EPR evidence for maghemitization of magnetite in a tropical soil

Electron paramagnetic spectroscopy (EPR) was used in combination with standard rock magnetic methods to study magnetic minerals in a tropical soil. The susceptibility and hysteresis measurements showed magnetite grains with a Curie temperature near 850 K as the dominant magnetic remanence carriers in the soil. A minor Ti content in the magnetite was found by energy dispersive X-ray analysis. In order to get insight into the weathering status of the magnetite, different chemical treatments, including oxalate and citrate–bicarbonate–dithionite (CBD) extraction, were applied to the soil samples. The hysteretic properties exhibited no significant differences between the untreated and the CBD or oxalate treated samples. By contrast, the comparison of the EPR spectra revealed a significant broadening of the linewidth (δB) and a shift of the g -values ( g _eff) to lower fields after the CBD treatment. Furthermore, the spectral parameters g _eff and δB exhibited an angular dependence. At low temperature, the CBD treated samples showed a jump in δB between 120 and 100 K, the temperature range characteristic for the Verwey transition in magnetite. The changes in the spectral properties after the CBD treatment, which dissolves ferric oxides, were attributed to the removal of maghemite formed by the oxidation of magnetite, that is, during the maghemitization of the magnetite grains.     

河南省义马县中侏罗统义马组兽脚类恐龙足印化石的发现及其意义

本文记述了河南省义马县中侏罗世地层中首次发现的大型兽脚类恐龙足印。该足印虽然与发现于下—中侏罗统的张北足印类似,但是又不完全相同,从而命名为该属的一新种:徐氏张北足印(新足迹种):Changpeipus xuianainchnosp. nov.。它具有以下特征:足印的长度与宽度的比率约为1.9,第Ⅱ趾长度稍短于第Ⅳ趾的长度;第Ⅱ和第Ⅲ趾之间的夹角约为25°;第Ⅲ和第Ⅳ趾之间的夹角约为32°,足印的后部具有蹠骨所留下的印痕。徐氏张北足印的发现,不仅为我国中侏罗世恐龙足印增加了新的成员,而且为将来在该地区中侏罗世的地层中发现大型兽脚类恐龙骨骼化石提供确凿的依据。     

Origin of high field strength element enrichment in volcanic arcs: Geochemical evidence from the Sulu Arc, southern Philippines

Lavas from the Sulu Arc, southern Philippines, exhibit an enrichment in high field strength elements (HFSE) that represents a departure from the typical volcanic arc geochemical signature. It has been postulated that this relative enrichment arises from metasomatism of mantle wedge peridotites by melts derived from the subducting oceanic lithosphere, through formation of amphibole which subsequently breaks down and enriches the mantle source of parental arc magmas in HFSE. Divergent chemical and isotopic characteristics between Sulu Arc HFSE-enriched lavas and the Sulu Sea crust being subducted—the presumed source of slab-derived melts—render it unlikely, however, that HFSE enrichment arises from the influence of such melts. New geochemical data suggest that the varying degrees of HFSE enrichment in Sulu Arc lavas are instead the result of variable amounts of mixing between enriched and depleted mantle end-components—the sources of South China Sea intraplate lavas and Sulu seafloor basalts, respectively—within a compositionally heterogeneous mantle wedge.     

Simulation of rain-bearing summer monsoon systems along the west coast of India by use of ARMEX re-analysis

Re-analysis, using surface, upper-air, and satellite observations specially collected during the Arabian Sea Monsoon Experiment-I (ARMEX-I), has been performed with a global data assimilation system at T-80/L18 resolution. Re-analysis was performed for the entire ARMEX-I period (15th June–16th August 2002). In this paper we discuss the results based on re-analysis and subsequent forecasts for two successive intensive observation periods associated with heavy rainfall along the west coast of India during 2–12 August, 2002. Results indicate that the re-analysed fields can bring out better synoptic features, for example troughs along the west coast and mid tropospheric circulation over the Arabian Sea. Simulated rainfall distribution using re-analysis as initial condition also matches observed rainfall better than data from the initial analysis.     

Sea-breeze-initiated rainfall over the east coast of India during the Indian southwest monsoon

Sea-breeze-initiated convection and precipitation have been investigated along the east coast of India during the Indian southwest monsoon season. Sea-breeze circulation was observed on approximately 70–80% of days during the summer months (June–August) along the Chennai coast. Average sea-breeze wind speeds are greater at rural locations than in the urban region of Chennai. Sea-breeze circulation was shown to be the dominant mechanism initiating rainfall during the Indian southwest monsoon season. Approximately 80% of the total rainfall observed during the southwest monsoon over Chennai is directly related to convection initiated by sea-breeze circulation.     

Temporal characteristics of the Indian southwest monsoon

In this study, we elucidate the temporal characteristics of the onset and withdrawal of the Indian southwest monsoon, making use of the model integration and daily analyses of the National Centre for Medium Range Weather Forecasting, India. The onset of the Indian southwest monsoon over the Bay of Bengal is discernable by a gradual increase in the adiabatic generation of kinetic energy, while over the Arabian Sea it is first noticeable by a steep and abrupt increase of generation. The horizontal transport of heat indicates a convergence regime over the Bay of Bengal prior to onset, while over the Arabian Sea a convergence regime is indicated by a change from the divergence to the convergence regime. The withdrawal of the southwest monsoon is characterized by the horizontal transport of heat and moisture that evince a transition from the convergence to divergence regime; similarly, diabatic heating noticed during the active period changes to cooling. The withdrawal over the Arabian Sea is characterized by the divergence regime of the horizontal transport of moisture. This change precedes even the circulation changes over northwest India, which may be regarded as a precursor. The withdrawal is further supported by a monotonic decrease in the net tropospheric moisture over the Arabian Sea, followed by a similar change at land locations.     

Field and geochemical characteristics of the Mesoarchean ( 3075 Ma) Ivisaartoq greenstone belt, southern West Greenland: Evidence for seafloor hydrothermal alteration in supra-subduction oceanic crust

The Mesoarchean (ca. 3075 Ma) Ivisaartoq greenstone belt in southern West Greenland includes variably deformed and metamorphosed pillow basalts, ultramafic flows (picrites), serpentinized ultramafic rocks, gabbros, sulphide-rich siliceous layers, and minor siliciclastic sedimentary rocks. Primary magmatic features such as concentric cooling-cracks and drainage cavities in pillows, volcanic breccia, ocelli interpreted as liquid immiscibility textures in pillows and gabbros, magmatic layering in gabbros, and clinopyroxene cumulates in ultramafic flows are well preserved in low-strain domains. The belt underwent at least two stages of calc-silicate metasomatic alteration and polyphase deformation between 2963 and 3075 Ma. The stage I metasomatic assemblage is composed predominantly of epidote (now mostly diopside) + quartz + plagioclase ± hornblende ± scapolite, and occurs mainly in pillow cores, pillow interstitials, and along pillow basalt-gabbro contacts. The origin of this metasomatic assemblage is attributed to seafloor hydrothermal alteration. On the basis of the common presence of epidote inclusions in diopside and the local occurrence of epidote-rich aggregates, the stage I metasomatic assemblage is interpreted as relict epidosite. The stage II metasomatic assemblage occurs as concordant discontinuous layered calc-silicate bodies to discordant calc-silicate veins commonly associated with shear zones. The stage II metasomatic assemblage consists mainly of diopside + garnet + amphibole + plagioclase + quartz ± vesuvianite ± scapolite ± epidote ± titanite ± calcite ± scheelite. Given that the second stage of metasomatism is closely associated with shear zones and replaced rocks with an early metamorphic fabric, its origin is attributed to regional dynamothermal metamorphism. The least altered pillow basalts, picrites, gabbros, and diorites are characterized by LREE-enriched, near-flat HREE, and HFSE (especially Nb)-depleted trace element patterns, indicating a subduction zone geochemical signature. Ultramafic pillows and cumulates display large positive initial ε_Nd values of + 1.3 to + 5.0, consistent with a strongly depleted mantle source. Given the geological similarities between the Ivisaartoq greenstone belt and Phanerozoic forearc ophiolites, we suggest that the Ivisaartoq greenstone belt represents Mesoarchean supra-subduction zone oceanic crust.