An experimental database for the development,calibration and verification of constitutive models for sand with focus to cyclic loading: part I—tests with monotonic loading and stress cycles

For numerical studies of geotechnical structures under earthquake loading, aiming to examine a possible failure due to liquefaction, using a sophisticated constitutive model for the soil is indispensable. Such a model must adequately describe the material response to a cyclic loading under constant volume (undrained) conditions, amongst others the relaxation of effective stress (pore pressure accumulation) or the effective stress loops repeatedly passed through after a sufficiently large number of cycles (cyclic mobility, stress attractors). The soil behaviour under undrained cyclic loading is manifold, depending on the initial conditions (e.g. density, fabric, effective mean pressure, stress ratio) and the load characteristics (e.g. amplitude of the cycles, application of stress or strain cycles). In order to develop, calibrate and verify a constitutive model with focus to undrained cyclic loading, the data from high-quality laboratory tests comprising a variety of initial conditions and load characteristics are necessary. The purpose of these two companion papers was to provide such database collected for a fine sand. The database consists of numerous undrained cyclic triaxial tests with stress or strain cycles applied to samples consolidated isotropically or anisotropically. Monotonic triaxial tests with drained or undrained conditions have also been performed. Furthermore, drained triaxial, oedometric or isotropic compression tests with several un- and reloading cycles are presented. Part I concentrates on the triaxial tests with monotonic loading or stress cycles. All test data presented herein will be available from the homepage of the first author. As an example of the examination of an existing constitutive model, the experimental data are compared to element test simulations using hypoplasticity with intergranular strain.     

Structure and origin of terpenoid hydrocarbons in some German coals

Hydrocarbon extracts of coal samples from major coal fields in West Germany have been investigated by gas chromatography-mass spectrometry (GC/MS). The samples are of Carboniferous and Tertiary age and derive from limnic and paralic environments, the Saar District, the Ruhr Area and the Lower Rhine Basin.Differences in facies, maturity and age reflected in the distribution patterns of the extracted alkylcyclohexanes. An unexpected occurrence of cyclic diterpenoid hydrocarbons in some samples of Carboniferous age has been found. The tetracyclic compounds mainly show phyllocladane type structures and can serve as source indicators.Hydrocarbons obtained from chemical degradation of the macromolecular material of the samples also revealed phyllocladane-type compounds which are normally associated to resins of modern and extinct familes of conifers. Origin and structural variations of this class of hydrocarbons are discussed in terms of maturity and palaeobotanical implications.     

Über die Vorzüge der Verwendung der „Relativen Bestrahlung” für strahlungsklimatologische Betrachtungen

Zusammenfassung Für die relative Bestrahlung, die als Quotient von gemessener Globalstrahlung und extraterrestrischer Strahlung definiert ist, wird eine Beziehung zumLinkeschen Trübungsfaktor abgeleitet. Diese dient als Grundlage zur Berechnung des Strahlungsklimas der Erde an wolkenlosen und an bewölkten Tagen bei gegebenen Trübungsfaktoren. Die durch unterschiedliche Rückstrahlung, durch den Einfluß von Änderungen des Wasserdampfgehaltes der Atmosphäre und durch Änderungen der Trübung bewirkte Variabilität der berechneten Strahlungswerte wird diskutiert. Die durch diese Änderungen bewirkten Abweichungen der berechneten Strahlungswerte liegen innerhalb von ±10%.

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Summary A relationship is derived betweenLinke's turbidity factor and relative insolation. The latter is defined as the quotient of measured global radiation and extraterrestrial radiation. The relationship is used as a basis for calculating radiation climate on cloudless and cloudy days, and for a given turbidity factor. The variability of the results due to varying reflexion, vapour content of the atmosphere, and turbidity, is discussed. The deviations of calculated values from observed values of radiation caused by these factors lie within ±10%.

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Résumé L'auteur établit une relation entre le rayonnement relatif, c'est à dire le quotient du rayonnement global au rayonnement extra-terrestre, et le facteur de trouble deLinke. Cette relation sert à calculer le climat radiatif de la terre pour les jours sans nuages et pour les jours nuageux à partir du rayonnement relatif et pour des facteurs de trouble donnés. Le rayonnement réfléchi, les variations de la teneur en vapeur d'eau et du trouble atmosphérique conduisent à des différences des valeurs calculées, dont les écarts restent inférieurs à 10% en valeur absolue.

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Mit 3 Textabbildungen     

Reconstruction of atmospheric CO2 from ice-core data and the deep-sea record of ontong Java plateau: the Milankovitch chron

We provide a reconstruction of atmospheric CO₂ from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple regression between deep-sea data, on one hand, and ice-core CO₂ data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO₂ can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric CO₂ (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO₂.     

Pure elastic stiffness of sand represented by response envelopes derived from cyclic triaxial tests with local strain measurements

Acta Geotechnica - The elastic stiffness of a fine sand at small to moderate strains ( $$\varepsilon \le 2 \times 10^{-4}$$ ) has been studied based on cyclic triaxial tests on cube-shaped samples...     

VRANCEA99—the crustal structure beneath the southeastern Carpathians and the Moesian Platform from a seismic refraction profile in Romania

The VRANCEA99 seismic refraction experiment is part of an international and multidisciplinary project to study the intermediate depth earthquakes of the Eastern Carpathians in Romania. As part of the seismic experiment, a 300-km-long refraction profile was recorded between the cities of Bacau and Bucharest, traversing the Vrancea epicentral region in NNE–SSW direction.

The results deduced using forward and inverse ray trace modelling indicate a multi-layered crust. The sedimentary succession comprises two to four seismic layers of variable thickness and with velocities ranging from 2.0 to 5.8 km/s. The seismic basement coincides with a velocity step up to 5.9 km/s. Velocities in the upper crystalline crust are 5.9–6.2 km/s. An intra-crustal discontinuity at 18–31 km divides the crust into an upper and a lower layer. Velocities within the lower crust are 6.7–7.0 km/s. Strong wide-angle PmP reflections indicate the existence of a first-order Moho at a depth of 30 km near the southern end of the line and 41 km near the centre. Constraints on upper mantle seismic velocities (7.9 km/s) are provided by Pn arrival times from two shot points only. Within the upper mantle a low velocity zone is interpreted. Travel times of a PLP reflection define the bottom of this low velocity layer at a depth of 55 km. The velocity beneath this interface must be at least 8.5 km/s.

Geologic interpretation of the seismic data suggests that the Neogene tectonic convergence of the Eastern Carpathians resulted in thin-skinned shortening of the sedimentary cover and in thick-skinned shortening in the crystalline crust. On the autochthonous cover of the Moesian platform several blocks can be recognised which are characterised by different lithological compositions. This could indicate a pre-structuring of the platform at Mesozoic and/or Palaeozoic times with a probable active involvement of the Intramoesian and the Capidava–Ovidiu faults. Especially the Intramoesian fault is clearly recognisable on the refraction line. No clear indications of the important Trotus fault in the north of the profile could be found. In the central part of the seismic line a thinned lower crust and the low velocity zone in the uppermost mantle point to the possibility of crustal delamination and partial melting in the upper mantle.     

Microscale Simultaneous Measurement of Carbon and Nitrogen Isotopes on Natural Diamond

Simultaneous analysis of carbon and nitrogen isotope ratios by SIMS was applied for the first-time to a natural diamond from the Kelsey Lake kimberlite, State Line Distinct, Colorado (UWD-1). This in situ procedure is faster, reduces sample size for analysis, and measures both isotope ratios from a single ~ 10 μm diameter pit, a critical advantage for zoned diamonds. The carbon isotope ratio (expressed as δ¹³C_VPDB) of the bulk UWD-1 crystal, determined by the conventional combustion method in the present study, is -5.9‰ ± 0.2‰ (VPDB, 2s). Nitrogen mass fraction ([N]) and isotope ratio (expressed as δ¹⁵N_Air) were determined by stepwise combustion and gas-source mass-spectrometry, resulting in 553 ± 64 μg g^-1 and -6.7‰ ± 1.1‰ (Air, 2s), respectively. Secondary ions of ¹²C₂^-, ¹²C¹³C^-, ¹²C¹⁴N^-, and ¹²C¹⁵N^- were simultaneously measured by SIMS using three Faraday cups and one electron multiplier. The spot-to-spot reproducibility of δ¹³C and δ¹⁵N values for the UWD-1 (178 spots on sixteen chips, 10 μm spots), were 0.3‰ and 1.6‰, respectively (2s). While ¹²C¹⁴N^-/¹²C₂^- ratios, which are an indicator for [N], varied up to 12% among these sixteen chips, such variation did not correlate with either δ¹³C or δ¹⁵N values. We propose that UWD-1 is a suitable reference sample for microscale in situ analysis of δ¹³C and δ¹⁵N values in diamond samples.     

Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.     

Synchronous pattern of moisture availability on the southern Tibetan Plateau since 17.5 cal. ka BP – the Tangra Yumco lake sediment record

A possible asynchronicity of the spatial and temporal moisture availability on the Tibetan Plateau has been a controversial subject of discussion in recent years. Here we present the first attempt to systematically investigate possible spatial and temporal variations in moisture availability by examining two lakes, Tangra Yumco and Nam Co, on an east–west transect on the southern Tibetan Plateau using identical proxies for palaeoenvironmental reconstruction. In this study, an independent record from Tangra Yumco was analysed applying a multi‐proxy approach to reconstruct variations in moisture availability since the Lateglacial. Results were subsequently compared with previously published records from Nam Co and additional records from Tso Moriri (northwestern Himalaya) and Naleng Co (southeastern Tibetan Plateau). Our results show that Tangra Yumco was at least partially ice covered prior to 17.1 cal. ka BP. A temperature rise after 17.1 cal. ka BP probably resulted in thawing of the permafrost. At 16.0 cal. ka BP moisture availability increased, representing an initial monsoonal intensification. Warmer conditions between 13.0 and 12.4 cal. ka BP and cooler conditions between 12.4 cal. ka BP and the onset of the Holocene reflect the Bølling‐Allerød and Younger Dryas. At the onset of the Holocene moisture availability rapidly increased, with moisture highest prior to 8.5 cal. ka BP when temperatures were also highest. After 8.5 cal. ka BP the moisture availability gradually decreased and showed only minor amplitude variations. These findings are consistent with the records from large lakes like Nam Co, Tso Moriri, and Naleng Co, revealing a synchronous pattern of moisture availability on the southern Tibetan Plateau.     

Survival of the thinnest: rediscovery of Bauer’s (1898) ichthyosaur tooth sections from Upper Jurassic lithographic limestone quarries,south Germany

During the late Early Cretaceous, the shallow-water domains of the western Tethys are characterized by the widespread deposition of Urgonian-type carbonates rich in rudists, corals and other oligotrophic, shallow-marine organisms. In the Helvetic Alps, the Urgonian occurrences have been dated by ammonite biostratigraphy as Late Barremian and Early Aptian. For the more proximal occurrences in the western Swiss Jura, a recent age model based on bio-, chemo- and sequence stratigraphy has been proposed, which allows for an improved correlation with the Helvetic counterparts. In order to corroborate the recently proposed age model for the Jura, a set of well-preserved rhynchonellids collected from five different lithostratigraphical formations and members (“Marnes bleues d’Hauterive”, “Marnes d’Uttins”, basal marly layers within the “Urgonien Jaune”, “Marnes de la Russille”, “Urgonien Blanc”) has been analysed for its strontium–isotope ratios (⁸⁷Sr/⁸⁶Sr). In addition, K–Ar dating was performed on well-preserved glauconite grains from two different levels (“Marnes d’Uttins” and a basal layer within the “Urgonien Jaune”). The correlation of the Sr–isotope data set with a belemnite-based, ammonite-calibrated reference curve provides an age model which is coherent with recently published ages based on calcareous nannofossil biostratigraphy and the correlation of trends in chemo- and sequence stratigraphy. K–Ar dating on well-preserved glauconite grains from the “Marnes d’Uttins” and lowermost part of the “Urgonien Jaune” delivered ages of 127.5 ± 2.3 and 130.7 ± 2.6 Ma, respectively. Whereas the age of the glauconitic level near the base of the “Urgonien Jaune” is chronostratigraphically meaningful, the K–Ar age of the “Marnes d’Uttins” appears too young relative to the presently used time scale. This may be related to rejuvenation of the K–Ar chronometer due to post-depositional Ar loss, most likely during hardground formation. The ages obtained here confirm the Late Barremian age for the onset of the Urgonian platform, an age which is conform with ages obtained in the Helvetic Alps and elsewhere along the northern Tethyan margin.