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891.
The Atacama Desert has been predominantly hyperarid since the middle Miocene. Combined ionic and X-ray diffraction analysis shows that calcium sulphate is prevalent on three similar alluvial fans in salar basins across a transect of different environments in Antofagasta Province, northern Chile. Differences between the fans were largely due to the effect of local factors on salt input, secondary redistribution and deposit preservation. Thus carbonate was notable in the High Andes (fan C) and Pre-Cordillera (fan B), whereas in the Central Valley (fan A) greater qualities of the more soluble salts (chlorides and nitrates) probably reflect the higher level of aridity and an oceanic source (the camanchaca). Calcium sulphate distribution on the alluvial fans and on adjacent hilltops indicates an aeolian origin. Evidence from the Pre-Cordillera (fan B), however, suggests that salt input may have been episodic, related to changes in conditions within the general aridity and possibly to stone pavement and soil development. Calcium sulphate sources range from an input in Andean precipitation and the camanchaca to abundant regional evaporite deposits. It is probable, however, that products of Andean volcanism constitute the dominant primary source of calcium sulphate, and that the salt has subsequently been distributed widely within the endoreic basins of the region by a combination of groundwater, surface flow and the wind. © 1997 John Wiley & Sons, Ltd. 相似文献
892.
Estimation of groundwater recharge to an unconfined aquifer is studied using analytical and numerical techniques and results are compared with field observations. There is an acute need for such estimation in water balance studies in arid climates, and the case study in this paper is for such a region. The wetting front movement in the unsaturated zone depends on antecedent soil moisture, the ponded water depth and its duration, and on the position of the water table and the hydraulic properties of the unsaturated zone. A hydraulic connection between the recharge basin and the aquifer is not immediately established because the wetting front is unsaturated. A numerical model is applied to estimate recharge in an arid-zone wadi, and its validity is tested by comparing it with an analytical solution of the equations. The calculated recharge values matched the piezometric levels observed at a well site at the edge of the wadi channel. The total recharge depths found by integration in the time domain provided a good estimate of the transmitted volume of water per unit length of wadi channel. The findings were confirmed by runoff volume measurements at gauging stations located in the basin. © 1997 John Wiley & Sons, Ltd. 相似文献
893.
The Deccan Trap region exhibits an erosional landscape over a relatively ancient and stable Deccan shield. The Quaternary history of the area has been reconstructed on the basis of evidence from alluvial deposits occurring along the major rivers. However, recent investigations have revealed that evidence for geo-environmental change during the Quaternary Period is also contained in the colluvial deposits that occur in the foothill zones. The colluvial deposits, ranging in thickness from 1 to 10 m, invariably occupy gently inclined pediment slopes. The sediments are presently deeply dissected by gullies, and the process of colluviation has almost ceased. These deposits are best preserved in the semi-arid parts of the region. Detailed textural, geochemical and stratigraphical studies at four different sites reveal similar input processes, the slight variations being attributed to local environmental factors. Scanning electron microscopy studies of some grains indicate marginal contribution of aeolian processes at the time of deposition. Mesolithic artefacts and a few U/Th dates indicate that the colluviation took place during the Late Quaternary. The properties of the deposits suggest relatively high energy conditions as well as a remarkable variability in the intensity of hillslope processes. These properties are indicative of semi-arid conditions during which the regolith was stripped from devegetated hillslopes and was deposited on the pediments. A variety of evidence indicates that the period of colluviation coincided with arid conditions during the Last Glacial Maximum. The geomorphological and archaeological evidence also indicates that incision by gully systems was initiated during the early Holocene humid phase. The environmental conditions deduced for the study area are similar to those reported for other parts of the intertropical zone. © 1997 John Wiley & Sons, Ltd. 相似文献
894.
Thilina U.JAYAWARDENA Won Woo LEE I.P.Shanura FERNANDO K.K.Asanka SANJEEWA Lei WANG Tee Gee LEE Young Jin PARK Chang-ik KO You-Jin JEON 《中国海洋湖沼学报》2019,(4)
The exploration and identification of antiproliferative phytochemicals have received increased attention in medicinal chemistry.In particular,research focused on the toxicology of marine natural products has increased in recent years.Terpenoids,among many secondary metabolites,have been demonstrated to act as effective anticancer agents.Soft corals,a group of marine invertebrates,produce a variety of terpenoids with biofunctional properties.The current study presents the extraction,purification,and identification of sterol congeners from the soft coral Dendronephthya putteri.The method involves 50%chloro form-methanol extraction,polar column fractionation,and analy sis through GC-MS~n.Do se-dependent antiproliferative activity was observed within the sterol-rich fraction(DPCMH 2-4),which consisted of3β-hydroxy-A5-steroidal congeners.This fraction inhibited the growth of HL-60 and MCF-7 cells with IC_(50) values of 25.27±1.43 and 22.81±0.15 μg/mL,respectively.Apoptotic body formation,DNA damage,cell cycle arrest,and apoptotic cell signaling pathway activation were also observed,reinforcing the dosedependent antiproliferative and apoptosis-inducing activity of 3β-hydroxy-A5-steroidal congeners.To our knowledge,this is the first report of anticancer agent identification from the soft coral D.putteri.Based on the observations,these steroidal congeners are promising candidates for the development of anticancer drugs. 相似文献
895.
Literature data on the thermodynamics of complexation of Zr with inorganic species, at 25°C, have been critically reviewed. The preponderance of published complexation constants deal with F− and OH− ions. Stability constants for the complexation reactions are relatively independent of ionic strength and thus recomended values for each ligand type are averages of the most reliable data. Complexation constants under elevated conditions (T 250°C andPv = PH2O) have been predicted for various Zr complexes (F−, Cl−, SO42− and OH−) using Helgeson's electrostatic approach. Predominance diagrams (calculated for simple systems with these constants) suggest that, over a wide range of pH conditions, Zr(OH)4(aq) will dominate the aqueous geochemistry of Zr except under very high activities of competing ligands (e.g., F−, SO42−).The solubilities of vlasovite [Na2ZrSi4O11] and weloganite [Sr3Na2Zr(CO3)6·3H2O have been measured in KCI solutions (0.5–1.0 M) at 50°C. Weloganite dissolution is complicated by the predictable precipitation of strontianite (SrCO3) whereas vlasovite dissolves incongruently. Solubility products for the dissolution of welonganite and vlasovite are determined to be −28.96±0.14 and −20.40±1.18, respectively. Concentrations of Zr up to 10−3 m were present in the experimental solutions; the presence of large amounts of Zr in aqueous solutions support the possibility of extensive remobilization of Zr during hydrothermal mineralization. 相似文献
896.
S. N. Tandon J. B. Hutchings S. K. Ghosh A. Subramaniam G. Koshy V. Girish P. U. Kamath S. Kathiravan A. Kumar J. P. Lancelot P. K. Mahesh R. Mohan J. Murthy S. Nagabhushana A. K. Pati J. Postma N. Kameswara Rao K. Sankarasubramanian P. Sreekumar S. Sriram C. S. Stalin F. Sutaria Y. H. Sreedhar I. V. Barve C. Mondal S. Sahu 《Journal of Astrophysics and Astronomy》2017,38(2):28
The performance of the ultraviolet telescope (UVIT) on-board AstroSat is reported. The performance in orbit is also compared with estimates made from the calibrations done on the ground. The sensitivity is found to be within \(\sim \)15% of the estimates, and the spatial resolution in the NUV is found to exceed significantly the design value of \(1.8^{\prime \prime }\) and it is marginally better in the FUV. Images obtained from UVIT are presented to illustrate the details revealed by the high spatial resolution. The potential of multi-band observations in the ultraviolet with high spatial resolution is illustrated by some results. 相似文献
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