Oxygen deficient perovskites in the system CaSiO3–CaAlO2.5 and implications for the Earth’s interior

Oxygen deficient perovskites of the system CaSiO₃–CaAlO_2.5 have been synthesised at high-pressure and -temperature conditions relevant to the Earth’s transition zone in order to investigate their stabilities in the Earth’s mantle and determine structural properties associated with vacancy incorporation. Two polysomes of thermodynamically stable defect perovskites with Ca(Al_0.4Si_0.6)O_2.8 and Ca(Al_0.5Si_0.5)O_2.75 stoichiometry have been identified. The ordering of oxygen defects into pseudo-cubic (111) layers results in well-ordered ten- or eightfold superstructures, respectively. At all other compositions examined, a metastable formation of perovskites has been observed instead, which are assumed to grow initially disordered. These are now characterised by tiny domains, formed due to subsequent ordering of vacancies along various pseudo-cubic {111} layers. Both ordered defect perovskites show a large P–T stability field ranging from about 9–18 GPa and 4–12 GPa, respectively. Microstructural TEM analyses revealed the presence of growth and ferroelastic twins, which indicate a phase transition from rhombohedral to monoclinic symmetry during quenching. Electron energy loss spectroscopy of Si and Al K edges point at the presence of tetrahedral, octahedral and maybe some pentacoordinated silicon, whereas aluminium is predominantly octahedrally coordinated with minor fractions in lower coordination. Observed properties are interpreted in terms of a new structural model, explaining the observed phase transition and formation of different twin laws as well as giving reasons for the development of such large superstructures. With respect to phase relations of the transition zone, the potential occurrence of such defect perovskites in the Earth’s interior is discussed.     

Results of concentration and mobility measurements of positively and negatively charged particles taken by a rocket-borne parachuted aspiration (Gerdien) probe in the height region from 72 to 39 km

Summary With a self-neutralizing, rocket-borne parachute aspiration probe concentration and mobility measurements of positively and negatively charged carriers were made between 72 and 40 km over Sardinia. Between 72 km and 60 km a heavy and a light group of positively charged particles were found. The heavy group was more abundant than the hight group in the greater heights. For the negatively charged particles only one mobility group was found which roughly corresponded to the mobility of the light group of the positively charged carriers. The probe was designed so that no electrons could enter the analyzer section of the aspiration system. By this the electron concentration was given by the difference in concentration between the positively and negatively charged particles.This paper was read byH. Dolezalek, in an abbreviated form supplied by the authors.     

Generating fracture networks using iterated function systems

In order to model flow and transport in fractured rocks it is important to know the geometry of the fracture network. A stochastic approach is commonly used to generate a synthetic fracture network from the statistics measured at a natural fracture network. The approach presented herein is able to incorporate the structures found in a natural fracture network into the synthetic fracture network. These synthetic fracture networks are the images generated by Iterated Function Systems (IFS) as introduced by Barnsley (1988). The conditions these IFS have to fulfil to determine images resembling fracture networks and the effects of their parameters on the images are discussed. It is possible to define the parameters of the IFS in order to generate some properties of a fracture network. The image of an IFS consists of many single points and has to be suitably processed for further use.     

Transportation as a limitation to rural development: The case of Abak in Nigeria

Abak was opened by the colonial government as an administrative centre in the early 1900s. Since then the town and its surrounding areas are still rural in outlook. Development possibilities are very slim unless transportation is viewed seriously by both the government.The difficulty here is that the Kwa Iboe River with its tributaries that crosses the area has created transport bottlenecks. Entry into the area from the E, W and S is through narrow onelane bridges on the rivers. The inefficient transport development has led to difficulties in the movement of farm products to the market. The prices of manufactured goods are higher in the area than in other places about 12 or 14 kilometres away.     

Rootless calc-silicate folds in granite: An implication towards syn- to post-plutonic emplacement

Deformation of the Champaner Group of rocks that form a part of Southern Aravalli Mountain Belt, western India, occurred during the Grenville orogeny (ca. 1400–935 Ma). Two phases of deformation are recorded: \(\hbox {D}_{1}\), persistent throughout the group and characterised by westerly plunging tight isoclinal folds and \(\hbox {D}_{2}\), a localized phase of deformation associated with shortening of the earlier folds from the eastern margin. Both the phases of deformation are in association with the syn-tectonically emplaced Godhra granite. The present work records rootless calc-silicate folds in granite belonging to the older formation, located at the eastern fringe of the Champaner Group. Field evidences suggest superimposition of Type 2 interference pattern trending NE–SW over rootless Type 0 of varying trends from NW–SE to N–S. The superposed pattern obtained from the field study differs in terms of structural trends with the neighbouring Precambrian stratigraphic units. These stratigraphic units include the Champaner Group to which the study area belongs, the Kadana Formation of the Lunavada Group and Pre-Chamapaner Gneissic Complex. Rootless character of folds found within the study area imply syn-post plutonic emplacement of Godhra granite.     

X-Ray investigations on the deformation of experimentally shock-loaded quartzes

Quartz single crystals submitted to dynamic pressures higher than 200 kbar show intensive anisotropic postshock cell expansions and lattice disordering which gradually increase along with the degree of shock compression. Maximum expansion and lattice distortion occur parallel to [10.0] followed by [21.0] and [20.1], whereas the lowest expansion rates and comparatively little lattice damage can be observed parallel to [10.2] and [00.1]. [10.0], [21.0], and [20.1] represent short Burgers vectors within the quartz lattice. They are probably preferred directions of a structure-controlled deformation.Annealing experiments carried out at 300, 605 and 900 ° C make the expanded cell parameters approach the values of unshocked quartz. Two different types of recrystallization can be observed:

Customization of WRF-ARW model with physical parameterization schemes for the simulation of tropical cyclones over North Indian Ocean

The convection and planetary boundary layer (PBL) processes play significant role in the genesis and intensification of tropical cyclones (TCs). Several convection and PBL parameterization schemes incorporate these processes in the numerical weather prediction models. Therefore, a systematic intercomparison of performance of parameterization schemes is essential to customize a model. In this context, six combinations of physical parameterization schemes (2 PBL Schemes, YSU and MYJ, and 3 convection schemes, KF, BM, and GD) of WRF-ARW model are employed to obtain the optimum combination for the prediction of TCs over North Indian Ocean. Five cyclones are studied for sensitivity experiments and the out-coming combination is tested on real-time prediction of TCs during 2008. The tracks are also compared with those provided by the operational centers like NCEP, ECMWF, UKMO, NCMRWF, and IMD. It is found that the combination of YSU PBL scheme with KF convection scheme (YKF) provides a better prediction of intensity, track, and rainfall consistently. The average RMSE of intensity (13?hPa in CSLP and 11?m?s^?1 in 10-m wind), mean track, and landfall errors is found to be least with YKF combination. The equitable threat score (ETS) of YKF combination is more than 0.2 for the prediction of 24-h accumulated rainfall up to 125?mm. The vertical structural characteristics of cyclone inner core also recommend the YKF combination for Indian seas cyclones. In the real-time prediction of 2008 TCs, the 72-, 48-, and 24-h mean track errors are 172, 129, and 155?km and the mean landfall errors are 125, 73, and 66?km, respectively. Compared with the track of leading operational agencies, the WRF model is competing in 24?h (116?km error) and 72?h (166?km) but superior in 48-h (119?km) track forecast.     

40Ar/39Ar Thermochronology west of the Main Uralian fault, southern Urals, Russia

West of the Main Uralian fault, the main suture in the southern Urals, ⁴⁰Ar/³⁹Ar apparent ages of amphibole, muscovite and potassium feldspar are interpreted as cooling ages. A fast exhumation of the metamorphic complex of Kurtinsky during Upper Carboniferous time is indicated by the small age difference (15 Ma) between cogenetic amphibole and muscovite. Differentiated movement in the footwall of the Main Uralian fault along strike is indicated by the age difference of 70 Ma between the metamorphic complexes of Kurtinsky (north) and Maksyutov (south). No Upper Paleozoic (Uralian) medium- to high-temperature event is recorded in ⁴⁰Ar/³⁹Ar data from the metamorphic complex of Beloretzk (MCB). An amphibole age of 718±5 Ma and the occurrence of mafic intrusions might signal the break-up of Rodinia and therefore indicate the rifting period followed by the separate movement of the "Beloretzk terrane". Muscovite ages of approximately 550±5 Ma, the unique pre-Ordovician tectonometamorphic evolution of the MCB and the Late Vendian sedimentary history of the western Bashkirian Megaanticlinorium (BMA) imply the existence of a Neoproterozoic orogeny at the eastern margin of Baltica. This orogeny might have been initiated by the accretion of the "Beloretzk terrane". The metamorphic grade of the overlain Silurian shales and the K/Ar microcline ages from the "Beloretzk terrane" give evidence for a new thermal event at approximately 370 Ma. A microcline age of 530–550 Ma obtained for the Vendian conglomerate in the western BMA suggests that a maximum temperature of approximately 200°C was reached in Cambrian or Vendian times. An orthoclase age (590–630 Ma) of the Vendian Zigan flysch deposits might be inherited from the eastern source area, the Cadomian orogen. An orthoclase age (910–950 Ma) from the Riphean Zilmerdak conglomerate coincides with a documented decrease in the subsidence rate of the Upper Riphean basin.