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61.
The spectrometers of the Cassini mission to the Saturn system have detected haze layers reaching up to 800 km in Titan’s atmosphere. Knowledge of the complex refractive index (k) of the haze is important for modeling the surface and atmosphere of Titan and retrieving some information about the functional groups present in the aerosols. Plasma discharges or ultraviolet radiation are commonly used to drive the formation of solid organics assumed to be good analogs of the Titan aerosols. [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. The photochemical formation of a Titan haze analog. Structural analysis by X-ray photoelectron and infrared spectroscopy. Icarus 162, 114-124; Tran, B.N., Force, M., Briggs, R., Ferris J.P., Persans, P., Chera, J.J., 2008. Photochemical processes on Titan: Irradiation of mixtures of gases that simulate Titan’s atmosphere. Icarus 177, 106-115] reported the index of refraction of analogs synthesized by far ultraviolet irradiation of various gas mixtures. k was determined in the 200-800 nm wavelength range from transmission and reflection spectroscopy. However, this technique is limited by (i) uncertainties in the absorption values because of the small amounts of organics available, (ii) light scattering by the surface roughness and particulates in the sample. These limitations prompted us to perform new measurements using photothermal deflection spectroscopy (PDS), a technique based on the conversion of absorbed light into heat in the material of interest. By combining traditional spectroscopy (λ < 500 nm) and PDS (λ > 500 nm), we determined values of k over the 375-1550 nm range. k values as low as 10−4 above 1000 nm were determined. This is one order of magnitude lower than the measurements generally used as a reference for Titan’s aerosols analogs [Khare, B.N., Sagan, C., Arakawa, E.T., Suits, F., Callicott, T.A., Williams, M.W., 1984. Optical-constants of organic Tholins produced in a simulated Titanian atmosphere—from soft-X-ray to microwave-frequencies. Icarus 60(1), 127-137]. We recommend that these results were used in models to describe the optical properties of the aerosols produced in Titan’s stratosphere. 相似文献
62.
Tin C. Tran Emmanuelle Grosjean Philip J. Marriott 《Geochimica et cosmochimica acta》2010,74(22):6468-6484
A comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry (GC × GC/TOFMS) method has been developed for separation of a series of petroleum samples using a polar/non-polar column set configuration. Groups of oils were selected to provide samples from the same oil family to assist in comparison of compositional changes during biodegradation. The groups also represented different sources and ages to allow an assessment of the application of GC × GC for the differentiation of oil source, as well as fluid history. The increased resolution and separation afforded by the GC × GC technique provides more complete compositional information on complex biodegraded oil samples than one-dimensional GC, and improves the ability to study biodegradation trends. Among the components identified, it is proposed that alkyl-decahydronaphthalenes constitute a significant contribution to the UCM. 相似文献
63.
Anh Phan Luu Vladimirov A. G. Kruk N. N. Polyakov G. V. Ponomarchuk V. A. Hoa Tran Trong Phuong Ngo Thi Kuibida M. L. Annikova I. Yu. Pavlova G. G. Kiseleva V. Yu. 《Doklady Earth Sciences》2010,432(2):839-845
Doklady Earth Sciences - Stanniferrous granite-leucogranite massifs in Vietnam to which the bedrock and placer commercial deposits of cassiterite are associated (Timtuc etc.) are of late Cretaceous... 相似文献
64.
Xuan Thanh Pham Bernard Fontaine Nathalie Philippon 《Theoretical and Applied Climatology》2010,99(1-2):105-113
The summer monsoon onset over southern Vietnam is determined through a new criterion based on both in situ daily rainfall at six selected stations provided by the Institute of Meteorology and Hydrology, Vietnam, and the zonal component of the wind at 1,000 hPa from the National Center for Environmental Prediction/Department of Energy Reanalysis 2. Over the period 1979–2004, the summer monsoon onset mean date is on 12 May, with a standard deviation of 11.6 days. The temporal and spatial structures of the atmospheric conditions prevailing during the onset period are detailed. Clear changes are seen in the zonal wind (strengthened over the Bay of Bengal and changed from negative to positive over South Vietnam) and in convection (deeper), in association with an intensification of the meridional gradients of sea level pressure at 1,000 hPa and of moist static energy at 2 m over Southeast Asia. The predictability of onset dates is then assessed. Cross-validated hindcasts based upon four predictors linked to robust signals in the atmospheric dynamics are then provided. They are highly significant when compared to observations (56% of common variance). Basically, late (early) onsets are preceded in March–April by higher (lower) sea level pressure over the East China Sea, stronger (weaker) southeasterly winds over southern Vietnam, decreasing (increasing) deep convection over the Bay of Bengal, and the reverse situation over Indonesia (120–140°E, 0–10°S). 相似文献
65.
Quang Thanh Nguyen Sabine Caré Yves Berthaud Alain Millard Frédéric Ragueneau 《国际地质力学数值与分析法杂志》2011,35(10):1141-1159
Most reinforced concrete structures are damaged due to corrosion of reinforcements in concrete. In normal conditions the pH near the reinforcements is around 12–13 which means that steel is in a passive state. But aggressive species, such as chloride ions or carbon dioxide, may penetrate into concrete and promote active corrosion. As a consequence (hydro)oxides are produced leading to degradation of concrete structures. For instance cracking of the concrete is generated due to the pressure induced by rust. In this paper, we study the inception and the propagation of cracking on reinforced mortar plates with rebars located either in the middle or at the corner. Additional experiments have been performed on cylindrical specimens to determine the local effect of rust pressure at the interface rust/mortar. The specimens have been subjected to imposed current density in order to enhance the corrosion and digital image intercorrelation has been used to determine displacement fields. The experiments have been compared to numerical modelling. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
66.
D. Lutz R. Genzel D. Kunze D. Rigopoulou H.W.W. Spoon E. Sturm D. Tran A.F.M. Moorwood 《Astrophysics and Space Science》1999,266(1-2):85-90
Spectroscopy from the Infrared Space Observatory ISO has for the first timeprovided the sensitivity to exploit the diagnostic power ofmid-infrared fine structure lines and PAH features for the study ofultraluminous infrared galaxies (LIR >1012
L
). We report on observations obtainedwith SWS, ISOPHOT-S, and the CVF option of ISOCAM. From both fine structure lines and PAH features, we find that the majority of ULIRGs is predominantlypowered by star formation. Our total sample of about 75 ULIRGs allows tosearch for trends within the class of ULIRGs: The fraction of AGNs increaseswith luminosity above 3 × 1012L but there is no obvioustrend for ULIRGs to be more AGN-like with more advanced merger phase. 相似文献
67.
The subsurface transport of heat and moisture and its effect on the environment: A numerical model 总被引:2,自引:0,他引:2
A numerical model was developed to study the transport of heat and vapor under the surface of bare soil and soil covered by some materials such as asphalt and concrete under no rainfall conditions. The computational results provide a good match with the experimental data. The results show that the transport of water vapor inside the soil has an important effect on the subsurface distribution of temperature, especially for bare soil. Because of evaporation, the temperature of bare soil is much lower than that under covered surfaces throughout the day and the temperature of the surface covered by asphalt is extremely high-higher than the atmospheric temperature even at night. An increase of thickness of the covering material further increases the temperature and heat stored under surfaces. The stored heat is released to the atmosphere at night, contributing to environmental effects such as the urban heat island. 相似文献
68.
Yi Yong Park Suong Oh Lee Tam Tran Seong Jun Kim Myong Jun Kim 《International Journal of Mineral Processing》2006,80(2-4):126-132
A simple process to produce fine and low soda α-alumina (α-Al2O3) from a commercial grade aluminium trihydroxide (gibbsite, Al(OH)3) produced by KC Corporation Ltd was developed. There are two options for this process with the first one producing low soda α-alumina (< 0.05% Na2O) having a mean particle size of 50 μm. The second option yields a fine product with a mean size of less than 10 μm. In the first option, a plant aluminium trihydroxide containing 0.20% Na2O was first fluidized with nitrogen at 400–600 °C to yield an amorphous activated alumina. This intermediate product was then treated with acetic or oxalic acid, washed with water and heated to 1200 °C to form calcined α-alumina, having a Na2O content of less than 0.05%. A 20 min leaching using 0.2 M acetic or oxalic acid could yield an alumina product containing 0.04% Na2O. In the second option, a new technique for the preparation of fine and low soda α-alumina was evaluated using an attrition mill working also as a leaching vessel at 80 °C. Fine (< 10 μm in mean particle size) and low soda (< 0.04% Na2O) alumina was produced by a 20 min leaching step with 0.2 M acetic acid and concurrent attrition milling. 相似文献
69.
Mathematical Geosciences - 相似文献
70.
Given a precision threshold to be imposed on the group velocity error and a finite difference scheme for the acoustic wave equation, it is possible to determine time-step and grid-spacing in an optimal manner, i.e., so as to minimize the computational cost. Using this optimal cost as a criterion, it becomes easy to compare schemes for efficiency in homogeneous media. Heterogeneous media with constant density can be accommodated to a certain extent by minimizing the cost over a range of Courant numbers. Such analysis shows that, amongst the second-order Taylor series schemes in time, higher-order schemes are generally more efficient than lower-order schemes. However, this result does not extend to very high order schemes. 相似文献