硫化物固—液界面电化学效应实验探讨

硫化物作为一类重要的常见矿物，目前国内外对其表面矿物学特征研究有限。具体到硫化物固－液界面处的行为机理，前人的研究程度就更低了。笔者自行设计了一个Fe1-xS-Cr^6 原电池，通过实测电动势（E），t-E关系曲线，溶液可见光吸收谱及其λ－A关系曲线，阐明硫化物与Cr^6＋溶液间的界面行为机理。认为其界面行为过程为；硫化物溶解→离子反应（氧化还原）→吸附Cr^3 。该原电池与一般原电池结构不同，其主要差别在于将反应电极和测量电极分开，从而解决电极反应过程中的浓度极化问题，提高了电化学实验的精度。该研究成果有助于揭示矿物－液体相互作用机理，完善和丰富表面矿物学研究内容，深化化界面成矿理论，并对环境治理，矿物材料应用等开发领域具有重要的参考价值。     

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and light-rare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positiveεNd(t) values (039-4.08), implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.     

测井数据滑动窗关联维计算和沉积学分析

应用滑动窗关联维计算方法对鲁北济阳坳陷某钻井剖面石炭系—二叠系陆表海沉积层段GR测井响应数据进行了分形维数计算,结果表明海侵体系域关联维数一般较小,且维数曲线振荡变化较弱,而高水位体系域则相反。这与海侵体系域形成时海平面上升的主控因素压制或掩盖了其他因素的显现有关,同时也证明测井序列分形分析能从另一个新的视角观察识别测井序列中所包含的地质信息。随着分形方法应用研究的不断开展,必将从测井数据中挖掘出更多的有用信息,指导油气等资源勘探与开发,丰富及完善测井地质学理论。相信将来分形会成为地质数据分析的标准工具。     

歧口凹陷古近纪东营期古物源体系重建与应用

以沉积盆地分析、层序地层研究和油气勘探实践中急待解决的古物源体系分析为切入点, 以歧口凹陷东营组研究为例, 阐述了古物源体系研究的途径、方法与技术路线; 初步总结出应用轻-重矿物时空配置关系、地震前积反射结构特征、古地貌恢复与沟谷展布特征、盆地内部骨架砂体形态与时空配置以及盆地边缘及内部层序界面上大型下切谷的空间展布特征, 即“五位合一”法来判断沉积盆地的古物源体系.该分析方法可为同领域的研究提供借鉴作用.      

成都经济区农业生态系统土壤镉通量研究

以四川成都经济区农业生态系统中的重金属Cd为对象,对其在土壤中的输入输出通量进行初步探索。综合各方面的因素,确定以大气干湿沉降、灌溉水、化肥为输入途径和农作物为输出途径进行研究。经过计算,经济区大气干湿沉降通量平均值为17.76g/hm2·a,灌溉水和化肥通量明显较低,三者对土壤Cd污染的贡献率分别为86%、10%和4%。对于6个不同的地区,三者比例略有差别,大气干湿沉降所占比例最高达94%,最低也达到了77%。Cd通过农作物收割输出的量相对较小。土壤Cd年净增量主要受大气干湿沉降的制约,因此大气环境质量应是重点监控的对象。以耕作土体为研究介质,经估算,当前的Cd年平均通量可引起土壤Cd的质量分数升高0.006mg/kg。     

EGM96和EGM2008地球重力场模型计算弹道扰动引力的比较

给出了利用地球重力场模型计算扰动引力以及重力场模型截断误差的公式,计算了36阶、360阶、2 160阶地球重力场模型在径向和水平方向的截断误差,并对36阶、360阶的EGM96和EGM2008重力场模型计算的弹道扰动引力矢量进行了分析和比较.结果表明,采用重力场模型计算扰动引力时,模型阶数和弹道点的高度越低,模型截断误差越大;EGM96和EGM2008模型的一致性随着模型阶数的升高而逐渐降低.总体来看,EGM2008模型的精度要好于EGM96模型.     

Tectonic Units and Their Fundamental Characteristics on the Northern Margin of the Alxa Block

The northern margin of the Alxa block is the junction of a tectonic units. Four first-order tectonic units are distinguished: 1. the Yagan structural zone characteristic of an immature island arc; 2. the Zhusileng-Hangwula structural zone, which was a passive continental margin in the Early Palaeozoic and was transformed into an active continental margin in the Late Palaeozoic;3. the Shalazha structural zone characteristic of a mature island arc; 4. the Nuru-Langshan structural zone, which was a Proterozoic orogenic belt and later evolved into an extensional transtional crust in the Palaeozoic. The above-mentioned tectonic units differ remarkably in sedimentary formations, magmatic rock associations, metamorphism and geochemistry and are bounded by faults between one another.     

印度洋热含量在南海夏季风爆发中的作用

利用Scripps海洋研究所0—400m上层海洋热含量资料和美国环境监测中心/国家大气研究中心(National Centers for Environmental Prediction/National Center for Atmospheric Research,NCEP/NCAR)的再分析资料,运用经验正交分解(empirical orthogonal function,EOF)等统计方法,研究在有ENSO影响和去除ENSO影响的情况下,前期春季印度洋热含量如何影响南海夏季风爆发。结果表明,在没有扣除ENSO信号的情况下,热带印度洋热含量EOF分解第一模态呈东西相反变化的空间分布。印度洋东部热含量为正(负)异常、西部为负(正)异常时,南海夏季风爆发较早(晚),印度洋上层热含量主要通过影响热带印度洋上空大气的垂直运动和高低层辐散辐合,进而影响季风纬向环流的强弱,来影响南海夏季风爆发的早晚。在扣除ENSO信号的情况下,印度洋热含量CEOF(conditional EOF)第一模态的空间分布类似于EOF第一模态的空间分布;第二模态表现为除小部分海区外,热带印度洋热含量呈一致变化的海盆模态。这两个模态对南海夏...     

Estimates of global M_2 internal tide energy fluxes using TOPEX/POSEIDON altimeter data

TOPEX/POSEIDON altimeter data from October 1992 to June 2002 are used to calculate the global barotropic M2 tidal currents using long-term tidal harmonic analysis. The tides calculated agree well with ADCP data obtained from the South China Sea (SCS). The maximum tide velocities along the semi-major axis and semi-minor axis can be computed from the tidal ellipse. The global distribution of M2 internal tide vertical energy flux from the sea bottom is calculated based on a linear internal wave generation model. The global vertical energy flux of M2 internal tide is 0.96 TW, with 0.36 TW in the Pacific, 0.31 TW in the Atlantic and 0.29 TW in the Indian Ocean, obtained in this study. The total horizontal energy flux of M2 internal tide radiating into the open ocean from the lateral boundaries is 0.13 TW, with 0.06 TW in the Pacific, 0.04TW in the Atlantic, and 0.03 TW in the Indian Ocean. The result shows that the principal lunar semi-diurnal tide M2 provides enough energy to maintain the large-scale thermohaline circulation of the ocean.