Archaean fluid-assisted crustal cannibalism recorded by low δ<Superscript>18</Superscript>O and negative ε<Subscript>Hf(T)</Subscript> isotopic signatures of West Greenland granite zircon

The role of fluids during Archaean intra-crustal magmatism has been investigated via integrated SHRIMP U–Pb, δ¹⁸O and LA-MC-ICPMS ¹⁷⁶Hf isotopic zircon analysis. Six rock samples studied are all from the Nuuk region (southern West Greenland) including two ~3.69 Ga granitic and trondhjemitic gneisses, a 3.64 Ga granitic augen gneiss, a 2.82 Ga granodioritic Ikkattoq gneiss, a migmatite with late Neoarchaean neosome and a homogeneous granite of the 2.56 Ga Qôrqut Granite Complex (QGC). All zircon grains were thoroughly imaged to facilitate analysis of magmatic growth domains. Within the zircon analysed, there is no evidence for metamictization. Initial ε_Hf zircon values (n = 63) are largely sub-chondritic, indicating the granitic host magmas were generated by the remelting of older, un-radiogenic crustal components. Zircon from some granite samples displays more than one ²⁰⁷Pb/²⁰⁶Pb age, and correlated with ¹⁷⁶Hf/¹⁷⁷Hf compositions can trace multiple phases of remelting or recrystallization during the Archaean. Model ages calculated using Lu/Hf arrays for each sample indicate that the crustal parental rocks to the granites, granodiorites and trondhjemites segregated from a chondrite-like reservoir at an earlier time during the Archaean, corresponding to known formation periods of more primitive tonalite–trondhjemite–granodiorite (TTG) gneisses. Zircon from the ~3.69 Ga granite, the migmatite and QGC granite contains Eoarchaean cores with chondritic ¹⁷⁶Hf/¹⁷⁷Hf and mantle-like δ¹⁸O compositions. The age and geochemical signatures from these inherited components are identical to those of surrounding tonalitic gneisses, further suggesting genesis of these granites by remelting of broadly tonalitic protoliths. Zircon oxygen isotopic compositions (n = 62) over nine age populations (six igneous and three inherited) have weighted mean or mean δ¹⁸O values ranging from 5.8 ± 0.6 to 3.7 ± 0.5‰. The 3.64 Ga granitic augen gneiss sample displays the highest δ¹⁸O with a mildly supra-mantle composition of 5.8 ± 0.6‰. Inherited Eoarchaean TTG-derived zircon shows mantle-like values. Igneous zircon from all other samples, spanning more than a billion years of Archaean time, record low δ¹⁸O sub-mantle compositions. These are the first low δ¹⁸O signatures reported from Archaean zircon and represent low δ¹⁸O magmas formed by the remelting and metamorphism of older crustal rocks following high-temperature hydrothermal alteration by meteoric water. Meteoric fluid ingress coupled with crustal extension, associated high heat flow and intra-crustal melting are a viable mechanism for the production of the low δ¹⁸O granites, granodiorites and trondhjemites reported here. Both high and low δ¹⁸O magmas may have been generated in extensional environments and are distinct in composition from Phanerozoic I-type granitic plutonic systems, which are typified by increasing δ¹⁸O during intra-crustal reworking. This suggests that Archaean magmatic processes studied here were subtly different from those operating on the modern Earth and involved extensional tectonic regimes and the predominance of remelting of hydrothermally altered crystalline basement.     

Dissolved and particulate organic carbon in hydrothermal plumes from the East Pacific Rise, 9°50′N

Chemoautotrophic production in seafloor hydrothermal systems has the potential to provide an important source of organic carbon that is exported to the surrounding deep-ocean. While hydrothermal plumes may export carbon, entrained from chimney walls and biologically rich diffuse flow areas, away from sites of venting they also have the potential to provide an environment for in-situ carbon fixation. In this study, we have followed the fate of dissolved and particulate organic carbon (DOC and POC) as it is dispersed through and settles beneath a hydrothermal plume system at 9°50′N on the East Pacific Rise. Concentrations of both DOC and POC are elevated in buoyant plume samples that were collected directly above sites of active venting using both DSV Alvin and a CTD-rosette. Similar levels of POC enrichment are also observed in the dispersing non-buoyant plume, ∼500 m downstream from the vent-site. Further, sediment-trap samples collected beneath the same dispersing plume system, show evidence for a close coupling between organic carbon and Fe oxyhydroxide fluxes. We propose, therefore, a process that concentrates POC into hydrothermal plumes as they disperse through the deep-ocean. This is most probably the result of some combination of preferential adsorption of organic carbon onto Fe-oxyhydroxides and/or microbial activity that preferentially concentrates organic carbon in association with Fe-oxyhydroxides (e.g. through the microbial oxidation of Fe(II) and Fe sulfides). This potential for biological production and consumption within hydrothermal plumes highlights the importance of a multidisciplinary approach to understanding the role of the carbon cycle in deep-sea hydrothermal systems as well as the role that hydrothermal systems may play in regulating global deep-ocean carbon budgets.     

Geochemistry,mineralogy and tectonic setting of deerite‐bearing meta‐ironstones from the Emo Metamorphics of Papua New Guinea

The geochemistry of two deerite‐bearing meta‐ironstones from the Emo Metamorphics of Papua New Guinea suggests that they were deposited as metalliferous cherts enriched in manganese and iron by hydrothermal exhalative activity in an ocean ridge system. Subsequent blueschist facies metamorphism resulted in the formation of the assemblage deerite‐quartz‐albite‐iron oxides‐alkali amphiboles‐spessar‐tine‐stilpnomelane‐apatite, with calcium‐manganese carbonates in one specimen. Assemblages in associated metabasites suggest P‐T conditions of 7 kb at 320°C, which overlap with the P‐T field defined by one of the meta‐ironstones. Oxygen fugacity was probably an important control in determining variations in mineralogy and mineral chemistry. Preliminary data on the trace element geochemistry of associated metabasites are consistent with an ocean ridge environment for the formation of the meta‐ironstones.     

Transient discrimination using a subspace method [acoustic array signal processing]

This paper describes a method using a subspace algorithm that can be used to discriminate between signals. Discrimination is necessary to ensure that the same transient from different data records is used in processing. The subspace discrimination algorithm was tested against synthetic transients and found to discriminate well at high signal-to-noise ratios (SNRs).     

In situ permeabilities of selected coastal marine sediments

An in situ permeameter probe was deployed off Fort Walton Beach, Florida in shallow-water coastal sandy sediment. Stations were occupied in a 600 m /spl times/ 600 m area. Intrinsic permeability in sand at 17 stations varied from 0.3 to 6.1 /spl times/ 10/sup -11/ m/sup 2/ to subbottom depths of 50 cm. Permeability decreased with increasing subbottom depth and minimal compaction. The sediment is a well-sorted, medium quartz sand with a mean grain size of approximately 0.34-0.52 mm and with 5%-8% carbonate shells and shell fragments. The probe was tested in a slightly finer-grained sediment near the main study area and revealed permeabilities of 0.1-3.2 /spl times/ 10/sup -11/ m/sup 2/. The permeabilities measured are reasonable for the observed sandy and slightly finer-grained sediments.     

Water depth is a strong driver of intra-lake diatom distributions in a small boreal lake

There has been much debate over the relative importance of environmental selection and spatial variation on community organization in microorganisms. To assess the importance of environmental or spatial variables in diatom species assemblages in Gall Lake, northwest Ontario, 41 surface-sediment samples were collected in a two-dimensional gridded pattern along and across depth contours. A depth-constrained cluster analysis separated the diatom flora into three communities: a shallow-water benthic zone (B1); a deeper-water benthic zone (B2); and a planktonic zone (P). Redundancy analysis (RDA) confirmed that water depth was a major predictor of variation in the flora. Further RDAs and variation partitioning using orthogonal polynomials and Moran’s eigenvector maps showed that spatial location had minimal effect on the diatom assemblages. Principal components analysis grouped the diatom flora not only by assemblage, but also by water depth, regardless of two-dimensional spatial separation, suggesting the importance of the environmental gradients associated with lake depth. These findings indicate that environment is a more important explanatory variable than spatial variables for diatoms within lakes, suggesting dispersal plays a limited role in intra-lake diatom distributions.     

Groundwater flow,nutrient, and stable isotope dynamics in the parafluvial-hyporheic zone of the regulated Lower Colorado River (Texas,USA) over the course of a small flood

Periodic releases from an upstream dam cause rapid stage fluctuations in the Lower Colorado River near Austin, Texas, USA. These daily pulses modulate fluid exchange and residence times in the hyporheic zone where biogeochemical reactions are typically pronounced. The effects of a small flood pulse under low-flow conditions on surface-water/groundwater exchange and biogeochemical processes were studied by monitoring and sampling from two dense transects of wells perpendicular to the river. The first transect recorded water levels and the second transect was used for water sample collection at three depths. Samples were collected from 12 wells every 2 h over a 24-h period which had a 16-cm flood pulse. Analyses included nutrients, carbon, major ions, and stable isotopes of water. The relatively small flood pulse did not cause significant mixing in the parafluvial zone. Under these conditions, the river and groundwater were decoupled, showed potentially minimal mixing at the interface, and did not exhibit any discernible denitrification of river-borne nitrate. The chemical patterns observed in the parafluvial zone can be explained by evaporation of groundwater with little mixing with river water. Thus, large pulses may be necessary in order for substantial hyporheic mixing and exchange to occur. The large regulated river under a low-flow and small flood pulse regime functioned mainly as a gaining river with little hydrologic connectivity beyond a narrow hyporheic zone.     

Climate change scepticism and public support for mitigation: Evidence from an Australian choice experiment

Public scepticism surrounding climate change is an obstacle for implementing climate change mitigation measures in many countries. However, very little is known about: (1) the nature and sources of climate change scepticism; and (2) its influence on preferences for climate change mitigation policies. In this paper, we investigate these two issues using evidence and analysis from an Australian public survey and choice experiment. The study has three key findings. First, the intensity of scepticism varies depending on its type; we observed little scepticism over the cause, trend and impact of climate change and widespread scepticism over the effectiveness of mitigation measures and global co-operation. Second, cause and mitigation scepticism play significant roles in determining public support for climate change abatement. Respondents who believed in human-induced climate change were significantly more supportive of mitigation. Likewise, respondents who believed that mitigation would be successful in slowing down climate change were significantly more likely to be supportive. Third, the general public tend to give the benefit of the doubt to supporting mitigation. Those who expressed higher uncertainty about climate outcomes were more supportive of mitigation than others with similar expectations but lower uncertainty.