Petrographic and trace element analysis of uranium-rich tufa calcite, middle Miocene Barstow Formation, California, USA

An integrated petrographic and spectroscopic (X‐ray diffraction, phosphor imaging and synchrotron X‐ray absorption spectroscopy) study of tufas from the Miocene Barstow Formation, California, relates sample morphology, mineralogy and geochemical composition. The tufas, composed mainly of calcite that formed at the interface between an ancient alkaline lake and ground or spring waters, have textures similar to those of microbially mediated terrestrial stromatolites and travertines. The tufas have elevated concentrations of a number of trace elements including Mn, Fe, Sr and U. Synchrotron X‐ray fluorescence analyses show that U concentrations can exceed 500 p.p.m. X‐ray absorption spectroscopy indicates that the U in these samples is incorporated as U(IV). It is suggested here that alkaline lake waters had a high U/Ca ratio and tufa calcite formed where groundwater or (possibly epithermal) springs brought in Ca and trace elements such as Sr. The rapid, and possibly microbially mediated, precipitation of calcite allowed for incorporation of high concentrations of trace metals as either structural substitutes or extremely fine‐scale inclusions.     

Petrography of Lower Cretaceous sandstones on Spitsbergen

The sandstone petrography of sample suites from four sites spanning the Rurikfjellet (Hauterivian) to Carolinefjellet (Aptian-Albian) formations in central Spitsbergen was investigated. The sandstones show a distinct stepwise shift in composition from quartz arenites to sublitharenites and lithic arenites, typically within the upper part of the Helvetiafjellet Formation. This shift is related to the introduction of 10 - 25% (grain%) plagioclase grains and volcanic lithics, and a notable increase in basement and sedimentary lithics. Quartz grain character also changes, and grain shapes become more varied. The shift is also associated with the transgressive arrival of marine sediments in the area, and the introduction of sands from the east-northeast by shore-parallel transport. Regional regression and subsequent transgression, and the change in sandstone composition is attributed to the development of the High Arctic Large Igneous Province in the region. The relative constancy of sand composition and volume of volcanic detritus within the Carolinefjellet Formation suggests long term (∼20 M) stability of the sediment system and a large volcanic source area, consistent with LIP (Large Igneous Province) derivation, along with significant exposure of basement rocks. Sample spacing and sediment recycling and mixing do not allow detection of events that would have changed sandstone composition that were less than ∼1 M duration. Preservation of significant amounts of plagioclase in a sediment-starved shelf can be explained by relatively cold climatic conditions.     

Imaging the Hikurangi subduction zone, New Zealand, using teleseismic receiver functions: crustal fluids above the forearc mantle wedge

We image the Hikurangi subduction zone using receiver functions derived from teleseismic earthquakes. Migrated receiver functions show a northwest dipping low shear wave feature down to 60 km depth, which we associate with the crust of the subducted Pacific Plate. Receiver functions (RF) at several stations also show a pair of negative and positive polarity phases with associated conversion depths of ∼20–26 km, where the subducted Pacific Plate is at a depth of ∼40–50 km beneath the overlying Australian Plate. RF inversion solutions model these phases with a thin low S -wave velocity zone less than 4 km thick, and an S -wave velocity contrast of more than ∼0.5 km s⁻¹ with the overlying crust. We interpret this phase pair as representing fluids near the base of the lower crust of the Australian Plate, directly overlying the forearc mantle wedge.     

Ambient noise Rayleigh wave tomography of New Zealand

We present the first New Zealand-wide study of surface wave dispersion, using ambient noise observed at 42 broad-band stations in the national seismic network (GeoNet) and the Global Seismic Network (GSN). Year-long vertical-component time-series recorded between 2005 April 1 and 2006 March 31 have been correlated with one another to yield estimated fundamental mode Rayleigh wave Green's functions. We filter these Green's functions to compute Rayleigh wave group dispersion curves at periods of 5–50 s, using a phase-matched filter, frequency–time analysis technique. The uncertainties of the measurements are estimated based on the temporal variation of the dispersion curves revealed by 12 overlapping 3-month stacks. After selecting the highest quality dispersion curve measurements, we compute group velocity maps from 7 to 25 s period. These maps, and 1-D shear wave velocity models at four selected locations, exhibit clear correlations with major geological structures, including the Taranaki and Canterbury Basins, the Hikurangi accretionary prism, and previously reported basement terrane boundaries.     

Direct and Indirect Interactions Between Lower Estuarine Mangrove and Saltmarsh Habitats and a Commercially Important Penaeid Shrimp

Vegetated habitats in estuaries may provide a structural refuge and food supply in the same place, but benefits are also derived where a productive food source and suitable habitat are adjacent to each other. Quantifying these relationships is fundamental to understanding the structural and functional characteristics of estuarine ecosystems and for informing management actions. Effective juvenile habitat (habitat that contributes greater-than-average numbers of recruits to the adult population), recruitment patterns and trophic relationships were studied for Eastern King Prawn (Penaeus plebejus) in the lower Clarence River estuary, New South Wales, between 2014 and 2016. Effective juvenile habitat was identified in both the north arm and main river channel of the estuary, and these areas also supported a higher abundance of juvenile prawns. There was minimal recruitment to the southern channels of the estuary, possibly due to reduced connectivity with the incoming tide arising from a rock wall. Trophic relationships in parts of the lower estuary were evaluated using stable isotopes, and saltmarsh grass (Sporobolus virginicus) was the dominant primary producer supporting juvenile Eastern King Prawn productivity across the area. Mangroves were of minimal importance, and seagrass cover was minimal in the area studied. The patterns observed indicate that nursery function of different areas within the lower estuary is a product of connectivity, recruitment and nutrition derived from primary productivity of vascular plants. Habitats within the lower Clarence River estuary have seen substantial degradation over decadal time scales, and the implications of our findings for targeting future habitat repair are discussed.     

Non-destructive assessment of polycyclic aromatic hydrocarbon (PAH) exposure by fluorimetric analysis of crab urine

The detection of urinary polycyclic aromatic hydrocarbon (PAH) metabolites by fluorescence spectrophotometry is particularly effective as a practical means to assess PAH exposure in decapod crabs. However, the practical application of this technique has thus far only been tested for the European shore crab (Carcinus maenas) and only a few field studies have been conducted in heavily polluted areas. The present study evaluated the adaptability of this method as a rapid, cost-effective and non-destructive biomonitoring tool for the New Zealand crab species, Macrophthalmus hirtipes (stalk-eyed mud crab). A field gradient could be detected among the sites and different input sources of PAH contamination could be discerned through the differentiation of pyrogenic and petrogenic PAH signatures. The present study shows that the fluorescence screening method is sensitive to relatively low levels of PAH contamination and more broadly applicable to smaller crab species than C. maenas, for which the technique was developed.