The Algoma-type iron-formations of the Nigerian metavolcano-sedimentary schist belts

Field relationships as well as petrographical and geochemical considerations form the basis of a model for the origin of the protoliths of the iron-formations and the associated phyllitic host rock of the Palaeoproterozoic schist belts of northern Nigeria. The iron-formations which consist of both the magnetite-subfacies and silicatefacies occur as relatively small, sporadic tabular bodies throughout the belts. They are concordantly interbanded with metasedimentary phyllites with which they share common metamorphic and deformational imprints. The iron-formations have high contents of Mn, Ca, Fe and P₂O₅ and low concentrations of alkalis (Na,K, Rb) Ba and Sr, Ti, Al and Si, whereas the phyllite exhibits exactly the opposite character. These results and other features (e.g. the composition of tourmaline in the phyllite and the occurrence of hydroclastic Cr-Mn-spinel and sulphides in the iron-formation) indicate a supply of materials from two different sources to the marine basin of Nigeria probably during Birimian time: slow but continuous deposition of continentally derived material of pelitic to psammitic composition; and rapid, sometimes intermittent, sporadic pulses of submarine-volcanic exhalations. During regional metamorphism (probably of Eburnian age) at greenschist to lower amphibolite fades conditions, the continental materials were transformed into phyllites and the mudstone-like sediments derived from volcanic exhalations into iron-formations. In the northern Nigerian schist belts two types of metamorphic parageneses in the iron-formations are recognized, both with various subtypes and without transitions between these two facies: (1) silicate-rich parageneses without magnetite (silicatefacies) and (2) magnetite-rich parageneses (magnetite-subfacies). In contrast to these parageneses, the iron-formations in the higher-grade metamorphic terrains of central Nigeria turn out to be hematitic (hematite-subfacies), and are derived from magnetite-bearing iron-formations by a second tectono-metamorphic event of Pan-African age (Mücke and Annor 1993). Whole-rock analyses of the Nigerian iron-formations explain the abundance of garnet (mainly spessartine) and clearly show that the formation of metamorphic minerals depended not only on temperature and pressure but also on the existing redox conditions. These environmental conditions controlled the formation of either magnetite parageneses (low redox conditions) or silicate parageneses without magnetite (high redox conditions). The environmental conditions are also an indication that magnetite (and hematite) could not have been constituents of the original sedimentary protolith of the Nigerian schist belts, but are exclusively of metamorphic origin.     

Estimation of instantaneous peak flows from maximum mean daily flows using the HBV hydrological model

The record length and quality of instantaneous peak flows (IPFs) have a great influence on flood design, but these high resolution flow data are not always available. The primary aim of this study is to compare different strategies to derive frequency distributions of IPFs using the Hydrologiska Byråns Vattenbalansavdelning (HBV) hydrologic model. The model is operated on a daily and an hourly time step for 18 catchments in the Aller‐Leine basin, Germany. Subsequently, general extreme value (GEV) distributions are fitted to the simulated annual series of daily and hourly extreme flows. The resulting maximum mean daily flow (MDF) quantiles from daily simulations are transferred into IPF quantiles using a multiple regression model, which enables a direct comparison with the simulated hourly quantiles. As long climate records with a high temporal resolution are not available, the hourly simulations require a disaggregation of the daily rainfall. Additionally, two calibrations strategies are applied: (1) a calibration on flow statistics; (2) a calibration on hydrographs. The results show that: (1) the multiple regression model is capable of predicting IPFs with the simulated MDFs; (2) both daily simulations with post‐correction of flows and hourly simulations with pre‐processing of precipitation enable a reasonable estimation of IPFs; (3) the best results are achieved using disaggregated rainfall for hourly modelling with calibration on flow statistics; and (4) if the IPF observations are not sufficient for model calibration on flow statistics, the transfer of MDFs via multiple regressions is a good alternative for estimating IPFs. Copyright © 2015 John Wiley & Sons, Ltd.     

Temporal characteristics of the Indian southwest monsoon

In this study, we elucidate the temporal characteristics of the onset and withdrawal of the Indian southwest monsoon, making use of the model integration and daily analyses of the National Centre for Medium Range Weather Forecasting, India. The onset of the Indian southwest monsoon over the Bay of Bengal is discernable by a gradual increase in the adiabatic generation of kinetic energy, while over the Arabian Sea it is first noticeable by a steep and abrupt increase of generation. The horizontal transport of heat indicates a convergence regime over the Bay of Bengal prior to onset, while over the Arabian Sea a convergence regime is indicated by a change from the divergence to the convergence regime. The withdrawal of the southwest monsoon is characterized by the horizontal transport of heat and moisture that evince a transition from the convergence to divergence regime; similarly, diabatic heating noticed during the active period changes to cooling. The withdrawal over the Arabian Sea is characterized by the divergence regime of the horizontal transport of moisture. This change precedes even the circulation changes over northwest India, which may be regarded as a precursor. The withdrawal is further supported by a monotonic decrease in the net tropospheric moisture over the Arabian Sea, followed by a similar change at land locations.     

Generation, mobilization and crystallization of impact-induced alkali-rich melts in granitic target rocks: Evidence from the Araguainha impact structure, central Brazil

This paper provides important insights into the generation, extraction and crystallization of clast-laden impact melt rocks from the Araguainha impact structure, central Brazil. Despite the mixed nature of the Araguainha target rocks (comprising a 2 km thick sequence of sedimentary rocks and underlying granitic basement), the exposed melt bodies are characterised by an alkali-rich granitic matrix embedding mineral and rock fragments derived only from the target granite. The melt rocks occur in the form of a massive impact melt sheet overlying the eroded central uplift structure, and as melt veins in the granite of the core of the central uplift. Bulk-rock major and trace element data (including platinum group elements) indicate that the precursor melts were generated locally, principally by partial melting of the target granite, without any contribution from the sedimentary sequence or the projectile. The dense network of melt veins was formed in isolation, by selective melting of plagioclase and alkali feldspar within the granite target. Plagioclase and alkali feldspar melted discretely and congruently, producing domains in the matrix of the melt veins, which closely match the stoichiometry of these minerals. The compositionally discrete initial melt phases migrated through a dense network of microfractures before being assembled into larger melt veins. Freezing of the melt veins was substantially fast, and the melt components were quenched in the form of alkali-feldspar and plagioclase schlieren in the matrix of the melt veins. The overlying impact melt rock is, in contrast, characterised by a granophyric matrix consisting of albite, sanidine, quartz, biotite and chlorite. In this case, melt components appear to have been more mobile and to have mixed completely to form a granitic parental melt. We relate the melting of the minerals to post-shock temperatures that exceeded the melting point of feldspars.     

S-type granite generation and emplacement during a regional switch from extensional to contractional deformation (Central Iberian Zone,Iberian autochthonous domain,Variscan Orogeny)

International Journal of Earth Sciences - Zircon grains extracted from S-type granites of the Mêda-Escalhão-Penedono Massif (Central Iberian Zone, Variscan Orogen) constrain the timing of...     

Treatment of broad palaeodose distributions in OSL dating of dune sands from the western Murray Basin, South Australia

Preliminary results of an optically stimulated luminescence dating study in the western Murray Basin in semi-arid south-eastern Australia are presented. The ultimate objective of the dating study is a reconstruction of dune formation indicative of palaeoclimatic changes in this region. So far, one site has been dated using the single-aliquot regenerative (SAR) dose protocol for quartz. A high scatter in individual palaeodoses was observed, which is unexpected in supposedly well bleached aeolian deposits. Therefore other sources of variability such as microdosimetry and bioturbation have to be taken into account. Nevertheless, the resulting ages are in chronostratigraphic order and document a long aeolian record from 180 to 9 ka.     

Comparison of gravimetric and seismic constraints on the structure of the Aegean lithosphere in the forearc of the Hellenic subduction zone in the area of Crete

The island of Crete is located in the forearc of the Hellenic subduction zone, where the African lithospheric plate is subducting beneath the Eurasian one. The depth of the plate contact as well as the internal structure of the Aegean plate in the area of Crete have been a matter of debate. In this study, seismic constrains obtained by wide-angle seismic, receiver function and surface wave studies are discussed and compared to a 3D density model of the region.The interface between the Aegean continental lithosphere and the African one is located at a depth of about 50 km below Crete. According to seismic studies, the Aegean lithosphere in the area of Crete is characterised by strong lateral, arc–parallel heterogeneity. An about 30 km thick Aegean crust is found in central Crete with a density of about 2850 kg/m³ for the lower Aegean continental crust and a density of about 3300 kg/m³ for the mantle wedge between the Aegean crust and the African lithosphere. For the deeper crust in the area of western Crete two alternative models have been proposed by seismic studies. One with an about 35 km thick crust and another one with crustal velocities down to the plate contact. A grid search is performed to test the consistency of these models with gravimetric constraints. For western Crete a model with a thick lower Aegean crust and a density of about 2950 kg/m³ is favoured. The inferred density of the lower Aegean crust in the area of Crete correlates well with S-wave velocities obtained by surface wave studies.Based on the 3D density model, the weight of the Aegean lithosphere is estimated along an E–W oriented profile in the area of Crete. Low weights are found for the region of western Crete.     

Deep seismic reflection profiling revealing the complex crustal structure of the Tongling ore district

Deep seismic reflection profiling has been the dominant method for probing the deep structure of continental crust since the initiation of the COCORP in 1974[1,2]. Over the past few decades, this tool has been applied to diverse geologic features from the Appalachian area of the United States, to the Rhine-graben area in Western Europe and to the Tibetan Pla-teau[36]. In recent years, the Australian Geodynamic Cooperative Research Center ( AGCRC ) has applied this technique to the stu…     

Tracing groundwater nitrate sources in the Dakar suburban area: an isotopic multi‐tracer approach

The Dakar region is a mega city with multiple contaminant sources from urban expansion as well as industrial and agricultural activities. The major part of the region is underlain by unconfined sandy aquifer, which is vulnerable to contaminants derived from human land use. At present, the contaminated groundwater which extends over a large area in the suburban zone of Thiaroye poses a threat to the future of this valuable resource, and more specifically, a health threat. This study focuses on nitrate pollution occurrences and associated processes using nitrate isotope data (¹⁵N_NO3, ¹⁸O_NO3) combined with environmental isotopic tracers (¹⁸O, ²H, and ³H). Samples from 36 wells were collected to determine the level, distribution, and sources of contamination in relation to land use. Results indicate that shallow groundwater in the urbanized area of Thiaroye shows distinct evidence of surface contamination with nitrate as much as 300 mg/l NO₃^?. In rural area not serviced by water supply distribution network, much higher NO₃^? contents were found in few wells due to household and livestock feedlots. In most groundwater samples δ¹⁵N values ranged from + 10 to + 22‰, indicative of predominantly human and animal wastes. This was confirmed by environmental isotope data which suggest a mixture of polluted recharge waters. By using the dual δ¹⁵N vs δ¹⁸O as well as δ¹⁵N vs NO₃^? approach, denitrification may occur to some extent but it is blurred by mixing with new infiltrated nitrates and cycling derived from continuous leaky septic system. Results suggest that nitrate contamination of the aquifer is a consequence of unregulated urbanisation (homemade latrines), continuing contaminant transfer in shallow water depth where aerobic conditions prevail. Copyright © 2011 John Wiley & Sons, Ltd.     

Groundwater recharge and evapotranspiration for two natural ecosystems covered with oak and heather

The evapotranspiration and groundwater recharge from two natural areas with high (oak) and low (heath) vegetation were estimated by calibrating a semi-physical numerical soil water and heat model to fit 8 and 7 years of TDR-measurements of water content, respectively. The measurements were made between the surface and 7 m depth. For the oak stand, the estimated annual recharge for the years 1992–1999 is 390 mm, the evaporation from soil and interception is 205 mm, and the transpiration is 285 mm. For the heath area estimation was carried out for the years 1993–1999. However, the heath was struck by a heavy beetle attack in 1994, which strongly affected the vegetation and thus the water balance for the following 3 years. For years not affected, the estimated recharge is 733 mm (about 50% larger than for the oak stand for the same years), the evaporation is 316 mm, and the transpiration is 128 mm. The estimated recharge values compare fairly well to estimates obtained from bromide tracer experiments. However, the recharge estimates obtained from the tracer experiments are very uncertain. The uncertainty is mainly due to spatial heterogeneity making the three replicate samples taken here for each time and depth insufficient.

The analyses of TDR-measurements and tracer data showed that water front movement depends on the antecedent soil water content. Some layers are bypassed, especially at low water contents, and at high soil water contents preferential flow was observed at the heath site.