A first approach to calculate BIOCLIM variables and climate zones for Antarctica

Theoretical and Applied Climatology - For testing the hypothesis that macroclimatological factors determine the occurrence, biodiversity, and species specificity of both symbiotic partners of...     

Heterogeneous response of hydrogeological systems to the Izmit and Düzce (Turkey) earthquakes of 1999

At four sites in Turkey and Armenia the physico-chemical properties of thermal and mineral waters were monitored continuously during the Izmit and Düzce earthquakes that occurred along the North Anatolian fault in August and November 1999. The epicentral distances between the moment magnitude (M_w) 7.6 Izmit earthquake and the monitoring locations were 313, 488, 1,161, and 1,395 km. At the most distant site, the specific electrical conductivity of mineral water from a flowing artesian well dropped co-seismically and postseismically by 7%. No changes were observed at the other sites, although the estimated earthquake strains and peak ground accelerations are much higher. A similar pattern was observed after the Düzce earthquake, which happened three months after the Izmit event. The response of a hydrogeological system seems to depend on the site characteristics rather than on the nature of the earthquake. A hydrogeological model for the sensitive observation site farthest from the Izmit earthquake explains the observations in terms of a changed mixing ratio between two fluid components. Passing seismic waves may trigger a local pore-pressure increase according to the mechanism of advective overpressure. The preconditions for this mechanism, free gas bubbles in the aquifer in combination with a trap for rising bubbles, is probably not fulfilled by the other groundwater systems. Electronic Publication     

Quantification of groundwater discharge into lakes using radon-222 as naturally occurring tracer

A case study was carried out with the aim to practically test whether estimates of groundwater discharge rates into dredging lakes can be made via an uncomplicated and straightforward technique using radon-222 as naturally-occurring groundwater tracer. Lake Ammelshainer See, a dredging, seepage lake, approximately 25 km east of Leipzig, Germany, was chosen as the investigation site. In order to evaluate changes in the spatial and temporal radon-222 patterns in the lake during different stages of stratification, sampling campaigns were conducted in April 2007 (well mixed stage) and in May 2007 (thermal stratification stage). Groundwater flow estimates were made using a radon mass balance approach accounting for all radon fluxes into and out of the lake and assuming steady-state conditions with respect to these radon fluxes. Once all positive and negative radon fluxes related to the lake water volume were determined, groundwater discharge was estimated by using the advective radon input and the radon activity concentration of the pore water as key parameters. The results showed that in case of a lake with a size and shape of Lake Ammelshainer See (530,000 m²) reasonable groundwater discharge estimates can be made by collection and analyzing just a few water samples and a few samples from the sediment layer.     

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.     

Single-crystal structure and Raman spectroscopy of synthetic titanite analog CaAlSiO<Subscript>4</Subscript>F

Synthetic CaAlSiO₄F, the Al-F analog of titanite, has been investigated using single-crystal synchrotron diffraction experiments at Beamline X06DA (Swiss Light Source, Paul Scherrer Institute, Villigen, Switzerland) and Raman spectroscopy. The presented structural model with 40 parameters was refined against 506 unique reflections to a final R _{o b s} of 0.026 (space group A2/a, a = 6.9120(11), b = 8.5010(10), c = 6.435(2) Å, β = 114.670(11)°, and Z = 4) and exhibits less distorted coordination polyhedra than earlier models from powder data. Vibrational spectra were calculated in harmonic approximation at the Γ point from fully relaxed energy optimisations of the crystal structure, using 3D-periodic density functional theory with Gaussian basis sets and the software CRYSTAL06. The lattice parameters of the fully relaxed structure were in good agreement with the experimental values, with the calculated values 0.8 ± 0.4 % too large; the monoclinic angle was calculated 0.4° too large. The agreement of the calculated Raman frequencies with the observed ones was very good, with standard deviation ±3 cm^?1 and maximum deviations of ±7 cm^?1. Furthermore, a detailed discussion of the atomic displacements associated with each Raman mode is given.     

Winter climate anomalies in Europe and their associated circulation at 500 hPa

Regional anomalies of the surface climate over Europe are defined by a simultanous EOF-analysis of the normalized monthly mean sea level pressure, temperature and precipitation fields of 100 winters (December–February, 1887–1986) at 40 stations. The monthly amplitudes of the first EOF (about 25% of the total variance) are used as an index for the monthly winter climate anomaly. They characterize a high (low) pressure cell over central Europe associated with a positive (negative) temperature and precipitation anomaly over northern (central-southern) Europe as indicated by a northward (southward) shift of the tail end of the cross-Atlantic cyclone track. These patterns resemble the phenomenological anticyclonic (cyclonic) Grosswetter classification and the European blocking (enhanced zonal flow) regime. The second EOF is of similar magnitude and gives latitudinal corrections to these two basic flow regimes. The joint probability distribution of both amplitudes shows a weak bimodality mainly associated with the first EOF. Further insight into the underlying physical processes of the climate anomaly patterns in Europe is obtained from the extended Eliassen-Palm flux diagnostics of the barotropic transient eddy-mean flow interaction (Hoskins et al. 1983) and the stationary wave propagation (Plumb 1985). The diagnostics confined to the barotropic components and applied to the regression and the composite anomaly fields of the transient and stationary eddy flows of the 500 hPa geopotential (1946–87, north of 20°N) leads to the following results: (1) The bandpass filtered transient eddy variances of the 500 hPa geopotential show a shift of the cross-Atlantic storm track: In high (low) pressure situations over Europe the cross-Atlantic storm track intensity is enhanced (reduced) and its tail end is shifted northward (remains zonal); the North Pacific storm track extends further (less) eastward and thus closer to the west coast of North America. (2) The extreme high pressure system over Europe tends to be supported by an anomalous transient eddy forcing of the mean flow stream-function: it enhances the zonal wind to its north and generates anticyclonic vorticity about 10° upstream from its center. In the low pressure composite the anomalous cyclonic vorticity is generated reducing the zonal flow to its north. (3) The occurrence (lack) of a strong eastward stationary wave activity flux over the Atlantic is associated with the high (low) pressure situations over Europe. Finally, a positive feedback is conjectured between the stationary wavetrain modifying the tail end of the cross-Atlantic storm track and the transient eddies intensifying this anomaly.     

Reconstructing climate variability on the northeastern Tibetan Plateau since the last Lateglacial – a multi-proxy,dual-site approach comparing terrestrial and aquatic signals

A sediment core from a closed basin lake (Lake Kuhai) from the semi-arid northeastern Tibetan Plateau was analysed for its pollen record to infer Lateglacial and post glacial vegetation and climatic change. At Lake Kuhai five major vegetation and climate shifts could be identified: (1) a change from cold and dry to relatively warmer and more moist conditions at 14.8 cal ka BP; (2) a shift to conditions of higher effective moisture and a stepwise warmer climate at 13.6 cal ka BP; (3) a further shift with increased moisture but colder conditions at 7.0 cal ka BP; (4) a return to a significantly colder and drier phase at 6.3 cal ka BP; (5) and a change back to relatively moist conditions at 2.2 cal ka BP. To investigate the response of lake ecosystems to climatic changes, statistical comparisons were made between the Lake Kuhai pollen record and a formerly published ostracod and sedimentary record from the same sediment core. Furthermore, the pollen and lacustrine proxies from Lake Kuhai were compared to a previously published pollen and lacustrine record from the nearby Lake Koucha. Statistical comparisons were done using non-metric multidimensional scaling and Procrustes rotation. Differences between lacustrine and pollen responses within one site could be identified, suggesting that lacustrine proxies are partly influenced by in-lake or local catchment processes, whereas the terrestrial (pollen) proxy shows a regional climate signal. Furthermore, we found regional differences in proxy response between Lake Kuhai and Lake Koucha. Both pollen records reacted in similar ways to major environmental changes, with minor differences in the timing and magnitude of these changes. The lacustrine records were very similar in their timing and magnitude of response to environmental changes; however, the nature of change was at times very distinct. To place the current study in the context of Holocene moisture evolution across the Tibetan Plateau, we applied a five-scale moisture index and average link clustering to all available continuous palaeo-climate records from the Tibetan Plateau to possibly find general patterns of moisture evolution on the Plateau. However, no common regional pattern of moisture evolution during the Holocene could be detected. We assign this to complex responses of different proxies to environmental and atmospheric changes in an already very heterogeneous mountain landscape where minor differences in elevation can cause strong variation in microenvironments.