Nitrogen isotope ratios of nitrate as a clue to the origin of nitrogen on the Pacific coast of Japan

To clarify the sources and transformation of NO₃⁻ on the Pacific coast of Japan, observations over the continental shelf were conducted during the summer in 2005 and 2006 when the Kuroshio flowed close to and away from the coastal area, respectively. Below the halocline, there are two prominent salinity peaks that originated in two different waters. In the subsurface layer, the salinity maximum (S_max) was indicative of the Kuroshio Water (KW), while the salinity minimum (S_min) in the middle layer at ∼400 m depth was indicative of the North Pacific Intermediate Water (NPIW). δ¹⁵N_NO3 ranged from 4.1‰ to 5.1‰ with a mean of 4.8±0.4‰ in the deeper water around S_min. Below 50 m depth over the shelf break, δ¹⁵N_NO3 values (3.1±0.8‰ in 2005 and 4.6±0.3‰ in 2006) clearly increased as contribution of NPIW increased in 2006. On the contrary, subsurface δ¹⁵N of NO₃⁻ values (−1.1±0.1‰) remained unchanged in both years, although the contribution of the KW to the subsurface water changed significantly. This suggests that the source of NO₃⁻ has little effect on the δ¹⁵N of NO₃⁻ in this layer. The negative δ¹⁵N values also coincided with the base of the chlorophyll maximum layer suggesting that these isotopic signals must be evidence of active nitrification in the upper layer.     

Continuing observation of disturbed reproductive cycle and ovarian spermatogenesis in the giant abalone, Haliotis madaka from an organotin-contaminated site of Japan

Histological examination of gonads as well as chemical analysis of organotin compounds in tissues of the giant abalone, Haliotis madaka, was conducted to evaluate continuing endocrine disruption in abalone populations in Japan. Abalone specimens were collected from two different areas, Tsushima as a reference site and Jogashima as a site representative of declining abalone populations where serious organotin contamination had been observed, each month from January 1998 to March 1999. Scores were given to the development stages of reproductive cells in the ovary and testis. The degree of sexual maturation was evaluated by calculating the mean value of a histogram of these scores for the reproductive cells of each abalone. The temporal variations in degree of sexual maturation showed that female and male abalone from Tsushima matured synchronously, while those from Jogashima did not, which were similar to results of the previous study during September 1995–November 1996. Approximately 19% of the female abalone from Jogashima were masculinized with an ovo-testis, which was also similar to the result of the previous study. The masculinization of female abalone is reported to be induced by tributyltin (TBT) and triphenyltin (TPhT) from antifouling paints. Concentrations of the sum of butyltins (TBT, dibutyltin (DBT) and monobutyltin (MBT): ΣBTs) and the sum of phenyltins (TPhT, diphenyltin (DPhT) and monophenyltin (MPhT): ΣPhTs) in the muscle of abalone from Jogashima (n = 73) of 7.8 ± 9.0 ng/g wet wt. and 4.5 ± 6.8 ng/g wet wt., respectively, were significantly higher than those from Tsushima (n = 87) of 4.7 ± 4.9 ng/g wet wt. and 0.8 ± 1.7 ng/g wet wt., respectively (p < 0.05 for ΣBTs; p < 0.001 for ΣPhTs), although concentrations of TBT and TPhT in the muscle of abalone from Jogashima (n = 73) of 2.2 ± 2.5 ng/g wet wt. and 5.8 ± 5.1 ng/g wet wt., respectively, were insignificantly and significantly higher than those from Tsushima (n = 87) of 0.4 ± 0.6 ng/g wet wt. and 0.5 ± 0.9 ng/g wet wt., respectively, (p > 0.05 for TBT; p < 0.001 for TPhT). Thus, endocrine disruption as well as contamination by organotins in the giant abalone from Jogashima is still persisting.     

Repeating earthquake activities associated with the Philippine Sea plate subduction in the Kanto district, central Japan: A new plate configuration revealed by interplate aseismic slips

We detect repeating earthquakes associated with the Philippine Sea plate subduction to reveal the plate configuration. In the Kanto district, we find 140 repeating earthquake groups with 428 events by waveform similarity analysis. Most repeating earthquakes in the eastern part of the Kanto district occur with a regular time interval. They have thrust-type focal mechanisms and are distributed near the upper surface of the Philippine Sea plate. These observations indicate that the repeating earthquakes there occur as a repetition of ruptures on the isolated patches distributed on the plate boundary owing to the concentration of stress caused by aseismic slips in the surrounding areas. This shows that the distributions of repeating earthquakes suggest the aseismic slips in the surrounding areas of small patches. We determine spatial distributions of repeating earthquakes in the eastern part of the Kanto district and find that they correspond to the upper boundary of the Philippine Sea plate, that is, the upper boundary of the oceanic crust layer of the Philippine Sea plate. The plate geometry around Choshi is newly constrained by repeating earthquake data and a rather flat geometry in the eastern part of the Kanto district is revealed. The obtained geometry suggests uplift of the Philippine Sea plate due to the collision with the Pacific plate beneath Choshi.Repeating earthquakes in the western part of the Kanto district have extremely shorter recurrence times, and their focal mechanisms are not of the thrust types. These repeating earthquakes are classified as “burst type” activity and likely to occur on the preexistent fault planes which are distributed around the “collision zone” between the Philippine Sea plate and the inland plate. The variation among the repeating earthquake activities in the Kanto district indicates that regular repetition of repeating earthquakes is possible only on the plate boundary with a smooth and simple geometry.     

Effectiveness of superelastic bars for seismic rehabilitation of clay‐unit masonry walls

This paper presents the results on shaking table tests of half‐scale brick walls performed to investigate the effectiveness of newly developed Cu–Al–Mn superelastic alloy (SEA) bars in retrofitting of historical masonry constructions. Problems associated with conventional steel reinforcing bars lie in degradation of stiffness and strength, or pinching phenomena, under cyclic loading, and presence of large residual cracks in structures during and after intense earthquakes. This paper attempts to resolve the problems by applying newly developed Cu–Al–Mn SEA bars, characterized by large recovery strain, low material cost, and high machinability, as partial replacements for steel bars. Sets of unreinforced, steel reinforced, and SEA‐reinforced specimens are subjected to scaled earthquake excitations in out‐of‐plane direction. Whereas steel‐reinforced specimens showed large residual inclinations, SEA‐reinforced specimens resulted in stable rocking response with slight residual inclinations. Corresponding nonlinear finite element (FE) models are developed to simulate the experimental observations. The FE models are further used to examine the sensitivity of the response with respect to the variations in experimental conditions. Both the experimental and numerical results demonstrate the superiority of Cu–Al–Mn SEA bars to conventional steel reinforcing bars in avoiding pinching phenomena. Copyright © 2012 John Wiley & Sons, Ltd.     

Western Boundary Current Separation Caused by a Deep Countercurrent

It is shown that the deep western boundary current (DWBC) in the North Atlantic may contribute to premature separation of the Gulf Stream. A simple analytical study is made based on the linear barotropic vorticity equation in which a possible effect of the DWBC is introduced as anomalous stretching of the water column in a manner consistent with certain qualitative aspects of the observed features. This additional positive vorticity may be generated by a deep downwelling associated with horizontal shears of the DWBC. It is found that separation latitudes are farther to the south as the stretching is strengthened. Vertical motion required for a southward shift of order unity (e.g., 500 km) is estimated to be of the order of 0.05 mm s m 1 , in reasonable agreement with the observed values. It is suggested that since the DWBC is intimately linked with the thermohaline circulation, a meridional migration of the Gulf Stream separation might reflect long-term variations in the North Atlantic.     

Expected changes in future agro-climatological conditions in Northeast Thailand and their differences between general circulation models

We have studied future changes in the atmospheric and hydrological environments in Northeast Thailand from the viewpoint of risk assessment of future cultural environments in crop fields. To obtain robust and reliable estimation for future climate, ten general circulation models under three warming scenarios, B1, A1B, and A2, were used in this study. The obtained change trends show that daily maximum air temperature and precipitation will increase by 2.6°C and 4.0%, respectively, whereas soil moisture will decrease by c.a. 1% point in volumetric water content at the end of this century under the A1B scenario. Seasonal contrasts in precipitation will intensify: precipitation increases in the rainy season and precipitation decreases in the dry season. Soil moisture will slightly decrease almost throughout the year. Despite a homogeneous increase in the air temperature over Northeast Thailand, a future decrease in soil water content will show a geographically inhomogeneous distribution: Soil will experience a relative larger decrease in wetness at a shallow depth on the Khorat plateau than in the surrounding mountainous area, reflecting vegetation cover and soil texture. The predicted increase in air temperature is relatively consistent between general circulation models. In contrast, relatively large intermodel differences in precipitation, especially in long-term trends, produce unwanted bias errors in the estimation of other hydrological elements, such as soil moisture and evaporation, and cause uncertainties in projection of the agro-climatological environment. Offline hydrological simulation with a wide precipitation range is one strategy to compensate for such uncertainties and to obtain reliable risk assessment of future cultural conditions in rainfed paddy fields in Northeast Thailand.