination allowed to improve essentially all estimates. In particular, the variability of the gravitational constantG was evaluated: $$\dot G/G = (0.47 \pm 0.47) \times 10^{ - 11} yr^{ - 1} $$ . The correction to Mercury perihelion motion: $$\Delta \dot \pi = - 0''.017 \pm 0''.052 cy^{ - 1} $$ and linear combination of the parameters of PPN formalism: $$\upsilon = (2 + 2\gamma - \beta )/3 = 0.9995 \pm 0.0013$$ were determined; they are in a good agreement with General Relativity predictions. The obtained values Δ.π and ν correspond to the negligible solar oblateness, the estimate of solar quadrupole moment being: $$J_2 = ( - 0.13 \pm 0.41) \times 10^{ - 6} $$ .     

Masses of macroscopic quark configurations in metric and dynamic theories of gravitation

Within the bounds of the general relativity and in gravidynamics, spherically-symmetric configurations are considered with the limit equation of state (P = ( - 4B)/3) and with the density increasing to the center. It is shown that unlike GR, where the existence of strange stars only is permissible (u-, d-, s-quarks), in the consistent dynamic theory of gravitation the existence ofstable configuration withr ^–2 (quark star) is possible with a bag out of quark-gluon plasma which includes all possible quark flavors (u, d, s, c, b, t, .. .). The total mass of such a compact object with the bag of the radius of 10 km (whose surface consists of the strange self-bound matter) must be 6 - 7M .     

The inverse planetary problem: a numerical treatment

The so-called inverse planetary problem can be stated as follows: given the distances from the centre, masses, and radii of (say) three planets of a planetary system, find the optimum polytropic index, mass, and radius of their star, and also other quantities of interest, which depend either explicitly or implicitly on the foregoing ones (e.g., central and mean density, central and mean pressure, central and mean temperature, etc.). It is hereafter tacitly assumed that the system is opaque with respect to observations concerning periods of planetary otbits; hence, we cannot have any relevant estimates due to the well-known period laws. In the present paper, the inverse planetary problem is treated numerically on the basis of the so-called global polytropic model, developed recently by the first author.     

Solar activity in the sixteenth and seventeenth centuries (a revision)

Maximum relative sunspot numbers for the 16th and 17th century were computed by means of the dependence of the maximum relative sunspot numbers on the solar cycle rise time and on the cycle asymmetry. In these dependencies four separate modes of relations, two for odd and two for even cycles, were identified. These modes are coupled two and two in even-odd cycle pairs. The rise times and the asymmetries of solar cycles in the 16th and 17th centuries were taken from cycle extreme estimates by Schove (1979), from auroral and telescopic sunspot observations during this period, but with some necessary corrections. Annual relative sunspot numbers and decade averages were estimated from the cycle maxima and the epochs of extremes. In addition, the efficiency of auroral records in latitudes lower than 55 deg was computed for the time interval 1500–1868. For this purpose the dependence of occurrence numbers of aurorae on the cycle and decade means of the relative sunspot numbers was derived.     

The effect of non-thermal excitation and ionization on the hydrogen emission in impulsive solar flares

This is a quantitative investigation of the electron beam effect on the hydrogen line profiles and continuum intensity distribution during the impulsive phase of flares. The flaring atmosphere is suggested to be a hydrogenic one and its physical condition corresponds to the gas dynamics problem solution. The radiative transfer, steady-state and particle conservation equations are solved for the three-level hydrogen model atoms with continua. Return-current losses were neglected. Hydrogen line profiles are found to be slightly sensitive to nonthermal impacts with beam electrons in the cores and more sensitive in the wings. With the initial energy flux,F ₀, rising and energy spectral index, , decreasing, the wing intensities begin to increase, and the H lines are shown to have rather extended wings as is often observed. The hydrogen continua are shown to be strongly affected by nonthermal impacts. The bigger the value ofF ₀ and the smaller the value of , the greater absolute intensities of the hydrogen continua heads. This effect is more noticeable for the Balmer and Paschen continua. The head intensity slopes of them can be used for determination of these electron beam parameters on depths of the hydrogen emission origin and their following comparison with the same parameters for the coronal heights from the X-ray observations.     

Quasi-periodical structures in the galaxy populations: mass and luminosity functions for the cluster galaxies

A search and estimation of the statistical significance of the quasi-periodical structures (QPS) has been carried out: for the luminosity function of the galaxies in a few rich clusters; for the integrated mass function of galaxies in the superclusters identified via = 21 cm observations. Some statistically significant QPS have been revealed. The periods for these structures are in agreement between each other, at this basis the hypothesis has been proposed that an effect of the QPS at the level of galaxies has some universal character. Frequency doubling has been discovered for these QPS.