Granulite formation in a Gondwana fragment: petrology and mineral equilibrium modeling of incipient charnockite from Mavadi, southern India

We report a new occurrence of incipient charnockite from Mavadi in the Trivandrum Granulite Block (TGB), southern India, and discuss the petrogenesis of granulite formation in an arrested stage on the basis of petrography, geothermobarometry, and mineral equilibrium modeling. In Mavadi, patches and lenses of charnockite (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Opx?+?Ilm?+?Mag) of about 30 to 220 cm in length occur within Opx-free Grt-Bt gneiss (Kfs?+?Qtz?+?Pl?+?Bt?+?Grt?+?Ilm). The application of mineral equilibrium modeling on the charnockite assemblage in the NCKFMASHTO system to constrain the conditions of charnockitization defines a P–T range of 800 °C at 4.5 kbar to 850 °C at 8.5 kbar, which is broadly consistent with the results from the conventional geothermobarometry (810–880 °C at 7.7–8.0 kbar) on these rocks. The P–T conditions are lower than the peak metamorphic conditions reported for the ultrahigh-temperature granulites from this area (T?>?900 °C). The heterogeneity in peak P–T conditions within the same crustal block might be related to local buffering of metamorphic temperatures by the Opx-Bt-Kfs-Qtz assemblage. The result of T versus mole H₂O (M(H₂O)) modeling demonstrated that the Opx-free assemblage in the Grt-Bt gneiss is stable at M(H₂O)?=?0.3 to 1.5 mol%, and orthopyroxene occurs as a stable mineral at M(H₂O) <0.3 mol%, which is consistent with the petrogenetic model of incipient charnockite related to the lowering of the water activity and stabilization of orthopyroxene through the breakdown of biotite by dehydration caused by the infiltration of CO₂-rich fluid from external sources. We also propose a possible alternative mechanism to form charnockite from Grt-Bt gneiss through slight variations in bulk-rock chemistry (particularly for the K- and Fe-rich portion of Grt-Bt gneiss) that can enhance the stability of orthopyroxene rather than that of biotite, with K-metasomatism playing a possible role.     

Millennium‐scale recurrent uplift inferred from beach deposits bordering the eastern Nankai Trough,Omaezaki area,central Japan

A flight of Holocene marine terraces on the southwestern coast of Cape Omaezaki of central Japan provides evidence of recurrent millennium‐scale uplift events. We reconstructed the uplift history of these terraces by using facies analysis of drill core and geoslicer samples, environmental analysis of trace fossils, and ¹⁴C age determinations. Coastal uplift can be identified by the displacement of beach deposits such as foreshore deposits, which represent the intertidal swash zone of a wave‐dominated sandy coast. Three levels of former beach deposits facing the Nankai Trough were identified near the coast in the Omaezaki area. The highest of these, dated at about 3020–2880 BC, records a maximum of 2.2–2.7 m of emergence. The middle beach surface, of minimum age 370–190 BC, shows 1.6–2.8 m of emergence. The lowest beach surface, which is older than 1300–1370 AD, records 0.4–1.6 m of emergence. Our analysis of vertical crustal deformation data during the Holocene in this region suggests that rapid and strong uplift was restricted to the southwestern coast of the Omaezaki area and was probably caused by high‐angle thrusting on subsidiary faults branching from the underlying plate boundary megathrust.     

Interactions of uranium with bacteria and kaolinite clay

We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10^− 6 M- and 4 × 10^− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH₃COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10^− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH₃COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.     

Very high-density carbonic fluid inclusions in sapphirine-bearing granulites from Tonagh Island in the Archean Napier Complex, East Antarctica: implications for CO2 infiltration during ultrahigh-temperature (T>1,100 °C) metamorphism

The ultrahigh-temperature (UHT) metamorphism of the Napier Complex is characterized by the presence of dry mineral assemblages, the stability of which requires anhydrous conditions. Typically, the presence of the index mineral orthopyroxene in more than one lithology indicates that H₂O activities were substantially low. In this study, we investigate a suite of UHT rocks comprising quartzo-feldspathic garnet gneiss, sapphirine granulite, garnet-orthopyroxene gneiss, and magnetite-quartz gneiss from Tonagh Island. High Al contents in orthopyroxene from sapphirine granulite, the presence of an equilibrium sapphirine-quartz assemblage, mesoperthite in quartzo-feldspathic garnet gneiss, and an inverted pigeonite-augite assemblage in magnetite-quartz gneiss indicate that the peak temperature conditions were higher than 1,000 °C. Petrology, mineral phase equilibria, and pressure-temperature computations presented in this study indicate that the Tonagh Island granulites experienced maximum P-T conditions of up to 9 kbar and 1,100 °C, which are comparable with previous P-T estimates for Tonagh and East Tonagh Islands. The textures and mineral reactions preserved by these UHT rocks are consistent with an isobaric cooling (IBC) history probably following an counterclockwise P-T path. We document the occurrence of very high-density CO₂-rich fluid inclusions in the UHT rocks from Tonagh Island and characterize their nature, composition, and density from systematic petrographic and microthermometric studies. Our study shows the common presence of carbonic fluid inclusions entrapped within sapphirine, quartz, garnet and orthopyroxene. Analysed fluid inclusions in sapphirine, and some in garnet and quartz, were trapped during mineral growth at UHT conditions as 'primary' inclusions. The melting temperatures of fluids in most cases lie in the range of -56.3 to -57.2 °C, close to the triple point for pure CO₂ (-56.6 °C). The only exceptions are fluid inclusions in magnetite-quartz gneiss, which show slight depression in their melting temperatures (-56.7 to -57.8 °C) suggesting traces of additional fluid species such as N₂ in the dominantly CO₂-rich fluid. Homogenization of pure CO₂ inclusions in the quartzo-feldspathic garnet gneiss, sapphirine granulite, and garnet-orthopyroxene gneiss occurs into the liquid phase at temperatures in the range of -34.9 to +4.2 °C. This translates into very high CO₂ densities in the range of 0.95-1.07 g/cm³. In the garnet-orthopyroxene gneiss, the composition and density of inclusions in the different minerals show systematic variation, with highest homogenization temperatures (lowest density) yielded by inclusions in garnet, as against inclusions with lowest homogenization (high density) in quartz. This could be a reflection of continued recrystallization of quartz with entrapment of late fluids along the IBC path. Very high-density CO₂ inclusions in sapphirine associated with quartz in the Tonagh Island rocks provide potential evidence for the involvement of CO₂-rich fluids during extreme crustal temperatures associated with UHT metamorphism. The estimated CO₂ isochores for sapphirine granulite intersect the counterclockwise P-T trajectory of Tonagh Island rocks at around 6-9 kbar at 1,100 °C, which corresponds to the peak metamorphic conditions of this terrane derived from mineral phase equilibria, and the stability field of sapphirine + quartz. Therefore, we infer that CO₂ was the dominant fluid species present during the peak metamorphism in Tonagh Island, and interpret that the fluid inclusions preserve traces of the synmetamorphic fluid from the UHT event. The stability of anhydrous minerals, such as orthopyroxene, in the study area might have been achieved by the lowering of H₂O activity through the influx of CO₂ at peak metamorphic conditions (>1,100 °C). Our microthermometric data support a counterclockwise P-T path for the Napier Complex.     

宝鸡古土壤层S7和黄土层L8的天然剩磁锁定深度初探

详细的古地磁及岩石磁学研究表明磁铁矿和赤铁矿是宝鸡古土壤层S7和黄土层L8的特征剩磁的主要载磁矿物,在稳定的正反极性期间,这两种磁性矿物携带的剩磁方向完全一致.然而,在地磁漂移事件或者松山-布容(M-B)极性转换的过程中,这两种载磁矿物有时携带的剩磁方向不同.高分辨率的磁性地层结果证实宝鸡古土壤层S7和黄土层L8能记录300～500年的短期地球磁场极性倒转事件.经与日本大阪湾高分辨率的海洋沉积物中记录的同期短期极性倒转事件相比,估算宝鸡剖面土壤层S7和黄土层L8的天然剩磁锁定深度小于5～8 cm.     

Wells turbine with end plates for wave energy conversion

In order to improve the performance of the Wells turbine for wave energy conversion, the effect of end plate on the turbine characteristics has been investigated experimentally by model testing. As a result, it is found that the characteristics of the Wells turbine with end plates are superior to those of the original Wells turbine, i.e., the turbine without end plate and the characteristics are dependent on the size and position of end plate. Furthermore, by using a computational fluid dynamics (CFD), reason of the performance improvement of the turbine has been clarified and the effectiveness of the end plate has been demonstrated.     

Selective transmission of light in the ocean waters and its relation to phytoplankton photosynthesis

Occurrence of the depth differences in pigment composition and photosynthetic properties of marine phytoplankton were examined in relation to the spectral changes of light with depth. Phytoplankton were taken from various depths in the northwestern North Pacific, and their absorption spectra were determined with intact cells and in 90% acetone extract. The photosynthetic activities of phytoplankton were concurrently measured under blue, green, red and white light. The difference in absorption spectra for the surface and deeper samples was considerably small, indicating that the prevailing green or blue light in the deeper layers may have little significance for depth-variations of the pigment composition in marine phytoplankton. The depth differentiation in the shape of the light-photosynthesis curve was marked in a well stratified water column but no active response of deeper phytoplankton to green light could be confirmed. The photosynthetic efficiencies of phytoplankton for blue and green light were approximately 105–115 % and 80–90 % of white light, respectively, irrespective of sampling depth.Contribution No. 261 from Shimoda Marine Biological Station     

First Report of Sapphirine-bearing Rocks from the Palghat-Cauvery Shear Zone System, Southern India

Silica deficient Mg-Al granulites from Paramati within the Palghat-Cauvery Shear System contain sapphirine in association with corundum, spinel and sillimanite. Gedrite, which occurs commonly in this locality, coexists with cordierite, corundum and sillimanite. Mineral assemblages and reaction textures indicate peak metamorphism at ultrahigh- temperature conditions. This new locality provides evidence for extreme crustal metamorphism along the Archean-Proterozoic collision boundary in southern India.     

High-frequency polarity swings during the Gauss-Matuyama reversal from Baoji loess sediment

Paleomagnetic records of the Gauss-Matuyama reversal were obtained from two loess sections at Baoji on the Chinese Loess Plateau. Stepwise thermal demagnetization shows two obvious magnetization components. A low-temperature component isolated between 100 and 200–250°C is close to the present geomagnetic field direction, and a high-temperature component isolated above 200–250°C reveals clearly normal, reversed, and transitional polarities. Magnetostratigraphic results of both sections indicated that the Gauss-Matuyama reversal consists of a high-frequency polarity fluctuation zone, but the characteristic remanent magnetization directions during the reversal are clearly inconsistent. Rock magnetic experiments demonstrated that for all the specimens with normal, reversed, and transitional polarities magnetite and hematite are the main magnetic carriers. Anisotropy of magnetic susceptibility indicates that the studied loess sediments have a primary sedimentary fabric. Based on virtual geomagnetic pole latitudes, the Gauss-Matuyama reversal records in the two sections are accompanied by 14 short-lived geomagnetic episodes (15 rapid polarity swings) and 12 short-lived geomagnetic episodes (13 rapid polarity swings), respectively. Our new records, together with previous ones from lacustrine, marine, and aeolian deposits, suggest that high-frequency polarity swings coexist with the Gauss-Matuyama reversal, and that the Gauss-Matuyama reversal may have taken more than 11 kyr to complete. However, we need more detailed analyses of sections across polarity swings during reversals as well as more high-resolution reversal records to understand geomagnetic behavior and inconsistent characteristic remanent magnetization directions during polarity reversals.