The melt rocks of the Vredefort impact structure - Vredefort Granophyre and pseudotachylitic breccias: Implications for impact cratering and the evolution of the Witwatersrand Basin

The unique combination of its large size (250-300 km diameter), deep levels of erosion (>7 km), and widespread regional mining activity make the Vredefort impact structure in South Africa an exceptional laboratory for the study of impact-related deformation phenomena in the rocks beneath giant, complex impact craters. Two types of impact-generated melt rock occur in the Vredefort Structure: the Vredefort Granophyre - impact melt rock - and pseudotachylitic breccias. Along the margins of the structure, mining and exploration drilling in the Witwatersrand goldfields has revealed widespread fault-related pseudotachylitic breccias linked to the impact event. There, volumetrically limited melt breccia occurs in close association with cataclasite or mylonitic zones associated with bedding-parallel normal dip-slip faults that formed during inward slumping of the crater walls, and in rare subvertical faults oriented radially to the center of the structure. This association is consistent with formation of pseudotachylites by frictional melting. On the other hand, rocks in the Vredefort Dome - the central uplift of the impact structure - contain ubiquitous melt breccias that range in size from sub-millimeter pods and veinlets to dikes up to tens of meters wide and hundreds of meters long. Like fault-related pseudotachylites in the goldfields and elsewhere in the world, they display a close geochemical relationship to their wallrocks, indicating local derivation. However, although mm/cm- to, rarely, dm-scale offsets are commonly found along their margins, they do not appear to be associated with broader fault zones, are commonly considerably more voluminous than most known fault-related pseudotachylites, and show no consistent relationship between melt volumes and slip magnitude. Recent petrographic observations indicate that at least some of these melt breccias formed by shock melting, with or without frictional melting. Consequently, the non-genetic term “pseudotachylitic breccia” has been adopted for these Vredefort occurrences. These breccias formed during the impact in rocks at temperatures ranging from greenschist to granulite facies, and were subsequently annealed to varying degrees during cooling of the central uplift.In addition to the pseudotachylitic breccias, nine clast-laden impact melt dikes (Vredefort Granophyre), each up to several kilometers long, occur in vertical radial and tangential fractures in the Vredefort Dome. Unlike the pseudotachylitic breccias, they display a remarkably uniform bulk composition and clast populations that are largerly independent of their wallrocks, and they contain geochemical traces of the impactor. They represent intrusive offshoots of the homogenized impact melt body that originally lay within the crater. U-Pb single zircon and Ar-Ar dating indicates that the Vredefort Granophyre and pseudotachylitic breccias, and the Witwatersrand pseudotachylites all formed at 2020±5 Ma - the age of the impact event, making the breccias a convenient time marker in the evolution of the structurally complex Witwatersrand basin with its unique gold deposits.     

The Impact of Sediment and Carbon Fluxes on the Biogeochemistry of Methane and Sulfur in Littoral Baltic Sea Sediments (Himmerfjärden, Sweden)

Three sediment stations in Himmerfjärden estuary (Baltic Sea, Sweden) were sampled in May 2009 and June 2010 to test how low salinity (5–7 ‰), high primary productivity partially induced by nutrient input from an upstream waste water treatment plant, and high overall sedimentation rates impact the sedimentary cycling of methane and sulfur. Rates of sediment accumulation determined using ²¹⁰Pb_excess and ¹³⁷Cs were very high (0.65–0.95 cm?year^?1), as were the corresponding rates of organic matter accumulation (8.9–9.5 mol C?m^?2?year^?1) at all three sites. Dissolved sulfate penetrated <20 cm below the sediment surface. Although measured rates of bicarbonate methanogenesis integrated over 1 m depth were low (0.96–1.09 mol?m^?2?year^?1), methane concentrations increased to >2 mmol?L^?1 below the sulfate–methane transition. A steep gradient of methane through the entire sulfate zone led to upward (diffusive and bio-irrigative) fluxes of 0.32 to 0.78 mol?m^?2?year^?1 methane to the sediment–water interface. Areal rates of sulfate reduction (1.46–1.92 mol?m^?2?year^?1) integrated over the upper 0–14 cm of sediment appeared to be limited by the restricted diffusive supply of sulfate, low bio-irrigation (α?=?2.8–3.1 year^?1), and limited residence time of the sedimentary organic carbon in the sulfate zone. A large fraction of reduced sulfur as pyrite and organic-bound sulfur was buried and thus escaped reoxidation in the surface sediment. The presence of ferrous iron in the pore water (with concentrations up to 110 μM) suggests that iron reduction plays an important role in surface sediments, as well as in sediment layers deep below the sulfate–methane transition. We conclude that high rates of sediment accumulation and shallow sulfate penetration are the master variables for biogeochemistry of methane and sulfur cycling; in particular, they may significantly allow for release of methane into the water column in the Himmerfjärden estuary.     

Delineation of spatial-temporal patterns of groundwater/surface-water interaction along a river reach (Aa River,Belgium) with transient thermal modeling

Among the advances made in analytical and numerical analysis methods to quantify groundwater/surface-water interaction, one methodology that stands out is the use of heat as an environmental tracer. A large data set of river and riverbed temperature profiles from the Aa River in Belgium has been used to examine the spatial-temporal variations of groundwater/surface-water interaction. Exchange fluxes were calculated with the numerical heat-transport code STRIVE. The code was applied in transient mode to overcome previous limitations of steady-state analysis, and allowed for the calculation of model quality. In autumn and winter the mean exchange fluxes reached ?90 mm d^?1, while in spring and early summer fluxes were ?42 mm d^?1. Predominantly gaining conditions occurred along the river reach; however, in a few areas the direction of flow changed in time. The river banks showed elevated fluxes up to a factor of 3 compared to the center of the river. Higher fluxes were detected in the upstream section of the reach. Due to the influence of exchange fluxes along the river banks, larger temporal variations were found in the downstream section. The exchange fluxes at the river banks seemed more driven by variable local exchange flows, while the center of the river was dominated by deep and steady regional groundwater flows. These spatial and temporal differences in groundwater/surface-water exchange show the importance of long-term investigations on the driving forces of hyporheic processes across different scales.     

Long-term variability of temperature and precipitation in the Czech Lands: an attribution analysis

Among the key problems associated with the study of climate variability and its evolution are identification of the factors responsible for observed changes and quantification of their effects. Here, correlation and regression analysis are employed to detect the imprints of selected natural forcings (solar and volcanic activity) and anthropogenic influences (amounts of greenhouse gases—GHGs—and atmospheric aerosols), as well as prominent climatic oscillations (Southern Oscillation—SO, North Atlantic Oscillation—NAO, Atlantic Multidecadal Oscillation—AMO) in the Czech annual and monthly temperature and precipitation series for the 1866–2010 period. We show that the long-term evolution of Czech temperature change is dominated by the influence of an increasing concentration of anthropogenic GHGs (explaining most of the observed warming), combined with substantially lower, and generally statistically insignificant, contributions from the sulphate aerosols (mild cooling) and variations in solar activity (mild warming), but with no distinct imprint from major volcanic eruptions. A significant portion of the observed short-term temperature variability can be linked to the influence of NAO. The contributions from SO and AMO are substantially weaker in magnitude. Aside from NAO, no major influence from the explanatory variables was found in the precipitation series. Nonlinear forms of regression were used to test for nonlinear interactions between the predictors and temperature/precipitation; the nonlinearities disclosed were, however, very weak, or not detectable at all. In addition to the outcomes of the attribution analysis for the Czech series, results for European and global land temperatures are also shown and discussed.     

The year-long unprecedented European heat and drought of 1540 – a worst case

The heat waves of 2003 in Western Europe and 2010 in Russia, commonly labelled as rare climatic anomalies outside of previous experience, are often taken as harbingers of more frequent extremes in the global warming-influenced future. However, a recent reconstruction of spring–summer temperatures for WE resulted in the likelihood of significantly higher temperatures in 1540. In order to check the plausibility of this result we investigated the severity of the 1540 drought by putting forward the argument of the known soil desiccation-temperature feedback. Based on more than 300 first-hand documentary weather report sources originating from an area of 2 to 3 million km², we show that Europe was affected by an unprecedented 11-month-long Megadrought. The estimated number of precipitation days and precipitation amount for Central and Western Europe in 1540 is significantly lower than the 100-year minima of the instrumental measurement period for spring, summer and autumn. This result is supported by independent documentary evidence about extremely low river flows and Europe-wide wild-, forest- and settlement fires. We found that an event of this severity cannot be simulated by state-of-the-art climate models.     

Recent ecological responses to climate variability and human impacts in the Nianbaoyeze Mountains (eastern Tibetan Plateau) inferred from pollen,diatom and tree-ring data

The Tibetan Plateau is a region that is highly sensitive to recent global warming, but the complexity and heterogeneity of its mountainous landscape can result in variable responses. In addition, the scarcity and brevity of regional instrumental and palaeoecological records still hamper our understanding of past and present patterns of environmental change. To investigate how the remote, high-alpine environments of the Nianbaoyeze Mountains, eastern Tibetan Plateau, are affected by climate change and human activity over the last ~600 years, we compared regional tree-ring studies with pollen and diatom remains archived in the dated sediments of Dongerwuka Lake (33.22°N, 101.12°E, 4,307 m a.s.l.). In agreement with previous studies from the eastern Tibetan Plateau, a strong coherence between our two juniper-based tree-ring chronologies from the Nianbaoyeze and the Anemaqin Mountains was observed, with pronounced cyclical variations in summer temperature reconstructions. A positive directional trend to warmer summer temperatures in the most recent decades, was, however, not observed in the tree-ring record. Likewise, our pollen and diatom spectra showed minimal change over the investigated time period. Although modest, the most notable change in the diatom relative abundances was a subtle decrease in the dominant planktonic Cyclotella ocellata and a concurrent increase in small, benthic fragilarioid taxa in the ~1820s, suggesting higher ecosystem variability. The pollen record subtly indicates three periods of increased cattle grazing activity (~1400–1480 AD, ~1630–1760 AD, after 1850 AD), but shows generally no significant vegetation changes during past ~600 years. The minimal changes observed in the tree-ring, diatom and pollen records are consistent with the presence of localised cooling centres that are evident in instrumental and tree-ring data within the southeastern and eastern Tibetan Plateau. Given the minor changes in regional temperature records, our complacent palaeoecological profiles suggest that climatically induced ecological thresholds have not yet been crossed in the Nianbaoyeze Mountains region.     

Decadal windstorm activity in the North Atlantic-European sector and its relationship to the meridional overturning circulation in an ensemble of simulations with a coupled climate model

The relationship between decadal variations in the North Atlantic meridional overturning circulation (MOC) and North Atlantic/Western European windstorm activity during the extended winter season is studied. According to an ensemble of three 240-year long simulations performed with the ECHAM5-MPIOM model, periods of high decadal windstorm activity frequently occur in the years following a phase of weak MOC (i.e. when the MOC starts to recover). These periods are characterised by a distinctive pattern in the mixed layer ocean heat content (OHC). A positive anomaly is located in the region 45°N?52°N/35°W?16°W (west of France). Negative anomalies are located to the North and South. The signal can be detected both in the heat content of the oceanic mixed layer and in the sea surface temperatures. Its structure is consistent with anomalously enhanced baroclinic instability in the region with the strong negative OHC gradient (30°W?10°W/45°N?60°N), which eventually produces a higher probability of windstorms.