Nitrogen distribution in Lower Palaeozoic slates/phyllites of the Meguma Supergroup, Nova Scotia, Canada: implications for Au and Zn-Pb mineralisation and exploration

Major and trace elements and nitrogen were analysed in 59 Cambrian and Ordovician slates/phyllites of various lithostratigraphic levels within the Meguma Supergroup, 14 Ordovician slates/phyllites of The Ovens gold mineralisation, and 16 Ordovician slates/phyllites of the Eastville Pb-Zn-Cu mineralisation.The fixed nitrogen content and the normative N_fix/K₂O ratio of muscovite separates members of the Goldenville (sandstone-greywacke-quartzite dominated) and Halifax Formation (slate-phyllite dominated). Low fixed nitrogen concentration is related to high manganese concentration. Black slates/phyllites of the saddle-reef-type Au-mineralisation in The Ovens area are characterised by high fixed nitrogen and a high normative N_fix/K₂O ratio of muscovite. The nitrogen is of secondary hydrothermal origin. Therefore, it might be possible to use the fixed nitrogen as an exploration tool for black slates/phyllite hosted gold mineralisation in Nova Scotia. Mineralised slates/phyllites of the Eastville stratabound Pb-Zn mineralisation cannot be distinguished from nonmineralised time equivalent lithologies on the basis of the fixed nitrogen distribution or the N_fix/K₂O ratio of muscovite.     

Nitrogen components in ureilites

Abundances and isotopic compositions of nitrogen and argon have been investigated in bulk samples as well as in acid-resistant C-rich residues of a suite of ureilites consisting of six monomict (Haverö, Kenna, Lahrauli, ALH81101, ALH82130, LEW85328), three polymict (Nilpena, EET87720, EET83309), and the diamond-free ureilite ALH78019. Nitrogen in bulk ureilites varies from 6.3 ppm (in ALH 78019) to ∼55 ppm (in ALH82130), whereas C-rich acid residues have ∼65 to ∼530 ppm N, showing approximately an order of magnitude enrichment, compared with the bulk ureilites, somewhat less than trapped noble gases. Unlike trapped noble gases that show uniform isotopic composition, nitrogen shows a wide variation in δ¹⁵N values within a given ureilite as well as among different ureilites. The variations observed in δ¹⁵N among the ureilites studied here suggest the presence of at least five nitrogen components. The characteristics of these five N components and their carrier phases have been identified through their release temperature during pyrolysis and combustion, their association with trapped noble gases, and their carbon (monitored as CO + CO₂ generated during combustion). Carrier phases are as follows: 1) Amorphous C, as found in diamond-free ureilite ALH78019, combusting at ≤500°C, with δ¹⁵N = -21‰ and accompanied by trapped noble gases. Amorphous C in all diamond-bearing ureilites has evolved from this primary component through almost complete loss of noble gases, but only partial N loss, leading to variable enrichments in ¹⁵N. 2) Amorphous C as found in EET83309, with similar release characteristics as component 1, δ¹⁵N ≥ 50‰ and associated with trapped noble gases. 3) Graphite, as clearly seen in ALH78019, combusting at ≥700°C, δ¹⁵N ≥ 19‰ and devoid of noble gases. 4) Diamond, combusting at 600-800°C, δ¹⁵N ≤ -100‰ and accompanied by trapped noble gases. 5) Acid-soluble phases (silicates and metal) as inferred from mass balance are expected to contain a large proportion of nitrogen (18 to 75%) with δ¹⁵N in the range -25‰ to 600‰. Each of the ureilites contains at least three N components carried by acid-resistant C phases (amorphous C of type 1 or 2, graphite, and diamond) and one acid-soluble phase in different proportions, resulting in the observed heterogeneity in δ¹⁵N. In addition to these five widespread components, EET83309 needs an additional sixth N component carried by a C phase, combusting at <700°C, with δ¹⁵N ≥ 153‰ and accompanied by noble gases. It could be either noble gas-bearing graphite or more likely cohenite. Some excursions in the δ¹⁵N release patterns of polymict ureilites are suggestive of contributions from foreign clasts that might be present in them.Nitrogen isotopic systematics of EET83309 clearly confirm the absence of diamond in this polymict ureilite, whereas the presence of diamond is clearly indicated for ALH82130. Amorphous C in ALH78019 exhibits close similarities to phase Q of chondrites.The uniform δ¹⁵N value of −113 ± 13 ‰ for diamond from both monomict and polymict ureilites and its independence from bulk ureilite δ¹⁵N, Δ¹⁷O, and %Fo clearly suggest that the occurrence of diamond in ureilites is not a consequence of parent body-related process. The large differences between the δ¹⁵N of diamond and other C phases among ureilites do not favor in situ shock conversion of graphite or amorphous C into diamond. A nebular origin for diamond as well as the other C phases is most favored by these data. Also the preservation of the nitrogen isotopic heterogeneity among the carbon phases and the silicates will be more consistent with ureilite formation models akin to “nebular sedimentation” than to “magmatic” type.     

Assimilation of IRS-P4 (MSMR) meteorological data in the NCMRWF global data assimilation system

Oceansat-1 was successfully launched by India in 1999, with two payloads, namely Multi-frequency Scanning Microwave Radiometer (MSMR) and Ocean Color Monitor (OCM) to study the biological and physical parameters of the ocean. The MSMR sensor is configured as an eight-channel radiometer using four frequencies with dual polarization. The MSMR data at 75 km resolution from the Oceansat-I have been assimilated in the National Centre for Medium Range Weather Forecasting (NCMRWF) data assimilation forecast system. The operational analysis and forecast system at NCMRWF is based on a T80L18 global spectral model and Spectral Statistical Interpolation (SSI) scheme for data analysis. The impact of the MSMR data is seen globally, however it is significant over the oceanic region where conventional data are rare. The dry-nature of the control analyses have been removed by utilizing the MSMR data. Therefore, the total precipitable water data from MSMR has been identified as a very crucial parameter in this study. The impact of surface wind speed from MSMR is to increase easterlies over the tropical Indian Ocean. Shifting of the positions of westerly troughs and ridges in the south Indian Ocean has contributed to reduction of temperature to around 30‡S.     

Laboratory investigations on rotary diamond drilling

Extensive laboratory drilling investigations were conducted on a wide variety of rocks to study the inter-dependence of machine as well as rock parameters on the performance of the drilling operation. Detailed physical and mechanical properties of all the rock types were determined to study the influence of the rock properties on the drilling performance. The effect of PEO (poly-ethylene-oxide) added to the drilling water was also studied. Slake durability tests were conducted in plain water as well as a PEO mixed water medium to observe the effects of PEO on the surface properties of the rock. An attempt is also made to understand the different modes of wear of impregnated diamond bits in the rotary drilling operation.     

Verification of the Contribution of Vehicular Traffic to the Total NMVOC Emissions in Germany and the Importance of the NO3 Chemistry in the City Air

In 1997 and 1998 several field campaigns for monitoring non-methane volatile organic compounds (NMVOCs) and nitrogen oxides (NO_x) were carried out in a road traffic tunnel and in the city center of Wuppertal, Germany. C₂–C₁₀ aliphatic and aromatic hydrocarbons were monitored using a compact GC instrument. DOAS White and long path systems were used to measure aromatic hydrocarbons and oxygenated aromatic compounds. A formaldehyde monitor was used to measure formaldehyde. Chemiluminescence NO analysers with NO₂ converter were used for measuring NO and NO₂. The high mixing ratios of the NMVOCs observed in the road traffic tunnel, especially 2.9 ppbv phenol, 1.5ppbv para-cresol and 4.4 ppbv benzaldehyde, in comparison with themeasured background concentration clearly indicate that these compounds were directly emitted from road traffic. Para-Cresol was for the first timeselectively detected as primary pollutant from traffic. From the measured data a NMVOC profile of the tunnel air and the city air, normalised to benzene (ppbC/ppbC), was derived. For most compounds the observed city air NMVOC profile is almost identical with that obtained in the traffic tunnel. Since benzene originates mainly from road traffic emission, the comparison of the normalised emission ratios indicate that the road traffic emissions in Wuppertal have still the largest impact on the city air composition, which is in contrast to the German emission inventory. In both NMVOC profiles, aromatic compounds have remarkably large contributions of more than 40 ppbC%. In addtion, total NMVOC/NO_x ratios from 0.6 up to 3.0ppbC/ppb in the traffic tunnel air and 3.4± 0.5 in the city air of Wuppertal were obtained. From the observed para-cresol/toluene and ortho-cresol/toluene ratios in the city air, evidence was found thatalso during daytime NO₃ radical reactions play an important role in urban air.     

伽师地震区地壳细结构及发震断层的初步研究

199年至1998年伽师地区共出现9次震级为6.1-6.8级的强震. 在一个非常短的时间间隔内和非常小的地区范围内接连出现这么多次震级非常接近的地震,确实非常罕见. 为研究伽师强震区的深部构造背景和孕震机制,本文对伽师地震区的余震观测资料进行了分析处理. 利用联合反演技术同时得到了地震震源位置和地震区地壳三维速度结构. 余震震中沿一北北东向条带分布,与强震分布的两个条带中的北东向条带位置基本重合. 三维反演得到的速度结构结果表明,在地下12 km以下存在一条北北东向和一条北北西向的低速条带. 上述两低速条带与强震分布的两个条带位置很接近. 初步推测,低速条带对应了地壳深部的两条断裂. 在我们观测期间,北北东向断裂有微震活动,北北西向断裂相对平静.     

Three-dimensional Travel-time Calculation Based on Fermat's Principle

— We present a new travel-time calculation method based on Fermat's principle. In the method, travel times are recursively calculated on horizontal planes of increasing depth. For typical configurations of exploration geophysics, the distance between the planes is on the order of 100 m. The travel times on the first plane are calculated by connecting straight ray segments from the source point to the grid points on the plane and integrating the slowness along each segment. The times on the other planes are calculated by finding the minimum of the combination of the times on the plane above plus the additional time along segments connecting grid points on the two planes. The travel-time calculation method is designed for calculating either the first arrival times, or the time of the shortest travel path arrival. The method is extended to handle vertically transverse isotropic (VTI) media by an approach which increases the computing time only slightly. The algorithm is tested against synthetic examples for isotropic and VTI wave propagation.     

Geology and characterisation of the Pecket coal deposit, Magellan Region, Chile

The geology, petrography and chemical variation of the Pecket coal sequence, Magellan Region (52°57′S, 71°10′W), the only Chilean coal used for electricity generation on a large scale, has been studied in order to predict their combustion behaviour, especially in coal blends. The depositional environment of formation of the coal seams was a swamp rarely exposed to subaerial conditions and was associated with the development of the folded foreland of the Magellan basin during the Tertiary (Oligo–Miocene). The general tectonic regime of the collision of the Antarctic and South American plates is reflected by a system of joints with 40°N–50°W strike. The maceral composition of all six seams studied indicates high contents of vitrinite (>90%), minor content of liptinite (4.7%) and inertinite (<2%). Occurrence of tonstein horizons altered to kaolinite indicates a distal volcanism during peat accumulation. Coal rank varies between lignite and subbituminous (Ro=0.28–0.42%) with an average dry basis calorific value of 5450 kcal/kg, 17 wt.% moisture, 41 wt.% volatile matter, and sulphur content below 0.5 wt.%. The mineral matter (LTA) associated with the coal shows a dominance of kaolinite with quartz, smectite, and minor basanite. SiO₂/Al₂O₃ and Fe₂O₃/CaO ratios of the ashes diminish towards the lower seams. With respect to the utilisation of Pecket coals in combustion, base/acid ratios (B/A) and silica ratios (SR) indicate potential fouling for seams 1, 2, 5, and 6i, with high fouling indexes (Rf) for seams 2 and 5. Pecket coal is excellent for blend combustion due to its low sulphur content.     

Sebkhas as ecological archives and the vegetation and landscape history of southeastern Tunisia during the last two millennia

Sebkhas are temporary lacustrine systems depending on the number and extension of floodings. They may create laminated sediments which can be exploited as ecological archives. Contrary to those of meromictic lakes they are seasonal but not annual. After each flooding a detritus layer and a plasmo-condensed layer of bacteria and algae are formed in the water body or film and during the subsequent dessication a third subaeric layer of evaporites is build up. These laminae show a quasi-textile fabric and they can trap and conserve any dust and fine grained material. A high resolution pollendiagram covering the last two millennia as well as geochemical analysis from a southeastern Tunisian sebkha demonstrate the potentials of these ecological archives.     

The Origin and Distribution of Salts on Alluvial Fans in The Atacama Desert,Northern Chile

The Atacama Desert has been predominantly hyperarid since the middle Miocene. Combined ionic and X-ray diffraction analysis shows that calcium sulphate is prevalent on three similar alluvial fans in salar basins across a transect of different environments in Antofagasta Province, northern Chile. Differences between the fans were largely due to the effect of local factors on salt input, secondary redistribution and deposit preservation. Thus carbonate was notable in the High Andes (fan C) and Pre-Cordillera (fan B), whereas in the Central Valley (fan A) greater qualities of the more soluble salts (chlorides and nitrates) probably reflect the higher level of aridity and an oceanic source (the camanchaca). Calcium sulphate distribution on the alluvial fans and on adjacent hilltops indicates an aeolian origin. Evidence from the Pre-Cordillera (fan B), however, suggests that salt input may have been episodic, related to changes in conditions within the general aridity and possibly to stone pavement and soil development. Calcium sulphate sources range from an input in Andean precipitation and the camanchaca to abundant regional evaporite deposits. It is probable, however, that products of Andean volcanism constitute the dominant primary source of calcium sulphate, and that the salt has subsequently been distributed widely within the endoreic basins of the region by a combination of groundwater, surface flow and the wind. © 1997 John Wiley & Sons, Ltd.