Temperature dependence of the water-ice spectrum between 1 and 4 microns: Application to Europa,Ganymede and Saturn's rings

Reflection spectra of water ice from 1 to 4 μm are presented as a function of temperature. It is found that a feature at 6056 cm^?1 changes its intensity sufficiently that it can be used as a spectroscopic measure of the ice temperature. A temperature calibration curve of this feature down to 55 K is developed and is used to determine ice temperatures for the Galilean satellites Europa (95±10 K), Ganymede (103±10 K), and the rings of Saturn (80±5 K). The ice temperatures for the Galilean satellites are lower than their measured brightness temperatures, which can be explained by a higher albedo of the ice covered regions relative to the rest of the satellite and possibly a concentration of the ice near the polar caps.     

Sulphate-related equilibria in the hypersaline brines of the Tyro and Bannock Basins, eastern Mediterranean

The Tyro and Bannock Basins, which are depressions in the eastern Mediterranean, contain hypersaline anoxic brines. These brines are of different composition: Tyro brine is primarily an early-stage halite (NaCl) brine, whereas Bannock brine includes the more soluble ions of late-stage evaporite minerals. Accordingly, the Bannock brine contains a much greater sulphate concentration than the Tyro Brine. This difference in sulphate concentration is reflected in the concentrations of ions such as Ca, Sr and Ba, which form sparingly soluble sulphate minerals.Equilibrium calculations using the Pitzer specific ion interaction model indicate that the brines in both basins are saturated with respect to gypsum (CaSO₄-2H₂O) and supersaturated to saturated with respect to dolomite (CaMg(CO₃)₂). The degree of saturation with respect to dolomite is greater in the Bannock Basin than it is in the Tyro Basin. Correspondingly, recent gypsum crystals and dolomite hardgrounds have been found in the Bannock Basin but not in the Tyro Basin.The Tyro brine is homogeneous in composition, whereas the Bannock brine demonstrates a clear two-layer brine structure. At the interface of the upper and the lower brine distinct positive anomalies occur in the total alkalinity and the concentration of phosphate, and negative anomalies occur in the concentrations of Mn²⁺ and the rare earth elements (REE). These anomalies and the observed association of gypsum/dolomite in the sediments are all consistent with a recent precipitation of dolomite and gypsum in the Bannock Basin. The brines in both basins are also saturated with respect to barite (BaSO₄).The ⁸⁷Sr/⁸⁶Sr and δ³⁴S ratios of the Bannock brines are amazingly consistent but differ dramatically from the values for modern or Messinian-age seawater. The Sr concentration and Sr and S isotope ratios in the gypsum crystals indicate that most of these crystals have resulted from precipitation/recrystallization from the brine and not from seawater. The observed variations between crystals are thought to reflect the recrystallization of (sub-) outcropping Messinian gypsum with a low ⁸⁷Sr/⁸⁶Sr ratio in the presence of seawater or brine fluids and with different extents of diagenesis.     

Biogeochemistry of surface sediments off Concepción (∼36°S), Chile: El Niño vs. non-El Niño conditions

We compared the signals of several water column properties (upwelling intensity, sea level anomaly, temperature, nutrients, dissolved oxygen, chlorophyll-a, and surface sediments) of the continental shelf off Concepción (36°S) during the 1997-1998 El Niño with those of a normal year (2002-2003). We found that the primary hydrographic effect of El Niño 1997-1998 was a reduction in the input of nutrient-rich, oxygen-poor Equatorial Subsurface Water over the shelf. This affected the biology of the water column, as evidenced by the reduced phytoplankton biomass. Surface sediment properties (biogenic opal, organic carbon, bulk δ¹⁵N) observed during El Niño 1997-1998 reflected a reduced export production and the sediments failed to show the water column seasonality that occurs under normal conditions. In addition, weakened denitrification and/or upper water column fertilization could be inferred from the sedimentary δ¹⁵N. Although diminished, export production was preserved in the surface sediments, revealing less degraded organic matter in the upwelling period of the El Niño year than in the normal year. We suggest that the fresher organic material on the seafloor was probably associated with a severe reduction in the polychaete Parapronospio pinnata, which is considered to be the most important metazoan remineralizer of organic carbon at the sediment-water interface in the study area.     

The Spatial Distribution of Gaseous Atomic Sodium in the Comae of Comets: Evidence for Direct Nucleus and Extended Plasma Sources

Sodium D-line emission (5890 and 5896 Å) has been observed in bright comets at small to moderate heliocentric distances for many years. We present here the first in depth study of a set of spatial profiles of the sodium D-line emission constructed from long-slit spectroscopic observations of Comets Bennett C/1969 Y1, Kohoutek C/1973 D1, and 1P/Halley. Preliminary analysis of these data lead to the suggestion by Combiet al.(1996,A Plasmagenic Source for Gaseous Sodium in Comets.Presented at Asteroids, Comets, Meteors) that a major fraction of the gaseous sodium was produced by an extended source in the tail and that the source was likely to be some charged species. Dissociative recombination of a molecular ion was suggested. The spatial profiles of sodium are not like typical neutral species. The inner region from the nucleus (<2 × 10⁴km) can be explained in terms of a model that accounts for collisional entrainment in the expanding coma and the heliocentric velocity dependent fluorescence rate and radiation pressure acceleration. This source comes either directly from the nucleus or has a very short-lived parent (?10³s). Away from the nucleus, down the tail and to the sides, the spatial profile slope flattens, indicating a second extended source. The striking similarity of the extended region of sodium spatial profiles with those of ions (H₂O⁺), both along and perpendicular to the tail, is highly suggestive that an ion source is responsible for the production of the extended component of gaseous sodium in the coma. The production rate of the highly variable extended source when present is four to five times that of the direct nucleus source. Observations (Schneideret al., 1991,Science253,1394–1397) and quantitative model analyses (Wilson and Schneider, 1994,Icarus111,31–34) have shown that a dissociative recombination of a sodium bearing molecular ion (NaX⁺) produces a peculiar component of the neutral sodium near Io. It displays a variable spatial morphology consistent with that of a molecular ion source “picked-up” in the plasma torus corotating with Jupiter's magnetic field. The rapid onset of the appearance of gaseous sodium in bright comets, its spatial distribution in the extended coma and near tail, and recent observations of sodium tails are all consistent with our original suggestion of this plasma source for sodium in comets.     

Determination of inorganic sulphur speciation with polarographic techniques: Some preliminary results for recent hypersaline anoxic sediments

Polarographic techniques have been used to determine reduced inorganic sulphur speciation in recent anoxic marine sediments from two hypersaline basins, the Tyro and the Bannock Basins, in the Eastern Mediterranean. The following phases were determined: acid volatile sulphur (AVS), pyritic sulphur and zerovalent sulphur. The determination of AVS and pyrite was based respectively on the acidification and Cr(II) reduction of these sulphur components to H₂S. H₂S was collected in base and the sulphide concentration was measured by polarography. Standard Na₂S and pyrite gave recoveries of 99.6% ± 3.9% and 97% ± 12% respectively. Total zerovalent sulphur in a sediment sample was measured by the reaction of sulphite with thiosulphate. Thiosulphate was measured directly by polarography.

Pyrite is the main phase of inorganic reduced sulphur in the sediments from the Tyro and the Bannock Basins, and it has about the same average level (125 υmoles per gramme dry weight) in the cores recovered from the two areas. However, the distribution of pyrite in the top 100 cm of the two cores differs significantly. In the Bannock Basin a sharp increase is observed with depth, whereas in the Tyro Basin there is a small decrease with depth.

The total amount of reduced inorganic sulphur is less than the total amount of sulphur in the sediments. This indicates that there must be additional sulphur-bearing phases. One of these phases may be gypsum, and indeed, gypsum crystals have been observed in the Bannock Basin.

In neither basin is there a significant correlation between reduced sulphur and organic carbon. The pyrite that occurs in these basins may have been formed syngenetically at the interface of the anoxic brine and oxic seawater. Diagenetic pyrite may have been formed within the sediments of the basins. AVS and total zerovalent sulphur are still observed at depth. We therefore suggest that this may be due to the incomplete transformation of AVS and zerovalent sulphur into pyrite.     

Burial and degradation of Rena oil within coastal sediments of the Bay of Plenty

ABSTRACT

During the Rena oil spill, no data existed for New Zealand conditions on the likely depth of burial and the expected degradation of oil deposited on sandy beaches. Sediment cores were taken from 12 locations along the Bay of Plenty coastline c. 1 year after the Rena oil spill. No visible oil was detected in cores and trenches dug within the beaches. Chemical extraction was performed on 20?cm slices from the upper 40?cm of 26 cores, and the elutriates were analysed for the presence of polycyclic aromatic hydrocarbons (PAHs). The results were compared with known PAH fingerprints of Rena oil and its degradation products. Only seven samples contained some marker PAHs, and none had a complete Rena profile, indicating stormwater contamination. Despite extensive deposition of Rena oil on beaches, no evidence of ongoing contamination could be located, indicating that the clean-up and degradation were effective at removing the oil.