Stable isotope study of base metal deposits from the Eastern High Atlas,Morocco

Tertiary epigenetic lead ± zinc and copper mineralizations occur in the Mesozoic carbonate cover and stibnite, barite and copper mineralization in the Precambrian to Palaezoic basement in the Eastern High Atlas, Morocco. The carbon isotope data from host carbonates range from +3 to -1‰ PDB. The data are typical for marine carbon. There is no difference between surrounding dolomites and younger vein dolomites. The oxygen isotopic composition of the samples is enriched in ¹⁶O; the range is from -3 to -11‰ PDB with respect to that of carbonates in equilibrium with marine water. It is postulated that the isotopic composition was changed during dolomitization being caused by transition of connate formation waters diluted to some degree by meteoritic water. The bacteriogenically reduced sulphur from syngenetic sulphides and Mesozoic marine sulphate mobilized during Tertiary orogenesis are thought to be the source of H₂S and SO₄. Cambro-Ordovicien sulphate is also supposed to be the source of sulphur in the Jebel Zelmou barite deposit in the basement. Isotopic composition of lead from galenas in the Tertiary deposits from the Mesozoic cover are strikingly homogenous. Model ages vary between 230–180 Ma. It is suggested that important mobilization processes are responsible for Tertiary metallogeny in Morocco.

     

Electromagnetic studies in the central Arctic water basin

The results of the electromagnetic studies, obtained on the North Pole drifting stations, are reviewed. These results are still of current interest. The aspects of similar future works are discussed.     

The tectono‐stratigraphic evolution of the Austral Basin and adjacent areas against the background of Andean tectonics,southern Argentina,South America

The Austral Basin (or Magallanes Basin) in southern Argentina is situated in a highly active tectonic zone. The openings of the South Atlantic and the Drake Passage to the east and south, active subduction in the west, and the related rise of the Andes have massively influenced the evolution of this area. To better understand the impacts of these tectonic events on basin formation to its present‐day structure we analysed 2D seismic reflection data covering about 95 000 km² on‐ and 115 000 km² offshore (Austral ‘Marina’ and Malvinas Basin). A total of 10 seismic horizons, representing nine syn‐ and post‐ rift sequences, were mapped and tied to well data to analyse the evolution of sedimentary supply and depocenter migration through time. 1D well backstripping across the study area confirms three main tectonic stages, containing (i) the break‐up phase forming basement graben systems and the evolution of the Late Jurassic – Early Cretaceous ancient backarc Austral/Rocas Verdes Basin (RVB), (ii) the inversion of the backarc marginal basin and the development of the foreland Austral Basin and (iii) the recent foreland Austral Basin. Synrift sedimentation did not exceed the creation of accommodation space, leading to a deepening of the basin. During the Early Cretaceous a first impulse of compression due to Andes uplift caused rise also of parts of the basin. Controlling factors for the subsequent tectonic development are subduction, balanced phases of sedimentation, accumulation and erosion as well as enhanced sediment supply from the rising Andes. Further phases of rock uplift might be triggered by cancelling deflection of the plate and slab window subduction, coupled with volcanic activity. Calculations of sediment accumulation rates reflect the different regional tectonic stages, and also show that the Malvinas Basin acted as a sediment catchment after the filling of the Austral Basin since the Late Miocene. However, although the Austral and Malvinas Basin are neighbouring basin systems that are sedimentary coupled in younger times, their earlier sedimentary and tectonic development was decoupled by the Rio Chico basement high. Thereby, the Austral Basin was affected by tectonic impacts of the Andes orogenesis, while the Malvinas Basin was rather affected by the opening of the South Atlantic.     

Geochemistry of Suspended Matter from Waters of the Amazon Basin

The geochemical study of the suspended matter in the waters of the Amazon River and its tributaries revealed that the chemical composition of this material ranges widely; however, generally, it is similar to the average composition of the suspended matter in the rivers and clayey sedimentary rocks around the world. Against this background, an essential regional Hg enrichment due to the anthropogenic factor is distinguished. The suspensions from the so-called clear waters from the tributaries of the Amazon River—Xingu and Trombetas—demonstrate the local enrichment in Pb, Sn, Zn, and organic carbon indicating the ore mineralization of the drainage basin, and points to the presence of metal-organic complexes.     

High-resolution ion-microprobe measurement of lead isotopes: Variations within single zircons from Lac Seul,northwestern Ontario

Selected-area measurements of lead-isotope ratios in zircons have been made at high mass resolution using a modified A.E.I. IM20 ion-microprobe. At a working resolution of 3200 it is shown that the important interfering molecular peaks generated from the zircon matrix may be separated from atomic lead peaks. Corrections for overlapping peaks, which are necessary in measurements of lead isotopes at low mass resolution, are then only required for ²⁰⁸Pb.Measurements on N.B.S. standards show no isotope discrimination within counting statistics. Determination of ²⁰⁷Pb/²⁰⁶Pb on 29 single zircon grains from a tonalite gneiss and a granite from Lac Seul, northwestern Ontario, give very variable ratios with mean values close to those of bulk separates. Peaks in the distribution of 207/206 ratios obtained from the tonalite gneiss may be interpreted as evidence for two stages of lead loss. High 207/206 ratios are shown to be significant for at least two zircons and probably record a minimum age of formation of 3.3 ± 0.1 b.y. for the gneiss.     

The First Results of U–Pb Isotope Dating of Detrital Zircons from the Upper Mesoproterozoic Gulliksenfellet Quartzite (Southern Part of Wedel Jarlsberg Land,Southwest Spitsbergen)

The first results of U–Pb isotopic dating (LA–ICP–MS) of detrital zircons from metasedimentary rocks of the pre-Devonian basement of the SW part of western Spitsbergen (from Upper Mezoproterozoic Gulliksenfellet quartzite) showed ages ranging from 1700 ± 25 to 2948 ± 27 Ma.