Fluid-controlled quartz recovery in granulite as revealed by cathodoluminescence and trace element analysis (Bamble sector,Norway)

Dispersed quartz veinlets in Proterozoic enderbitic charnockite from Tromøy, Bamble sector (southern Norway), with Ti-concentrations of mostly 80–180 ppm, produce bright blue cathodoluminescence (CL), against contrasting micro-textures of secondary pure quartz with low CL intensity. The textures comprise grain boundary alteration, healed micro-fractures, patches of secondary quartz, and euhedral quartz nuclei. The secondary quartz locally makes up 50% of the total quartz. Trace element analysis has been done by electron-probe micro-analysis (EPMA), laser-induced coupled plasma mass spectrometry (LA-ICPMS), and additional electron-paramagnetic resonance (EPR) spectroscopy. These studies testify systematic trace element reduction and extensive quartz recovery during retrograde metamorphism. We assume healing of a part of the aqueous fluid inclusions during a late thermal event, possible correlated with Paleozoic magmatic activity in the Oslo-Rift. During final cooling, aqueous fluids were largely retrapped in patches of secondary quartz associated with healed fractures, whereas carbonic inclusions (without secondary quartz) may have survived retrograde metamorphism. The variable but generally high salinity of fluid inclusions is assumed to be in part the result of quartz recovery by which ion concentrations were increased in the percentage range.Editorial Responsibility: J. Touret     

II. Geophysik Die geophysikalische Erforschung Nordwestdeutschlands im Zeitraum 1932–1947, ein Überblick

Ohne Zusammenfassung     

Exposing metal and silicate charges to electrical discharges: Did chondrules form by nebular lightning?

In order to investigate the hypothesis that dust aggregates were transformed to meteoritic chondrules by nebular lightning, we exposed silicatic and metallic dust samples to electrical discharges with energies of 120 to 500 J in air at pressures between 10 and 10⁵ Pa. The target charges consisted of powders of micrometer-sized particles and had dimensions of mm. The dust samples generally fragmented leaving the major fraction thermally unprocessed. A minor part formed sintered aggregates of 50 to 500 μm. In a few experiments melt spherules having sizes ?180 μm in diameter (and, generally, interior voids) were formed; the highest spherule fraction was obtained with metallic Ni. Our experiments indicate that chondrule formation by electric current or by particle bombardment inside a discharge channel is unlikely.     

Rock magnetic study of basic intrusions and massive sulphides in the Hercynian central Jebilets Massif (Occidental-Meseta), Morocco

This paper describes a multidisciplinary study approach (petrography and rock magnetism) conducted on samples collected from the study area to characterise the magnetic mineralogy and to determine if the magnetisation of both lithologies were induced or retain a remnant component. Petrophysical, mineralogical and geochemical analyses confirm bimodal aspects, particularly in basic rocks; the two magnetic modes depend essentially on the mineralogical and geochemical characteristics of the samples. The ultramafic rocks comprise a highly altered primary mineralogy with chromite and magnetite as magnetic phases. The second type is of mafic composition with a less altered primary mineralogy and essentially magnetite and/or (hemo-ilmenite) as a carrier of magnetic mineralisation. Sulphides are characterised by high concentrations of Cu, Zn and Pb. The mineralogy is composed mainly of pyrrhotite (85% to 90%), sphalerite, galena, chalcopyrite, arsenopyrite and, occasionally, stannite. Monocline pyrrhotite seems to be the magnetic carrier of magnetisation in both Draa Sfar and Koudiat Aïcha. However, we suspect a different amount of hexagonal pyrrhotite as the cause of different magnetic behaviour. Paleomagnetic and thermomagnetic analyses reveal different. The calculated characteristic direction of natural remnant magnetisation for sulphides was used to model the magnetic anomaly of Draa Sfar. The proposed model match the geological features concluded from geological mapping and boreholes. Results from this work can be very useful for any modelling processes of magnetic anomalies suspected due to a sulphide mineralisation in an area with poor outcrops and no presence of boreholes information or of any geological or geochemical data.     

Über ein Strahlungsmessgerät mit Ultrarotdurchlässiger Windschutzhaube am Meteorologischen Observatorium Hamburg

Zusammenfassung Es wird ein Strahlungsmessgerät mit ultrarotdurchlässigen Windschutzhauben beschrieben, das die von uns gestellten Forderungen nach laufender Registrierung der atmosphärischen Gegenstrahlung, der langwelligen Ausstrahlung des Erdbodens, der effektiven Ausstrahlung (bei Nacht) und der Strahlungsbilanz (bei Tag) unter den Bedingungen des Windschutzes, des Strahlungsempfangs aus dem Halbraum 2 und der Befolgung des Cos-Gesetzes erfüllt und sich im Dauerbetrieb bewährt hat. Als Strahlungsempfänger werden zweiMoll'sche Thermosäulen (eine nach oben und eine nach unten gerichtet) verwendet, die gegen den Windeinfluss durch eine ultrarotdurchlässige Lupolen-H-Folie geschützt sind. Die Thermosäulen sind elektrisch derart an drei Galvanometer geschaltet, dass die atmosphärische Gegenstrahlung für sich allein, die langwellige Ausstrahlung des Erdbodens für sich allein und bei Nacht zusätzlich die effektive Ausstrahlung sowie am Tage die Strahlungsbilanz laufend registriert werden können.

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Summary A radiation measuring instrument with windshelter transmitting infrared waves is described, it fulfills our demands for continuous records of the atmospheric radiation, of the long-wave outgoing radiation of the ground, of the effective outgoing radiation (nocturnal radiation), and of the radiation balance (during the days) on the conditions of protection against wind, of reception of radiation from the hemisphere (2 ), and of following the Cosinelaw; the instrument has proved well without interruption. The radiation is received by twoMoll thermopiles (one of which points towards the sky and the other one towards the earth's surface) which are protected against wind by means of a thin leave of Lupolen-H transmitting the infrared waves. The thermopiles are connected with three galvanometers in such a way that we are able to record continuously the atmospheric radiation for itself, the long-wave outgoing radiation of the ground for itself, and in the night additionally the effective outgoing radiation, as well as the whole day long the radiation balance.

     

Nd and Sr isotope compositions in modern and fossil bones - Proxies for vertebrate provenance and taphonomy

Rare earth elements (REE), while not essential for the physiologic functions of animals, are ingested and incorporated in ppb concentrations in bones and teeth. Nd isotope compositions of modern bones of animals from isotopically distinct habitats demonstrate that the ¹⁴³Nd/¹⁴⁴Nd of the apatite can be used as a fingerprint for bedrock geology or ambient water mass. This potentially allows the provenance and migration of extant vertebrates to be traced, similar to the use of Sr isotopes. Although REE may be enriched by up to 5 orders of magnitude during diagenesis and recrystallization of bone apatite, in vivo¹⁴³Nd/¹⁴⁴Nd may be preserved in the inner cortex of fossil bones or enamel. However, tracking the provenance of ancient or extinct vertebrates is possible only for well-preserved archeological and paleontological skeletal remains with in vivo-like Nd contents at the ppb-level. Intra-bone and -tooth REE analysis can be used to screen for appropriate areas. Large intra-bone Nd concentration gradients of 10¹-10³ are often measured. Nd concentrations in the inner bone cortex increase over timescales of millions of years, while bone rims may be enriched over millenial timescales. Nevertheless, ε_Nd values are often similar within one ε_Nd unit within a single bone. Larger intra-bone differences in specimens may either reflect a partial preservation of in vivo values or changing ε_Nd values of the diagenetic fluid during fossilization. However, most fossil specimens and the outer rims of bones will record taphonomic ¹⁴³Nd/¹⁴⁴Nd incorporated post mortem during diagenesis. Unlike REE patterns, ¹⁴³Nd/¹⁴⁴Nd are not biased by fractionation processes during REE-uptake into the apatite crystal lattice, hence the ε_Nd value is an important tracer for taphonomy and reworking. Bones and teeth from autochthonous fossil assemblages have small variations of ±1 ε_Nd unit only. In contrast, fossil bones and teeth from over 20 different marine and terrestrial fossil sites have a total range of ε_Nd values from -13.0 to 4.9 (n = 80), often matching the composition of the embedding sediment. This implies that the surrounding sediment is the source of Nd in the fossil bones and that the specimens of this study seem not to have been reworked. Differences in ε_Nd values between skeletal remains and embedding sediment may either indicate reworking of fossils and/or a REE-uptake from a diagenetic fluid with non-sediment derived ε_Nd values. The latter often applies to fossil shark teeth, which may preserve paleo-seawater values. Complementary to ε_Nd values, ⁸⁷Sr/⁸⁶Sr can help to further constrain the fossil provenance and reworking.     

Controls on ostracod valve geochemistry: Part 2. Carbon and oxygen isotope compositions

The stable carbon and oxygen isotope compositions of fossil ostracods are powerful tools to estimate past environmental and climatic conditions. The basis for such interpretations is that the calcite of the valves reflects the isotopic composition of water and its temperature of formation. However, calcite of ostracods is known not to form in isotopic equilibrium with water and different species may have different offsets from inorganic precipitates of calcite formed under the same conditions. To estimate the fractionation during ostracod valve calcification, the oxygen and carbon isotope compositions of 15 species living in Lake Geneva were related to their autoecology and the environmental parameters measured during their growth. The results indicate that: (1) Oxygen isotope fractionation is similar for all species of Candoninae with an enrichment in ¹⁸O of more than 3‰ relative to equilibrium values for inorganic calcite. Oxygen isotope fractionation for Cytheroidea is less discriminative relative to the heavy oxygen, with enrichments in ¹⁸O for these species of 1.7 to 2.3‰. Oxygen isotope fractionations for Cyprididae are in-between those of Candoninae and Cytheroidea. The difference in oxygen isotope fractionation between ostracods and inorganic calcite has been interpreted as resulting from a vital effect. (2) Comparison with previous work suggests that oxygen isotope fractionation may depend on the total and relative ion content of water. (3) Carbon isotope compositions of ostracod valves are generally in equilibrium with DIC. The specimens’ δ¹³C values are mainly controlled by seasonal variations in δ¹³C_DIC of bottom water or variation thereof in sediment pore water. (4) Incomplete valve calcification has an effect on carbon and oxygen isotope compositions of ostracod valves. Preferential incorporation of at the beginning of valve calcification may explain this effect. (5) Results presented here as well as results from synthetic carbonate growth indicate that different growth rates or low pH within the calcification site cannot be the cause of oxygen isotope ‘vital effects’ in ostracods. Two mechanisms that might enrich the ¹⁸O of ostracod valves are deprotonation of that may also contribute to valve calcification, and effects comparable to salt effects with high concentrations of Ca and/or Mg within the calcification site that may also cause a higher temperature dependency of oxygen isotope fractionation.     

Plant-Arthropod Associations from the Lower Miocene of the Most Basin in Northern Bohemia(Czech Republic):A Preliminary Report

<正>Terrestrial plants and insects currently account for the majority of the Earth's biodiversity,and approximately half of insect species are herbivores.Thus,insects and plants share ancient associations that date back more than 400 Myr.However,investigations of their past interactions are at the preliminary stages in Western Europe.Herein,we present the first results of our study of various feeding damage based on a dataset of nearly 3500 examined plant specimens from the Lower Miocene of the Lagerstatte Bilina Mine in the Most Basin, Czech Republic.This site provides a unique view of the Neogene freshwater ecosystems.It has long been studied by scientists working in different branches of sedimentology,paleobotany,and paleozoology.The fossils are preserved in three characteristic horizons overlaying the coal seam(Clayey Superseam Horizon,Delta Sandy Horizon,and Lake Clayey Horizon),reflecting paleoenvironmental changes in a short time period of development The trace fossils are classified as functional feeding groups orguilds,without searching for a direct cause or a recent analog host relation.Approximately 23%of specimens of dicotyledonous plant leaves were found to be damaged and associated with some leafmorphotypes.Deciduous plant-host taxa,and those with a chartaceous texture typical of riparian habitats,were frequently damaged,such as Populus,recorded with two species Populus zaddachii and Populus populina(57.9%and 31%herbivory levels,respectively),followed by Acer,Alnus,and Carya,averaging almost 30%of damaged leaves/leaflets.There has been evidence of 60 damage types(DT) representing all functional feeding groups recorded at the Bilina Mine,including 12 types of leaf mines and 16 gall- type DT.In total,Lower Miocene of the Lagerstatte Bilina Mine exhibits a high level of external foliage feeding types(23.7%),and a low level of more specialized DT,such as galls(43%)and leaf mines(1%).A broader comparison based on DT of the main sedimentary environments shows significance supporting different biomes by frequency of damage levels and DT diversities.     

People at Risk of Flooding: Why Some Residents Take Precautionary Action While Others Do Not

Self-protective behavior by residents of flood-prone urban areas can reduce monetary flood damage by 80%, and reduce the need for public risk management. But, research on the determinants of private households’ prevention of damage by natural hazards is rare, especially in Germany. To answer the question of why some people take precautionary action while others do not, a socio-psychological model based on Protection Motivation Theory (PMT) is developed, explaining private precautionary damage prevention by residents’ perceptions of previous flood experience, risk of future floods, reliability of public flood protection, the efficacy and costs of self-protective behavior, their perceived ability to perform these actions, and non-protective responses like wishful thinking. The validity of the proposed model is explored by means of representative quantitative telephone surveys and regression analyses, and compared with a socio-economic model (including residents’ age, gender, income, school degree and being owner or tenant). Participants were 157 residents of flood-prone homes in Cologne, Germany, a city that has traditionally been subject to minor and major flood events. Results of the study show the explanatory power of the socio-psychological model, with important implications for public risk communication efforts. To motivate residents in flood-prone areas to take their share in damage prevention, it is essential to communicate not only the risk of flooding and its potential consequences, but also the possibility, effectiveness and cost of private precautionary measures.     

Mineralogy and chemistry of Rumuruti: The first meteorite fall of the new R chondrite group

Abstract— The Rumuruti meteorite shower fell in Rumuruti, Kenya, on 1934 January 28 at 10:43 p.m. Rumuruti is an olivine-rich chondritic breccia with light-dark structure. Based on the coexistence of highly recrystallized fragments and unequilibrated components, Rumuruti is classified as a type 3–6 chondrite breccia. The most abundant phase of Rumuruti is olivine (mostly Fa_～39) with about 70 vol%. Feldspar (～14 vol%; mainly plagioclase), Ca-pyroxene (5 vol%), pyrrhotite (4.4 vol%), and pentlandite (3.6 vol%) are major constituents. All other phases have abundances below 1 vol%, including low-Ca pyroxene, chrome spinels, phosphates (chlorapatite and whitlockite), chalcopyrite, ilmenite, tridymite, Ni-rich and Ge-containing metals, kamacite, and various particles enriched in noble metals like Pt, Ir, arid Au. The chemical composition of Rumuruti is chondritic. The depletion in refractory elements (Sc, REE, etc.) and the comparatively high Mn, Na, and K contents are characteristic of ordinary chondrites and distinguish Rumuruti from carbonaceous chondrites. However, S, Se, and Zn contents in Rumuruti are significantly above the level expected for ordinary chondrites. The oxygen isotope composition of Rumuruti is high in δ¹⁷O (5.52 ‰) and δ¹⁸O (5.07 ‰). Previously, a small number of chondritic meteorites with strong similarities to Rumuruti were described. They were called Carlisle Lakes-type chondrites and they comprise: Carlisle Lakes, ALH85151, Y-75302, Y-793575, Y-82002, Acfer 217, PCA91002, and PCA91241, as well as clasts in the Weatherford chondrite. All these meteorites are finds from hot and cold deserts having experienced various degrees of weathering. With Rumuruti, the first meteorite fall has been recognized that preserves the primary mineralogical and chemical characteristics of a new group of meteorites. Comparing all chondrites, the characteristic features can be summarized as follows: (a) basically chondritic chemistry with ordinary chondrite element patterns of refractory and moderately volatile lithophiles but higher abundances of S, Se, and Zn; (b) high degree of oxidation (37–41 mol% Fa in olivine, only traces of Fe, Ni-metals, occurrence of chalcopyrite); (c) exceptionally high Δ¹⁷O values of about 2.7 for bulk samples; (d) high modal abundance of olivine (～70 vol%); (e) Ti-Fe³⁺?rich chromite (～5.5 wt% TiO₂); (f) occurrence of various noble metal-rich particles; (g) abundant chondritic breccias consisting of equilibrated clasts and unequilibrated lithologies. With Rumuruti, nine meteorite samples exist that are chemically and mineralogically very similar. These meteorites are attributed to at least eight different fall events. It is proposed in this paper to call this group R chondrites (rumurutiites) after the first and only fall among these meteorites. These meteorites have a close relationship to ordinary chondrites. However, they are more oxidized than any of the existing groups of ordinary chondrites. Small, but significant differences in chemical composition and in oxygen isotopes between R chondrites and ordinary chondrites exclude formation of R chondrites from ordinary chondrites by oxidation. This implies a separate, independent R chondrite parent body.