High pressure phase equilibria in the system CaTiO3-CaSiO3: stability of perovskite solid solutions

Phase relations in the system CaTiO₃-CaSiO₃ were experimentally examined at 5.3–14.7 GPa and 1200–1600 °C with a 6–8 type multianvil apparatus. As pressure increases, stability field of perovskite solid solution extends from CaTiO₃ to CaSiO₃, and the perovskite becomes stable for the entire composition range above about 12.3 GPa. The stability field of Ca(Ti_1?X, Si_X)₂O₅ (0.78<x≦1) titanite solid solution +Ca₂SiO₄ larnite exists in the CaSiO₃-rich composition range at 9.3–12.3 GPa and 1200 °C. Perovskite solid solutions containing CaSiO₃ component of 0 to 66 mol% could be quenched to 1 atm. The composition-molar volume relationship of perovskite solid solution showed that molar volume of perovskite solid solution linearly reduces from the value of CaTiO₃ to that of CaSiO₃.     

Effects of hypoxia on benthic organisms in Tokyo Bay, Japan: a review

Bottom hypoxia (dissolved oxygen concentration ≤2 ml l(-1)) from anthropogenic eutrophication is a growing global concern. Here, we summarized characteristics of hypoxia and its effects on benthic organisms in Tokyo Bay. Despite recent decreases in nutrient inputs, hypoxia has been increasing in duration and spatial extent, suggesting that the substantial loss of tidal flats from reclamation is contributing to a decrease in the ability of Tokyo Bay to recycle nutrients. Hypoxia develops in the central to northern part of the bay and persists from spring to autumn, causing defaunation of benthic organisms. After the abatement of hypoxia in autumn, the defaunated area is recolonized, either through migration or larval settlement. Some megabenthic species with a spawning peak in spring and summer experience failure of larval settlement, which is probably due to hypoxia. The adverse effects of hypoxia are an impediment to recovery of benthic organisms in Tokyo Bay.     

Naturally occurring radionuclides and rare earth elements in weathered Japanese soil samples

The activity concentrations of ²²⁶Ra and ²²⁸Ac in weathered Japanese soils from two selected prefectures have been measured using a γ-ray spectroscopy system with high purity germanium detector. The uranium, thorium, and rare earth elements (REEs) concentrations were determined from the same soil samples using inductively coupled plasma mass spectrometry (ICP-MS). For example, granitic rocks contain higher amounts of U, Th, and light REEs compared to other igneous rocks such as basalt and andesites. Therefore, it is necessary to understand the interaction between REEs and nature of soils since soils are complex heterogeneous mixture of organic and inorganic solids, water, and gases. In this paper, we will discuss about distribution pattern of ²³⁸U and ²³²Th along with REEs in soil samples of weathered acid rock (granite) collected from two prefectures of Japan: Hiroshima and Miyagi.     

Human impacts on large benthic foraminifers near a densely populated area of Majuro Atoll, Marshall Islands

Human impacts on sand-producing, large benthic foraminifers were investigated on ocean reef flats at the northeast Majuro Atoll, Marshall Islands, along a human population gradient. The densities of dominant foraminifers Calcarina and Amphistegina declined with distance from densely populated islands. Macrophyte composition on ocean reef flats differed between locations near sparsely or densely populated islands. Nutrient concentrations in reef-flat seawater and groundwater were high near or on densely populated islands. δ¹⁵N values in macroalgal tissues indicated that macroalgae in nearshore lagoons assimilate wastewater-derived nitrogen, whereas those on nearshore ocean reef flats assimilate nitrogen from other sources. These results suggest that increases in the human population result in high nutrient loading in groundwater and possibly into nearshore waters. High nutrient inputs into ambient seawater may have both direct and indirect negative effects on sand-producing foraminifers through habitat changes and/or the collapse of algal symbiosis.     

Field measurements of absolute gravity in East Antarctica

Abstract This paper reports the results of field-based absolute gravity measurements aimed at detecting gravity change and crustal displacement caused by glacial isostatic adjustment. The project was initiated within the framework of the 53rd Japanese Antarctic Research Expedition （JARE53）. Absolute gravity measurements, together with GPS measurements, were planned at several outcrops along the Prince Olav Coast and S6ya Coast of East Antarctica, including at Syowa Station. Since the icebreaker Shirase （AGB 5003） was unable to moor alongside Syowa Station, operations were somewhat restricted during JARE53. However, despite this setback, we were able to complete measurements at two sites： Syowa Station and Langhovde. The absolute gravity value at the Syowa Station IAGBN （A） site, observed using an FG-5 absolute gravimeter （serial number 210; FG-5 #210）, was 982 524 322.7＋0.1 ktGal, and the gravity change rate at the beginning of 2012 was -0.26 gGal.a-1. An absolute gravity value of 982 535 584.2~0.7 ktGal was obtained using a portable A-10 absolute gravimeter （serial number 017; A-10 #017） at the newly located site AGS01 in Langhovde.     

Thermal Evolution of the Phaethon–Geminid Stream Complex

The thermal evolution of the Geminid meteor stream and the Phaethon–Geminid stream Complex (PGC) are summarized. Sodium contents of Geminid meteor streams are altered thermally, perhaps during orbital motion in interplanetary space due to the short perihelion distance of the orbit (q ～ 0.14 AU). However, the temperature of meteoroids is less than the sublimation temperature of Na in alkali silicates, suggesting that the parent body 3200 Phaethon itself might have suffered from the thermal processing. On the other hand, a breakup event on PGC parent is suggested by the existence of dynamically associated asteroids (Phaethon, 2005 UD and 1999 YC) sharing pristine features (C, B types). A possible mechanism behind the breakup is the sublimation of ice inside the PGC parent due to its thermal evolution. It is tempting to guess that the PGC parent might be evolved dynamically from the outer part of the main asteroid belt where the residence of ice-rich asteroids (main belt comets) into current PGC-like orbit.     

Seismic velocity discontinuities in the crust and uppermost mantle beneath the Kanto district, central Japan, identified from receiver function imaging and repeating earthquake activity

We constructed vertical cross-sections of depth-converted receiver function images to estimate the seismic velocity structure of the crust and uppermost mantle beneath the Kanto district, central Japan. Repeating earthquake data for the plate boundary were also used to estimate geometries of the subducting Philippine Sea plate and the subducting Pacific plate. As a result, we present images of some major seismic discontinuities. The upper boundary of the Pacific plate dips to the northwest in northern Kanto and to the west–southwest in southern Kanto with some undulations. On the other hand, the upper boundary of the Philippine Sea plate as a whole dips to the northwest. However, it is concave to the northeast in the southern Boso peninsula. We suggest that the low-velocity mantle wedge may be indicated on the top of both subducting plates. Plate thickness gradually decreases to the northeast. The northeastern end of the Philippine Sea plate is interpreted to be at depths of 45–90 km. The Moho discontinuity in the overriding plate is deeper than 25 km in the northern Kanto. It contacts the subducting Philippine Sea plate in the southwestern part near 35.8°N.     

Quasi-static slip on the plate boundary associated with the 2003 M8.0 Tokachi-oki and 2004 M7.1 off-Kushiro earthquakes, Japan

We analyzed small repeating earthquakes recorded over a 13-year period and GPS data recorded over an 8-month period to estimate interplate quasi-static slip associated with the 2003 Tokachi-oki earthquake (M8.0) and the 2004 off-Kushiro earthquake (M7.1). The repeating-earthquake analysis revealed that the slip rate near the source region of the Tokachi-oki earthquake was relatively low (< 5 cm/year) prior to the earthquake; however, in the last 3 years leading up to the event, a minor acceleration in slip occurred upon the deeper extension of the coseismic slip area of the earthquake. Repeating-earthquake and GPS data indicate that large amounts of afterslip occurred around the rupture area following the earthquake; the afterslip mainly propagated to the east of the coseismic slip area. We also infer that the occurrence of the 2004 off-Kushiro earthquake, located about 100 km northeast of the epicenter of the Tokachi-oki earthquake, was advanced by the afterslip associated with the Tokachi-oki earthquake.     

An empirical probabilistic approach for constraining the uncertainty of long-term solute transport predictions in fractured rock using in situ tracer experiments

Although radionuclide tracer tests have been carried out for over 30  years, the role of tracer tests in radioactive waste repository performance assessment (PA) has been questioned due to the differences between the time scales for tracer tests and PA. The possibility of using in situ tracer tests to constrain PA time scale (over 10,000  years) solute transport has been demonstrated using a systematic “microstructural model” approach to define advective and retentive materials. A series of simulations were conducted of the “TRUE-1” sorbing solute transport experiments in a well-characterized block of fractured granite. These experiments were then used to constrain the uncertainty of long-term transport on the same pathways, using a gradient several orders of magnitude smaller. The comparison of uncertainty of this long-term transport, with and without this conditioning step, provided a measure of the ability of tracer tests to reduce PA time-scale uncertainty. Although this approach for quantifying uncertainty reduction is somewhat empirical, it does indicate the potential usefulness of tracer experiments in reducing the uncertainty of the key PA time-scale transport parameters such as the flow wetted surface, provided that immobile zone properties such as sorption (Kd), porosity and diffusivity are available.