New geochemical data from the Nigerian sector of the Chad basin: implications on hydrocarbon prospectivity

Organic geochemical studies have been carried out to assess the qualities of source rocks penetrated by four wells (Kemar-1, Murshe-1, Tuma-1 and Ziye-1) in the Nigerian sector of the Chad basin. The Chad basin is a large intracratonic basin in Central West Africa. Commercial hydrocarbon accumulations have been discovered in some sectors of the basin outside the Nigerian border in a structurally related contiguous basin. Fair to poor quality source rocks are inherent in the sequences penetrated by the studied wells. About 80% of all samples have their total organic carbon (TOC) contents more than 0.5 wt.%, the minimum limit for hydrocarbon generation. Juxtaposition of the hydrogen indices against the TOC and T_max indicates that the source rocks are entirely gas-prone. However, biomarker chromatograms and extract vs. TOC plots indicate the presence of oil shows in Ziye-1 well at a depth of 1210 m. Although generated hydrocarbons (wherever they have accumulated) would be overwhelmingly gaseous, gas is the energy of the future. The gas resources of this part of Nigeria's inland basins can be economically exploited through policies that will increase the tempo of gas-utilization projects and the construction of a national grid of gas pipelines with nodal points of input and output.     

Reversibility of radiocaesium sorption on illite

Adsorption of trace amounts of radiocaesium on NH₄-, K-, and Na-saturated Fithian illite and subsequent desorption by 1 M NH₄ showed that a substantial amount of radiocaesium (44%, 46%, and 91% for NH₄-, K-, and Na-illite, respectively) cannot be desorbed after only 5 min of adsorption. Our results suggest that this instantaneous fixation is caused by the collapse of the frayed edges of the clay mineral and the relatively high concentration of radiocaesium building up in solution in the batch desorption experiments. Consequently, commonly applied high-NH₄ extractions underestimate truly exchangeable amounts of radiocaesium in soils and sediments containing illitic clay minerals. The rate of desorption of trace amounts of radiocaesium from the solids using high NH₄ or Cs concentrations has a half-life of about 2 yr, reflecting radiocaesium desorption from (partially) collapsed interlayers. Extraction of radiocaesium from illite after 5 min of contact time with a Cs-selective adsorbent or a 1 × 10^-6 M CsCl solution shows that 100% of the bound radiocaesium is readily available. The desorption rate in the presence of a Cs-selective adsorbent has a half-life of about 0.2 yr. Desorption of radiocaesium from illite using different ammonium concentrations shows that radiocaesium partitioning follows reversible ion-exchange theory if the NH₄ concentration is below 1 × 10^-4 M, and sufficient time (weeks) is allowed for the reaction to proceed. Thus, radiocaesium sorption reversibility in the natural environment is much higher than generally assumed, and equilibrium solid/liquid partitioning may be assumed for the long-term modelling of radiocaesium mobility in the natural environment. In the particular case of anoxic freshwater sediments with very high NH₄ concentrations in the pore waters (up to several mmol.L^-1), collapse of the frayed edges of illite may occur, influencing radiocaesium partitioning. If collapse occurs before radiocaesium adsorbs to illite, high caesium sorption reversibility as measured by high-NH₄ extraction can be expected because further collapse of the frayed edges during the extraction procedure will be limited. This effect has indeed been observed earlier in the extraction of radiocaesium from anoxic freshwater sediments with high-NH₄ solutions and was as yet unexplained.     

Assessing scleractinian corals as recorders for paleo-pH: Empirical calibration and vital effects

Laboratory experiments on the branching, symbiont-bearing coral genus Porites and Acropora have been carried out to determine the dependence of the skeletal boron isotopic composition (δ¹¹B) on the pH of seawater. The results show a clear relationship similar to previously established empirical calibrations for planktonic foraminifera and inorganic calcite. A −0.6‰ offset exists between P. cylindrica and A. nobilis which is systematic over the pH range of 7.7-8.2. To test whether the δ¹¹B of coral skeletons changes with physiological processes such as photosynthesis and respiration, corals were grown along a depth transect in their natural environment and under controlled conditions in the laboratory at varying light intensities and food supply. Although we also observe an isotopic offset between P. compressa and Montipora verrucosa, neither experimental treatment systematically changed the δ¹¹B of the two species. These findings are encouraging for using the boron isotope paleo-pH proxy in corals, because it appears that seawater pH is the dominant control on the boron isotopic composition in corals.     

Quasi-simultaneous VLBI and RATAN-600 observations of active galactic nuclei

VLBI observations of several quasars and BL Lacertae objects were carried out at 1.66 GHz in November–December 1999 using six antennas (Medvezh'i Ozera, Svetloe, Pushchino, Noto, HartRAO, and Shanghai). Maps of six sources (0420+022, 0420-014, 1308+326, 1345+125, 1803+784, and DA 193) obtained with milliarcsecond resolution are presented and discussed, together with their broad-band (1–22 GHz) spectra obtained on the RATAN-600 radio telescope at epochs close to those of the VLBI observations. Comparison of the VLBI maps with maps of these sources obtained on standard VLBI networks and with the RATAN-600 quasisimultaneous total-flux measurements indicates the reliability of the results obtained on this Low Frequency VLBI Network and the good efficiency of this network.     

Pulsating evershed flows and propagating waves in a sunspot

A comparative analysis of oscillatory spectra based on 66 time series for 14 active regions observed in 2001 shows that, although the chromospheric and photospheric oscillations in the Evershed flow zone possess many common features, there is no firm evidence that the direct and inverse flows have the same physical origin. The interactions between the various oscillation modes and stationary flows results in a complex pattern of wave motions in a sunspot. We studied the Doppler-velocity variations in the sunspot NOAA 0051 during its motion over the disk. The spatial-temporal distribution of the line-of-sight velocity in the chromospheric umbra displays a chevron structure, clearly indicating the presence of propagating waves. These waves move from the center of the umbra to outer regions with a phase speed of 45–60 km/s, a period of 2.8 min, and a measured Doppler speed of 2 km/s. The amplitude of these oscillations decreases abruptly at the boundary between the umbra and penumbra, and the observed waves are not directly related to propagating penumbral waves. Furthermore, the observed pattern of the photospheric velocities shows periodic motions (with a period of 5 min) directed from the inner boundary of the penumbra and superpenumbra toward the line of maximum Evershed velocity.     

The rapid variability of blazars at optical wavelengths

We monitored five active galactic nuclei in the R optical band with a CCD mounted on the 1-m Zeiss-1000 telescope of the Special Astrophysical Observatory from April 2001 to August 2003. Three sources displayed intraday variability on several nights. Stronger variability was detected on time scales from two days to a week. The two-year light curves are presented for four of the observed objects.     

Velocity field in the spiral-wave pattern observed in rotating shallow-water experiments

The paper presents the first quantitative results of a laboratory study of the velocity field in a two-arm spiral-wave pattern generated in a steady-state fashion by a hydrodynamical instability in a differentially rotating, thin layer of liquid. The liquid layer has a free surface, and the rotational profile includes an interval where the velocity drops abruptly, as in the gaseous disks of spiral galaxies. The properties of anticyclonic vortices observed between the arms of this pattern at the corotation radius are considered.     

Near-polar starspots and polar dynamo waves

A possible mechanism for the formation of near-polar magnetic spots on some stars with convective envelopes is proposed. The mechanism is based on the idea that the maximum of the dynamo waves that are excited in thin convective shells by the dynamo mechanism is shifted appreciably from the maximum of the magnetic-field sources in the direction of motion of the dynamo wave. If there is no region of super-rotation near the equator for some reason (as a consequence of disruption due to tidal interaction with a companion in a binary system, for example) and the wave of stellar activity propagates toward the poles rather than toward the equator, this maximum will be in the near-polar regions.     

U-Pb Zircon Calendar for Namaquan (Grenville) Crustal Events in the Granulite-facies Terrane of the O'okiep Copper District of South Africa

The O'okiep Copper District is underlain by voluminous 1035–1210Ma granite gneiss and granite with remnants of metamorphosedsupracrustal rocks. This assemblage was intruded by the 1030Ma copper-bearing Koperberg Suite that includes jotunite, anorthosite,biotite diorite and hypersthene-bearing rocks ranging from leuconoriteto hypersthenite. New sensitive high-resolution ion microprobeage data demonstrate the presence of 1700–2000 Ma zirconas xenocrysts in all of the intrusive rocks, and as detritalzircon in the metasediments of the Khurisberg Subgroup. Thesedata are consistent with published Sm–Nd model ages ofc. 1700 Ma (T_CHUR) and c. 2000 Ma (T_DM) of many of the intrusivesthat support a major crust-forming event in Eburnian (Hudsonian)times. In addition, U–Th–Pb analyses of zirconsfrom all major rock units define two tectono-magmatic episodesof the Namaquan Orogeny: (1) the O'okiepian Episode (1180–1210Ma), represented by regional granite plutonism, notably theNababeep and Modderfontein Granite Gneisses and the Concordiaand Kweekfontein Granites that accompanied and outlasted (e.g.Kweekfontein Granite) regional tectonism [F₂(D₂)] and granulite-faciesmetamorphism (M₂); (2) the Klondikean Episode (1020–1040Ma), which includes the intrusion of the porphyritic RietbergGranite and of the Koperberg Suite that are devoid of regionalplanar or linear fabrics. Klondikean tectonism (D₃) is reflectedby major east–west-trending open folds [F₃(D_3a)], andby localized east–west-trending near-vertical ductilefolds [‘steep structures’; F₄(D_3b)] whose formationwas broadly coeval with the intrusion of the Koperberg Suite.A regional, largely thermal, amphibolite- to granulite-faciesmetamorphism (M₃) accompanied D₃. This study demonstrates, interalia, that the complete spectrum of rock-types of the KoperbergSuite, together with the Rietberg Granite, was intruded in ashort time-interval (<10 Myr) at c. 1030 Ma, and that therewere lengthy periods of about 150 Myr of tectonic quiescencewithin the Namaquan Orogeny: (1) between the O'okiepian andKlondikean Episodes; (2) from the end of the latter to the formalend of Namaquan Orogenesis 800–850 Ma ago. KEY WORDS: U–Pb, zircon; O'okiep, Namaqualand; granite plutonism; granulite facies; Koperberg Suite; Namaquan (Grenville) Orogeny     

Formation of Carbon and Hydrogen Species in Magmas at Low Oxygen Fugacity

Studies of iron-bearing silicate melt (ferrobasalt) + iron metallicphase + graphite + hydrogen equilibria show that carbon andhydrogen solubilities in melts are important for the evolutionof the upper mantle. In a series of experiments conducted at3·7 GPa and 1520–1600°C, we have characterizedthe nature (oxidized vs reduced) and quantified the abundancesof C- and H-compounds dissolved in iron-bearing silicate melts.Experiments were carried out in an anvil-with-hole apparatuspermitting the achievement of equal chemical potentials of H₂in the inner Pt capsule and outer furnace assembly. The fO₂for silicate melt–iron equilibrium was 2·32 ±0·04 log units below iron–wüstite (IW). Theferrobasalt used as starting material experienced a reductionof its iron oxides and silicate network. The counterpart wasa liberation of oxygen reacting with the hydrogen entering thecapsule. The amount of H₂O dissolved in the glasses was measuredby ion microprobe and by step-heating and was found to be between1 and 2 wt %. The dissolved carbon content was found to be 1600ppm C by step-heating. The speciation of C and H componentswas determined by IR and Raman spectroscopy. It was establishedthat the main part of the liberated oxygen was used to formOH^– and to a much lesser extent H₂O, and only traces ofH₂, CO₂ and