Lower Paleozoic volcanic members have been investigated by geological, petrographical and geochemical means in a traverse across the Ossa-Morena Zone (OMZ) in south-west Spain.The volcanism lasted from the Early Cambrian to the Early Ordovician, with a peak in the Middle Cambrian. The volcanism is bimodal, starting up with acidic and ending with basic compositions. From north to south, peralkaline rhyolites change to rhyolites, and strongly enriched alkali basalts change via transitional basalts to mid-ocean ridge basalt (MORB-type basalts). The geological and magmatic evolution suggests an extensive Early Paleozoic rifting with its center along the southern boundary of the OMZ. Temporal, spatial and crustal aspects of the rifting event are presented in a geodynamic model. 相似文献
Springs located at the historical sites of Wadi Araba (Eastern Desert of Egypt) and emerging from the escarpments of the Northern and Southern Galala Plateaus were investigated. A combination of methods, including hydrochemistry, stable and radioisotope composition, and structural analyses based on satellite data, provided information about the structure of the subsurface and the derived groundwater flow paths. Satellite images reveal karst features within the northern plateau, e.g. conical landforms. Karstic caves were documented along both escarpments. Chemical analysis of floodwater from Wadi Araba indicates higher concentrations of terrestrial salts compared to floodwaters from central and southern parts of the desert. δ18O and δ2H signatures in spring waters resemble those of floodwater and fall on the global meteoric water line, confirming their fast infiltration with minor influence of evaporation. The aquifer feeding the springs of the Northern Galala Plateau has low retention and the springs dry out quickly, even after heavy rainfall. Contrastingly, 3H activities in springs emerging from the Southern Galala Plateau refer to much slower subsurface passage. With respect to 3H content (3.8 TU) in recent flood waters, the spring water at Southern Galala Plateau contains about 40% recently recharged groundwater. However, its largest spring—the St. Antony spring—discharges water with a radiocarbon age of about 15,000 years. In combination with this spring’s constant and high discharge over a period of several months, that age estimate suggests a large reservoir with moderate to high retention.
Hydrogeology Journal - The development of hydrogeology with respect to hard-rock and fractured-rock aquifers is described. The differences between porous aquifers and karst are explained, as well... 相似文献
Behaviour of Some Pharmaceuticals during Artificial Groundwater Recharge – Elimination and Effects on Microbiology The behaviour of bezafibrate, carbamazepine, clofibric acid, diclofenac, ibuprofen, and gemfibrozil during artificial groundwater recharge was investigated with different test systems simulating field conditions. The given concentrations of the pharmaceuticals were 100 μg/L in the influent of the systems. Concentrations in the influent as well as in the effluent were measured by GC‐MS. These column experiments indicated a significant elimination of bezafibrate, diclofenac, and ibuprofen (60 to 80%) during slow sand filtration. The results showed a moderate elimination of clofibric acid and gemfibrozil (40 to 60%) but a rather low elimination of carbamazepine (<40%). The adaptation times until the elimination processes started were about 5 days. Only the elimination of carbamazepine needed a lag phase up to 17 days. Additional column experiments with groundwater model systems indicated a high persistence of pharmaceuticals under aerobic and anaerobic groundwater conditions. The elimination was less than 20%. Only diclofenac was eliminated with rates between 60% and 80% in aerobic systems and between 40% and 60% in anaerobic systems. Analysis of eubacterial 16S‐rDNA by PCR and DGGE demonstrated changes in the microbial community structure in slow sand filters after application of pharmaceuticals. Adaptation processes may cause these changes, e.g. the appearance or disappearance of single species. Also differences between the populations of water and of the solid phase in slow sand filters could be demonstrated by DGGE pattern. 相似文献
In the framework of TREDER 's gravitational theory we elaborate the consequences of a class of field equations for some solar-system effects and their connection to the problem of cosmological singularity. These equations read on special conditions with components of the energy momentum tensor, KRONECKER 's symbol, tetrad components). ω is a real parameter. If we choose the integration constants of the static spherically symmetric vacuum case in such a way that red shift is the same like that of EINSTEIN 's theory and the source of gravitational field is that of a point mass we obtain for the perihelion rotation the expression is EINSTEINS value of the perihelion rotation.) For we obtain But only if ω > 2/5 cosmological models exist which have no cosmological singularity. On the other hand for ω > 2/5 the value is greater than. 相似文献
The origin of the nearly circular Colônia structure, located at the southwestern edge of the city of São Paulo, Brazil, has been the subject of a long‐standing debate, ever since the 1960s when the structure was first investigated by geophysical methods. The structure still raises interest for geological research, as its sedimentary infill holds important paleoclimatic information about the evolution of the tropical rainforest, as well as the interplay between the South American summer monsoon, the Intertropical Convergence Zone, and the southern Westerly wind belt—for possibly as long as several million years. In addition, the search for evidence to conclusively establish the origin of this structure continues, and the answer most likely lies in the lower portions of the basin's sedimentary infill, which also holds a significant potential for underground water resources. Here, we present the results from recent seismic (reflection and HVSR), gravimetric, and geoelectrical surveys. They have provided a reliable image of the sedimentary infill, and the maximum depth to basement within the structure has been constrained consistently by the different methods to approximately ?400 m. The geophysical data have also allowed to map the lateral contact between the crystalline basement rocks and the sedimentary infill, which indicates a diameter of approximately 2.8 km for the sedimentary basin, with 3.6 km being the diameter of the outermost limit of the structure. A total of six seismic stratigraphic boundaries were identified within the sedimentary infill, providing a framework for the planning of a deep drilling campaign and subsequent sampling program aimed at geological and paleoclimatology studies. 相似文献
Tektites are terrestrial natural glasses produced during a hypervelocity impact of an extraterrestrial projectile onto the Earth's surface. The similarity between the chemical and isotopic compositions of tektites and terrestrial upper continental crust implies that the tektites formed by fusion of such target rock. Tektites are among the driest rocks on Earth. Although volatilization at high temperature may have caused this extreme dryness, the exact mechanism of the water loss and the behavior of other volatile species during tektite formation are still debated. Volatilization can fractionate isotopes, therefore, comparing the isotope composition of volatile elements in tektites with that of their source rocks may help to understand the physical conditions during tektite formation.For this study, we have measured the Zn isotopic composition of 20 tektites from four different strewn fields. Almost all samples are enriched in heavy isotopes of Zn compared to the upper continental crust. On average, the different groups of tektites are isotopically distinct (listed from the isotopically lightest to the heaviest): Muong-Nong type indochinites (δ66/64Zn = 0.61 ± 0.30‰); North American bediasites (δ66/64Zn = 1.61 ± 0.49‰); Ivory Coast tektites (δ66/64Zn = 1.66 ± 0.18‰); the Australasian tektites (others than the Muong Nong-type indochinites) (δ66/64Zn = 1.84 ± 0.42‰); and Central European moldavites (δ66/64Zn = 2.04 ± 0.19‰). These results are contrasted with a narrow range of δ66/64Zn = 0–0.7‰ for a diverse spectrum of upper continental crust materials.The elemental abundance of Zn is negatively correlated with δ66/64Zn, which may reflect that isotopic fractionation occurred by evaporation during the heating event upon tektite formation. Simple Rayleigh distillation predicts isotopic fractionations much larger than what is actually observed, therefore, such a model cannot account for the observed Zn isotope fractionation in tektites. We have developed a more realistic model of evaporation of Zn from a molten sphere: during its hypervelocity trajectory, the molten surface of the tektite will be entrained by viscous coupling with air that will then induce a velocity field inside the molten sphere. This velocity field induces significant radial chemical mixing within the tektite that accelerates the evaporation process. Our model, albeit parameter dependent, shows that both the isotopic composition and the chemical abundances measured in tektites can be produced by evaporation in a diffusion-limited regime. 相似文献
A new IRSL dataset is presented for the age and setting of a critical Late Glacial Maximum tephra isochron marker. The rhyolitic tephra, known as the Kawakawa Tephra, occurs as a 14 cm thick layer within a 5.9 m thick loess section overlying alluvial gravels in the Rangitikei River valley, SW North Island of New Zealand. Ages range from 21 at the base to 5 ka near the top of the loess and bracket an age of 17.0 ± 2.2 for the tephra. The new IRSL ages are in agreement with published and unpublished luminescence ages from other localities of loess, sand and ash above and below the tephra and of the tephra itself, that indicate an age of ca. 19 ka for the Kawakawa Tephra. This age is considerably younger than the generally accepted 14C 27.1 ka cal yrs BP age of the Kawakawa Tephra and highlights an unresolved discrepancy between the two dating systems. 相似文献
Ocean Dynamics - Our understanding of the marine ecosystem is expressed in our ability to predict ecological processes. Several approaches are compared to make such predictions on plankton... 相似文献