Formation and diagenesis of bedding cycles in uppermost Cretaceous chalks of the Dan Field, Danish North Sea

Metre-scale lithologic cycles, visible in core and on logs from Maastrichtian chalks of the Dan Field, were examined to determine their mechanisms of deposition and relation to hydrocarbon production. The lower parts of cycles consist of porous, cream-coloured, largely non-stylolitic, commonly laminated chalk with limited bioturbation (mainly escape burrows). Cycles are capped by thinner intervals of white to grey, hard, stylolitic chalk with concentrations of bioclastic material, intense burrowing and few preserved primary sedimentary structures. The cycle caps contain nearly twice as much Mg as compared to the more porous parts of cycles and also have slightly larger δ¹⁸O values (?4·1‰ for the caps; ?4·4‰ for porous zones). There is a significant reduction of average cycle thickness, as well as total thickness of the Maastrichtian chalk section, from SW to NE across the Dan Field. The cycle thinning largely results from a reduced thickness of porous chalks from the lower parts of cycles and thus is reflected in lower average porosity and permeability on the NE side of the field. These data indicate that episodic winnowing removed fine-grained constituents from highstanding northeastern areas. Porous cycle bases were deposited at relatively high rates that precluded complete bioturbation; preserved laminae, coupled with escape burrows, reflect episodic sediment influx in areas that flank the seafloor highs. Cycle tops apparently accumulated more slowly (throughout the region, but especially on seafloor highs), perhaps because of reduced productivity of planktic organisms. Slower sedimentation allowed more complete bioturbation and destruction of sedimentary structures, and also led to incipient high-magnesium calcite seafloor cementation (sufficient to yield firmer sediment and enhanced burrow preservation, but not to form true hardgrounds). Thus, the elevated magnesium contents and reduced porosity of the cycle caps reflect very early diagenetic processes that were only partially modified by burial diagenesis. Rates of chalk deposition, as inferred from physical and geochemical evidence, appear to be a significant control on reservoir characteristics in North Sea chalks. The highest average porosities and permeabilities are found in areas with the highest sediment accumulation rates where seafloor diagenesis is minimized. Topographic depressions at the time of sedimentation can thus be expected to have the best production characteristics, and synsedimentary topographic highs should have the thinnest sections and the poorest petrophysical properties.     

Advanced Marginality as a comparative research strategy in praxis: the Danish “Grey Belt” in conversation with the French “Red Belt”

Urban Outcast and advanced marginality belongs to a theory culture rarely engaged in comparative urban studies. Here the potential of advanced marginality as a comparative research strategy is explored paying special attention to the concepts of epistemic reflexivity, analogical reasoning and homology. These concepts are applied as the foundation of a comparative research design comprising three necessary and interconnected analytical moments linking reflexivity, theory and empirical analysis. Empirically this strategy and design is confronted in the case of four Danish “Grey belt” housing estates. The empirical confrontation demonstrates that both strategy and design are relevant and productive. Nevertheless, there is a need to question, adapt and extent the six original properties of advanced marginality. Secondly the empirical confrontation demonstrates that both strategy and design can contribute to the current conversations on the comparative in urban studies empirically and conceptually, underscoring the curiosity of its eclipse in these conversations.     

A Textural Record of Solidification and Cooling in the Skaergaard Intrusion, East Greenland

The clinopyroxene–plagioclase–plagioclase dihedralangle, _cpp, in gabbroic cumulates records the time-integratedthermal history in the sub-solidus and provides a measure oftextural maturity. Variations in _cpp through the Layered Seriesof the Skaergaard intrusion, East Greenland, demonstrate thatthe onset of crystallization of clinopyroxene (within LZa),Fe–Ti oxides (at the base of LZc) and apatite (at thebase of UZb) as liquidus phases in the bulk magma is recordedby a stepwise increase in textural maturity, related to an increasein the contribution of latent heat to the total heat loss tothe surroundings and a reduction in the specific cooling rateat the crystallization front of the intrusion. The onset ofboth liquidus Fe–Ti oxide and apatite crystallizationis marked by a transient increase in textural maturity, probablylinked to overstepping before nucleation. Textural maturationat pyroxene–plagioclase–plagioclase triple junctionseffectively ceases in the uppermost parts of the Layered Seriesas a result of the entire pluton cooling below the closure temperaturefor dihedral angle change, which is 1075°C. Solidificationof the Layered Series of the Skaergaard intrusion occurred viathe upwards propagation of a mush zone only a few metres thick. KEY WORDS: magma; partial melting; asthenosphere; olivine; mantle     

Evaluation of MODFLOW-LGR in connection with a synthetic regional-scale model

This work studies costs and benefits of utilizing local-grid refinement (LGR) as implemented in MODFLOW-LGR to simulate groundwater flow in a buried tunnel valley interacting with a regional aquifer. Two alternative LGR methods were used: the shared-node (SN) method and the ghost-node (GN) method. To conserve flows the SN method requires correction of sources and sinks in cells at the refined/coarse-grid interface. We found that the optimal correction method is case dependent and difficult to identify in practice. However, the results showed little difference and suggest that identifying the optimal method was of minor importance in our case. The GN method does not require corrections at the models' interface, and it uses a simpler head interpolation scheme than the SN method. The simpler scheme is faster but less accurate so that more iterations may be necessary. However, the GN method solved our flow problem more efficiently than the SN method. The MODFLOW-LGR results were compared with the results obtained using a globally coarse (GC) grid. The LGR simulations required one to two orders of magnitude longer run times than the GC model. However, the improvements of the numerical resolution around the buried valley substantially increased the accuracy of simulated heads and flows compared with the GC simulation. Accuracy further increased locally around the valley flanks when improving the geological resolution using the refined grid. Finally, comparing MODFLOW-LGR simulation with a globally refined (GR) grid showed that the refinement proportion of the model should not exceed 10% to 15% in order to secure method efficiency.     

丹麦北部浅层生物气的渗漏与聚集作用

在丹麦北部的陆上和海底沉积物中浅层气分布十分普遍。来自海底两个渗漏区的天然气主要由CH4和少量的N2、CO2和O2组成(表1)。样品中未检测出存在有重烃。表1海底渗漏区气体的化学成分和同位素组成Table 1 Chemical and isotopic composition ofgas from submarine seeps地点水深/mCH4/%CO2/%N2/%O2+Ar/%δ13CCH4(‰)δ2HCH4(‰)NordreRonner12 94·8 2·1 3·0 0·1-68·4-191Hirsholmene 10 98·6 0·3 0·8 0·2-65·3-168上述两个渗漏区甲烷的C、H同位素比率(表1)表明,天然气为CO2降解产生的细菌成因气。细菌成因气的另外一…     

Observations of beach cusps

Aagaard. Troels: Observations of beach cusps. Geografisk Tidsskrift 85: 27–31 Copenhagen, October 1985.

Observations of beach cusps have been conducted under low-energy conditions on the northern coast of Zealand, Denmark. The distance between cusps showed consistently good correlation with values calculated from a hypothetical occurrence of synchronous or subharmonic edge waves. A relationship is implied between the edge wave frequency and the value of the surf scaling parameter. Supplementary observations from the southern coast of England indicate that the edge wave theory may not be adequate in explaining the distance between cusps on pocket beaches.     

Extending Data Worth Analyses to Select Multiple Observations Targeting Multiple Forecasts

Hydrological models are often set up to provide specific forecasts of interest. Owing to the inherent uncertainty in data used to derive model structure and used to constrain parameter variations, the model forecasts will be uncertain. Additional data collection is often performed to minimize this forecast uncertainty. Given our common financial restrictions, it is critical that we identify data with maximal information content with respect to forecast of interest. In practice, this often devolves to qualitative decisions based on expert opinion. However, there is no assurance that this will lead to optimal design, especially for complex hydrogeological problems. Specifically, these complexities include considerations of multiple forecasts, shared information among potential observations, information content of existing data, and the assumptions and simplifications underlying model construction. In the present study, we extend previous data worth analyses to include: simultaneous selection of multiple new measurements and consideration of multiple forecasts of interest. We show how the suggested approach can be used to optimize data collection. This can be used in a manner that suggests specific measurement sets or that produces probability maps indicating areas likely to be informative for specific forecasts. Moreover, we provide examples documenting that sequential measurement election approaches often lead to suboptimal designs and that estimates of data covariance should be included when selecting future measurement sets.     

Fate of Point‐Source Pesticide Spill in Clayey Till after 15 Years

This study investigated the development of pesticide pollution two, three, and 17 years after spills of the herbicides dichlorprop, mecoprop (MCPP), MCPA, 2,4‐D (phenoxy acids), simazine, and terbutylazine (triazines) in a former orchard machinery service yard. The spills had occurred over several decades on a 23‐m thick, mainly anaerobic fractured clayey till aquitard. Angled monitoring wells were installed in the aquitard 3 years after the spills ceased in 1989. In 1993, monitoring revealed that high groundwater concentrations of dichlorprop (677 µg/L) and MCPP (139 µg/L) were accumulated as a zone of maximum pollution in anaerobic and largely immobile pore water at 5 to 6 m depth in the aquitard profile. In contrast, 2,4‐D was determined in only one water sample, and MCPA and simazine and terbutylazine were determined only in low concentrations (below10 µg/L), although these pesticides had been handled at the site in greater amounts than dichlorprop and MCPP according to detailed historic information obtained for the site. Repeated monitoring in the same wells after a further 14 years in 2007 revealed that no identifiable degradation of MCPP had occurred, while dichlorprop had degraded by 75% to 80% (estimated half‐life of approximately 5 years). Furthermore, degradation products related to the phenoxy acids had accumulated, especially 4‐CPP with a maximum concentration of 218 µg/L. In the same zone, MCPA and simazine had almost disappeared. As the pollution was mainly accumulated in largely immobile pore water of the aquitard clayey matrix, and the groundwater recharge was low (30 to 60 mm/year), only minor vertical displacement of the zone with maximum pollution zone had occurred during the 15 years of monitoring. However, concentrations of dichlorprop (0.01 to 0.02 µg/L), MCPP (0.1 to 0.2 µg/L), and 4‐CPP (0.6 to 0.7 µg/L) had spread along textural heterogeneities in the aquitard into the underlying sandy aquifer at 23‐m depth.     

Coastal profile response to sea level rise: a process‐based approach

Prevailing ideas and calculations of coastal response to sea level rise (SLR) are often based on the Bruun model (Bruun P., Sea‐level rise as a cause of shore erosion, Journal Waterways Harbors Division, ASCE 88 : 117–130, 1962) that predicts upward and landward transfer of an equilibrium profile during SLR through offshore sediment transport on the shoreface. The model is based on a number of assumptions of questionable validity as well as outdated concepts on how sediment is transported across the shoreface. This contribution takes a numerical modelling approach that is based on first‐order processes contributing to the movement of sediment across the shoreface. Using a wave transformation model that predicts hydrodynamic processes driving cross‐shore sediment transport and an energetics‐based model for the coupling between hydrodynamics and sediment transport, we show that cross‐shore sediment transport is mainly onshore directed at the boundary between the lower and the upper shoreface, in agreement with the model proposed by Davidson‐Arnott (Conceptual model of the effects of sea level rise on sandy coasts, Journal of Coastal Research 21 : 1166–1172, 2005). The transition from onshore to offshore directed transport is located well within the surf zone and with a rising sea level this transition point becomes displaced landward and upward. Tests also show that substrate slope is of fundamental importance to the manner in which beaches react to rising sea level. Copyright © 2012 John Wiley & Sons, Ltd.     

Textural Maturity of Cumulates: a Record of Chamber Filling, Liquidus Assemblage, Cooling Rate and Large-scale Convection in Mafic Layered Intrusions

Textural maturity describes the extent to which a rock has evolvedfrom the initial reaction-controlled texture towards texturalequilibrium controlled by the minimization of interfacial energy.Solidification in a magma chamber results in the formation ofan impingement texture by the random juxtaposition of planar-sidedgrains. Orthocumulates, in which the initial melt-filled poresare pseudomorphed by later-crystallizing phases, have an ophiticor intersertal texture immediately after complete solidification,which then evolves towards solid-state equilibrium by roundingof initially planar grain boundaries and an increase in themedian dihedral angle subtended at the junctions of two primocrysticgrains with the interstitial phase. The bulk of the increasein angle occurs just below the solidus temperature in kilometre-scalemafic plutons. Quantification of textural maturity via measurementof dihedral angle populations in troctolitic and gabbroic cumulatesfrom the Rum Eastern Layered Intrusion and the Skaergaard Intrusiondemonstrates that the rocks preserve a record of thermal eventsrelated to magma chamber replenishment and the onset of chamber-wideconvection. Textural maturity is also a function of the liquidusphase assemblage: for systems in which only olivine and plagioclaseare liquidus (i.e. cumulus) phases in the main magma body abovethe crystal mush, the texture is significantly less mature thanthat in systems in which clinopyroxene is an additional liquidusphase. The difference in textural maturity reflects differencesin the cooling and solidification rate, and demonstrates directlythat the liquidus phase assemblage plays a role in determiningthe thermal history of plutons. KEY WORDS: cumulates; dihedral angles; Rum; Skaergaard; textures