Evidence for manganese substitution in synthetic goethite

Goethite (α-FeOOH) synthesized in the presence of Mn incorporates up to ca. 15 mole% Mn into its structure. This conclusion is based on a shift towards the isostructural groutite (α-MnOOH) of the unit cell dimensions a, b and c, and of the OH-bending modes. These results and a chemical test indicate trivalency of the incorporated Mn. The dehydroxylation (DTA) and the crystallinity (XRD line broadening) are also modified by Mn incorporation. All modifications of the goethites are analogous to the Al-for-Fe substitution.     

Amino acids of the Murchison meteorite: II. Five carbon acyclic primary β-, γ-, and δ-amino alkanoic acids

All ten of the possible five-carbon acyclic primary β-, γ-, and δ-amino alkanoic acids (amino position isomers of the valines) have been positively identified in hot-water extracts of the Murchison meteorite using combined gas chromatography-mass spectrometry (GC-MS) and ion exchange chromatography. With the exception of δ-aminovaleric acid, none of these amino acids has been previously reported to occur in meteorites or in any other natural material. The γ-amino acids (4-aminopentanoic acid, 4-aminc-2-meth-ylbutanoic acid, and 4-amino-3-methylbutanoic acid) are present at higher concentrations (about 5 nmol g^?1) than are the β-amino isomers (3-aminopentanoic acid, 3-amino-2-methylbutanoic acid, allo-3-amino-2-methylbutanoic acid, 3-amino-3-methylbutanoic acid, 3-amino-2-ethylpropanoic acid, and 3-amino-2,2-dimethylpropanoic acid) which are present at concentrations of 1–2 nmol g^?1. These amino acids are less abundant in the meteorite than either the corresponding α-amino acids or the four-carbon homologues. Thirty-six amino acids have now been positively identified in the Murchison meteorite, 17 of which are apparently unique to carbonaceous chondrites. The fact that the meteorite contains all possible five-carbon acyclic primary α-, β-, γ-, and δ-amino alkanoic acids is consistent with a synthetic process involving random combination of single-carbon precursors.     

Graphite content and isotopic fractionation between calcite-graphite pairs in metasediments from the Mgama Hills,Southern Kenya

Amphibolite-grade metasediments from the Mgama Hills region, Kenya, contain conspicuous quantities of graphite, most probably derived from organic progenitor materials. The highest graphite contents (5.1–20.4%) are found in schists whereas calcite marbles intercalated in the sequence contain relatively low amounts (0.1–2.0%). The graphitic constituents are consistently enriched in ¹³C relative to common sedimentary organic material, with the highest isotopic ratios in graphite from the marbles (δ¹³C = ?7.3 ± 5.0%.; n = 10). Carbon isotope fractionations between calcite and graphite mostly vary between 3.3 and 7.1‰, which comes close to both empirically recorded and thermodynamically calculated fractionations in the temperature range of the upper amphibolite faciès (550–650°C). However, larger values occasionally encountered in the marbles suggest that complete isotopic equilibrium is not always attained in amphibolite-facies metamorphism.     

Loss of metals from pelites during regional metamorphism

In aluminous metapelites the ratio H₂O⁺/K₂O decreases with increasing metamorphic grade and degree of reaction. This ratio is a very practical indicator for the progress of the mineral reconstitution during progressive metamorphism. With decreasing values of the ratio H₂O⁺/ K₂O the Cu concentration and the following element ratios also decrease either continuously or in stepwise fashion: Tl/K₂O, Ba/K₂O, Pb/K₂O, Bi/K₂O, Hg/K₂O, Sr/Na₂O, Zn/(Fe²⁺+Mg), Cd/(Fe²⁺+Mg); Rb/K₂O remains approximately constant. In the aluminous metapelites of the Damara Orogen in Namibia the following losses occur between the biotite isograd and anatexis: 61% Cu, 20% Tl, 34% Ba, 59% Pb, 86% Bi, 46% Hg, 30% Sr, 25% Zn, 31% Cd. Thus the potential of regional metamorphism to form hydrothermal deposits in the low grade environment should not be neglected.     

Influence of basement structures on the evolution of the major sedimentary basins of Brazil: A case of tectonic heritage

The present study deals with the correlation between the geotectonic features of the basement and the internal structure, shape, geologic evolution, etc. of the major sedimentary basins of the South American platform. The Paraná, Parnaíba and Amazonas basins occupy an area of the order of 3.6 × 10⁶ km², and their sedimentary cratonic sequences were deposited from Silurian to Triassic times. Subsidence rates are estimated around 15 m/Ma in the main depocenters.A geologic study was carried out along the basement features in the surroundings of such basins in order to identify the major structural, geotectonic and geochronological discontinuities. The extension of these basement characteristics towards the interior of the basins are examined. Basement core samples from deep wells were investigated through petrological and geochronological analyses, and pre-existing geophysical and structural maps of those basins were taken again into consideration.It can be concluded that many of the identified basement discontinuities display a direct influence on the depositional history of the basins as well as on their internal subdivisions and external outlines. Basement structures generated during the late Precambrian Brasiliano Cycle turned out to be particularly important.The Paraná and Parnaíba basins are considered to represent cratonic basins, located on rigid lithosphere, tectonically stabilized in the latest Precambrian/early Palaeozoic, and their subsidence is attributed to the establishement of some initial rifted grabens. The Amazonas basin is more complex and includes three large sub-basins with distinct evolutions, each located on a different tectonic segment of the basement.     

Zum Abbau von Formaldehyd durch adaptierte Bakterien

Municipal activated sludge was cultivated in a medium composed of formaldehyde, glucose and mineral salt. By passages with increasing formaldehyde content a bacterial culture was selected which remained active also at initial concentrations of 1 g/1 formaldehyde. With this culture, formaldehyde and glucose were oxidized simultaneously to formate and gluconate, which subsequently served simultaneously as substrate for the growth of bacteria. Glucose alone was also oxidized to gluconate, which then was used as substrate for growth. Formaldehyde alone was only oxidized. If the actual formaldehyde concentration was kept low, however, by fed-batch cultivation, it was assimilated also through formate formation. The biochemical background and the importance of the findings for the purification of formaldehyde-containing wastewaters are discussed.     

Radioactive element distribution in the Archean granulite terrane of Jequié — Bahia,Brazil

The radioactive element distribution in the Archean granulite facies rocks of Jequié, Brazil, has been determined. The K/Rb ratios show a large spread with majority of the values falling within the normal field (K/Rb<300). The Th/U ratios fall into two groups, one group with values in the range of 1.7 to 2.6, whereas the other group show Th/U values greater than 7 (7 to 25). These distributions can be explained on the basis of the presence of accessory minerals apatite and zircon. The relatively high concentrations of the radioactive and other elements in Jequié granulites probably represents the relict primary geochemical character, little modified during metamorphism. The radiogenic heat production data for the area are calculated and using the measured regional heat flow value from nearby area an estimate of the relative thickness of the continental lithosphere is made using the model developed by Oxburgh (1981).     

Zum Umweltverhalten von Fluortensiden Teil 1: Prüfung auf Aquatoxizität

Poecilia reticulata PETERS (guppy) and the green alga Monoraphidium griffithii were used for testing of different fluorotensides. After the representation of the methods of investigation and the definition of criteria of toxicity the obtained results of investigation are discussed. In general, the toxicity of the four investigated fluorotensides to algae was lower than to fish. The anionic fluorotenside CF₃—(CF₂)n—CFH—COONa was an exception. In tables and diagrams the results are summarized. Finally, for the condition of the receiving-water biocenosis class “2” the respective still permissible matter concentrations are proposed. They vary between 0.05 and 0.2 mg/1.