Improved description of global mixed-layer depth using Argo profiling floats

A global data set describing the gridded mixed-layer depth (MLD) in 10-day intervals was produced using high-quality Argo float data from 2001 to 2009. The characteristics and advantages provided by the new MLD data set are described here, including a comparison based on two different thresholds and using data sets of different vertical and temporal resolution. The MLD in the data set was estimated on the basis of a shallower depth of the iso-thermal layer (TLD) or iso-pycnal layer (PLD), calculated using the finite difference method. The MLD data are incorporated into 2° × 2° grid in the global ocean, including marginal seas. Also, two threshold values were used to examine differences in the MLD and its seasonal temporal variability. The characteristics and advantages of using the Argo 10-day intervals to determine the MLD were then confirmed by comparing those data with the station buoy daily means and the Argo monthly means. With respect to vertical and temporal resolutions, the Argo 10-day data has two distinct advantages: (1) improved representation of the MLD vertical change due to high vertical resolution, especially during periods of large MLD variability and (2) more detailed representation of the temporal change in MLD than achieved with the Argo monthly mean data, especially from winter to spring in mid and high latitudes. These advantages were maintained in the case of a larger threshold despite the fact that the MLD is rather deep and the detailed variation in its distribution differs depending on the season and location. This study also investigated the relative influence of TLD and PLD to the MLD calculation for each grid. Generally, the MLD is primarily determined based on the PLD at low and mid latitudes (TLD > PLD), whereas the TLD is more important at high latitudes, especially in winter (TLD < PLD). In the case of a larger threshold, the area of the larger PLD influence spreads polewards because of the greater effect of salinity in winter. Although there are some differences in the effect of temperature and salinity in estimations of the MLD, both are indispensable factors for the MLD estimations even at different thresholds.     

Seabed shear modulus profile inversion using surface gravity (water) wave-induced bottom motion

Summary. The motion of a layered seabed induced by propagating gravity water waves is modelled by the coupling matrix for a massless incompressible elastic bed according to Yamamoto. An amplitude inversion scheme is developed to extract the bottom shear modulus profile from the motion of the seabed at a point on the bed surface using the linear inverse theory combined with the Yamamoto theory of wave-seabed interaction. Numerical tests using synthetic data without noise confirmed that the inversion is unique and consistent. The inversion technique is applied to a set of field data from the Mississippi River Delta. A good agreement is obtained between the inverted profile and the direct measurements.     

Chemical compositions of refractory inclusions in the Murchison C2 chondrite

Samples from ten refractory inclusions in Murchison, some of which are splits of inclusions whose mineralogical and petrographic characteristics are known, have been analysed for thirty-six elements by neutron activation. Six inclusions have group II or group III patterns or variants of such patterns. Two inclusions, BB-5 and MUCH-1, have large negative Yb anomalies unaccompanied by correspondingly large negative Eu anomalies. It is possible that the latter condensed originally with group III patterns and preferentially took up Eu in later exchange processes under reducing conditions. One inclusion, SH-2, has heavy REE enrichment factors that increase with the refractoriness of the REE, indicating the presence of an extremely high-temperature, or ultrarefractory, REE condensate, but it also has a heavy REE/light REE ratio that indicates mixing of that component with a lower-temperature REE condensate. The frequency of highly fractionated REE patterns and absence of group I patterns suggest that refractory inclusions in Murchison stopped equilibrating with the nebular gas at higher temperatures than most Allende coarse-grained inclusions. The lower Ir/Os and Ru/Re ratios of some Murchison inclusions compared to those of Allende coarse-grained inclusions indicate that condensate alloys that contributed noble metals to the former also stopped equilibrating with the nebular gas at higher temperatures than those that contributed noble metals to the latter. Murchison inclusions tend to be lower in non-refractory elements than Allende coarse-grained inclusions, suggesting that, on average, the former underwent less severe secondary alteration than the latter.     

Chemical composition of HAL,an isotopically-unusual Allende inclusion

Thirty-seven major, minor and trace elements were determined by INAA and RNAA in samples of hibonite, black rim and portions of friable rim from an unusual Allende inclusion, HAL. The peculiar isotopic, mineralogical and textural properties of HAL are accompanied by very unusual trace element abundances. The most striking feature of the chemistry is the virtual absence of Ce from an inclusion otherwise highly enriched in REE compared to Cl chondrites. HAL is also depleted in Sr, Ba, U, V, Ru, Os and Ir, relative to other refractory elements. Of the lithophile elements determined which are normally considered to be refractory in a gas of solar composition, Sr, Ba, Ce, U and V are the most volatile in oxidizing gases. The distribution of REE between hibonite and rims seems to have been established when hibonite and other refractory minerals were removed at slightly different temperatures from a hot, oxidizing gas in which they previously coexisted as separate grains. On the basis of HAL's chemical and isotopic composition, possible locations for the chemical and mass dependent isotopic fractionation are in ejecta from the low temperature helium-burning zone of a supernova and in the locally oxidizing environment generated by evaporation of interstellar grains of near-chondritic chemical composition.     

Ion microprobe analysis of graphite from ca. 3.8 Ga metasediments, Isua supracrustal belt, West Greenland: Relationship between metamorphism and carbon isotopic composition

In-situ ion microprobe measurements of carbon isotopic compositions of graphite were made in seven metasediments and two carbonate rocks from the ca. 3.8 Ga Isua supracrustal belt, West Greenland. The δ¹³C values of micron-scale graphite globules in the metasediments and the carbonate rocks vary from -18 to +2‰ and from -7 to -3‰, respectively. The maximum δ¹³C value of graphite globules in the metasediment rises from -14 to -5‰, as the metamorphic grade increases from epidote-amphibolite to upper amphibolite facies. In a single hand specimen, the δ¹³C values of graphite inclusions in garnet are ∼7‰ lower on average than those outside garnet. Similarly, graphite armored by quartz apparently shows a few permil lower δ¹³C values than those on grain boundaries between noncarbonate minerals. The fact that early crystallized minerals include relatively ¹³C-depleted graphite indicates that the regional metamorphism increased the δ¹³C values of the Isua graphite. This is consistent with the regional trend of ¹³C-enrichment accompanied by the increase of metamorphic grade. The minimum fractionation between graphite and carbonate is consistent with the equilibrium fractionation at about 400 to 550 °C. These observations indicate that isotopic exchange with isotopically heavy carbonate caused ¹³C-enrichment of Isua graphite. The δ¹³C values of graphite reported here (δ¹³C > -18‰) were produced either as a metamorphic modification of organic carbon with initially much lower δ¹³C values, or as an abiological reaction such as decomposition of carbonate. If the isotopic exchange between carbonate and graphite during regional metamorphism controlled the ¹³C-enrichment of Isua graphite, previously reported large ¹³C-depletion of graphite, especially armored by apatite (Mojzsis et al., 1996) was probably premetamorphic in origin. This supports the existence of life at Isua time (ca. 3.8 Ga).     

Seasonality of the Interaction between Convection over the Western Pacific and General Circulation in the Northern Hemisphere

The seasonality of the interaction between convection over the western Pacific and general circulation in the Northern Hemisphere (NH) is analyzed in the present paper with singular value decomposition (SVD) and empirical orthogonal function (EOF) analysis approaches, based on 500 hPa monthly mean geopotential height data and high-cloud amount data. The analyses demonstrate that coupled dominant patterns in the interaction between the convection over the western Pacific and the general circulation in NH are different in various seasons. In spring, the convection over the western Pacific is closely related with the western Atlantic (WA) and North Pacific (NP) like patterns of the general circulation in NH, and some associations between the WA and NP like pat?terns and the El Ni?o / Southern Oscillation (ENSO) cycle are also existed. The Pacific Japan (PJ) pattern is the dom?inant pattern in the interaction between the interannual variabilities of the convection over the western Pacific and the general circulation in NH summer. The WA like pattern and 3-4 year period oscillation are also relatively obvious for the summer case. In autumn, the convection over the western Pacific is closely linked with the Eurasian (EU) like pattern and the Atlantic oscillation in the general circulation in NH, it is suggested that in autumn the vitiation of convective activity over the western Pacific is largely affected by the general circulation anomaly (cold air from high latitudes) through EU like teleconnection pattern. Abrupt change happened by the end of 1980’s in the autumn interaction. The strong interaction between the western Pacific (WP) and EU like patterns in the general circulation in NH and the convection over the western Pacific and a linear trend of increasing of this interaction are also suggested in winter. It is also demonstrated that the interaction in summer and winter is stronger than in the transition seasons (spring and autumn).     

Estimation of spectral refractive index of colloidal sulfur at 20°C

In the marine environment, colloidal sulfurs often occur due to the redox reaction of sulfide ions and oxygen molecules. It is important to know the spectral refractive index of colloidal sulfurs for the discussion of the light scattering in the region where colloidal sulfurs are formed. We presented new methods to estimate the refractive index from the wave length of maximum absorbance (turbidity) of a nearly mono-dispersed colloidal solution. In these methods, the ripples in a first main maximum of the scattering efficiency,Q _sca , were taken into consideration. By virtue of these methods, we obtained the spectral refractive index of colloidal sulfurs,m _s (), at 20°C. The Cauchy's expression of it was given by

In situ hydraulic tests in the active fault survey tunnel, Kamioka Mine, excavated through the active Mozumi-Sukenobu Fault zone and their hydrogeological significance

Abstract   The spatial hydrogeological and structural character of the active Mozumi-Sukenobu Fault (MSF) was investigated along a survey tunnel excavated through the MSF in the Kamioka Mine, central Japan. Major groundwater conduits on both sides of the MSF are recognized. One is considered to be a subvertical conduit between the tunnel and the surface, and the other is estimated to be a major reservoir of old meteoric water alongside the MSF. Our studies indicate that part of the MSF is a sub-vertical continuous barrier that obstructs younger meteoric water observed in the south-eastern part of the Active Fault Survey Tunnel (AFST) and water recharge to the rock mass intersected by the north-western part of the AFST. The MSF might be a continuous barrier resulting in the storage of a large quantity of older groundwater to the northwest. The observations and results of in situ hydraulic tests indicate that the major reservoir is not the fault breccia associated with the northeast–southwest trending faults of the MSF, but the zone in which blocks of fractured rocks occur beside high angle faults corresponding to X shears whose tectonic stress field coincides with the present regional stress field and antithetic Riedel shears of the MSF. The results from borehole investigations in the AFST indicate that secondary porosity is developed in the major reservoir due to the destruction of filling minerals and fracture development beside these shears. The increase in hydraulic conductivity is not directly related to increased density of fractures around the MSF. Development of secondary porosity could cause the increase in hydraulic conductivity around the MSF. Our results suggest that minor conduits of the fracture network are sporadically distributed in the sedimentary rocks around the MSF in the AFST.