Improvement in the calculation of anti-Stokes energy transfer and experimental justification based on Er0.01YbxY1 - 0.01 - xVO4 crystal

The improvement on the calculation of anti-Stokes energy transfer rate is studied in the present work. The additional proportion coefficient between Stokes and anti-Stokes light intensities of quantum Raman scattering theory as compared with the classical Raman theory is introduced to successfully describe the anti-Stokes energy transfer. The theoretical formula for the improvement on the calculation of anti-Stokes energy transfer rate is derived for the first time in this study. The correctness of introducing coefficient exp{ΔE / kT} from well-known Raman scatter theory is demonstrated also. Moreover, the experimental lifetime measurement in Er_0.01Yb_xY_{1 - 0.01 - x}VO₄ crystal is performed to justify the validity of our important improvement in the original phonon-assisted energy transfer theory for the first time.     

Active manipulation of the selective alignment by two laser pulses

This paper solves numerically the full time-dependent Schrõdinger equation based on the rigid rotor model, and proposes a novel strategy to determine the optimal time delay of the two laser pulses to manipulate the molecular selective alignment. The results illustrate that the molecular alignment generated by the first pulse can be suppressed or enhanced selectively, the relative populations of even and odd rotational states in the final rotational wave packet can be manipulated selectively by precisely inserting the peak of the second laser pulse at the time when the slope for the alignment parameter by the first laser locates a local maximum for the even rotational states and a local minimum for the odds, and vice versa. The selective alignment can be further optimised by selecting the intensity ratio of the two laser pulses on the condition that the total laser intensity and pulse duration are kept constant.     

Structural, curvature and electronic properties of Rh adsorption on armchair single-walled carbon nanotube

This paper systematically studies the rolling effects of the (n, n) single-wall carbon nanotubes (SWCNT) with different curvatures on Rh adsorption behaviours by using density functional theory. The outside charge densities of SWCNTs are found to be higher than those inside, and the differences decrease with the increase of the tube radius. This electronic property led to the discovery that the outside adsorption energies are higher than the inside ones, and that the differences are reduced with the increase of the tube radius. Partial density of states and charge density difference indicate that these strong interactions induce electron transfer between Rh atoms and SWCNTs.     

An interconnect width and spacing optimization model considering scattering effect

As the feature size of the CMOS integrated circuit continues to shrink, the more and more serious scattering effect has a serious impact on interconnection performance, such as delay and bandwidth. Based on the impact of the scattering effect on latency and bandwidth, this paper first presents the quality-factor model which optimises latency and bandwidth effectively with the consideration of the scattering effect. Then we obtain the analytical model of line width and spacing with application of curve-fitting method. The proposed model has been verified and compared based on the nano-scale CMOS technology. This optimisation model algorithm is simple and can be applied to the interconnection system optimal design of nano-scale integrated circuits.     

A type of new conserved quantity deduced from Mei symmetry for Appell equations in a holonomic system with unilateral constraints

A type of new conserved quantity deduced from Mei symmetry of Appell equations for a holonomic system with unilateral constraints is investigated. The expressions of new structural equation and new conserved quantity deduced from Mei symmetry of Appell equations for a holonomic system with unilateral constraints expressed by Appell functions are obtained. An example is given to illustrate the application of the results.     

Faithful quantum secure direct communication protocol against collective noise

An improved quantum secure direct communication (QSDC) protocol is proposed in this paper. Blocks of entangled photon pairs are transmitted in two steps in which secret messages are transmitted directly. The single logical qubits and unitary operations under decoherence free subspaces are presented and the generalized Bell states are constructed which are immune to the collective noise. Two steps of qubit transmission are used in this protocol to guarantee the security of communication. The security of the protocol against various attacks are discussed.     

Coherent spectroscopy of a strongly driven triple quantum dot molecule

Based on a calculation model, we study the interference phenomena of serially coupled V-type and Λ-type triple quantum dots (CTQDs) driven simultaneously by a strong driving field and a weak probe field. Strongly depending on the configuration of the three-level CTQD, the probe absorption spectra, which are shown in the tunneling current, exhibit various quantum coherence properties. In the case where the two pairs of transitions of the CTQD have a small eigenfrequency difference Δω, the double-coupling effect of the driving field results in two Autler-Townes doublets and one weak Mollow triplet in one spectrum. With the value of Δω increasing, only one Autler-Townes splitting remains due to the single-coupling of the field. We also find that the effect of spontaneous emission of phonons may lead to an obvious background current, which can be used to distinguish which transition is driven by the driving field in experiment. The interesting quantum property of a CTQD revealed in our results suggests its potential applications in quantum modulators and quantum logic devices.     

北部湾盆地涠西南凹陷C洼烃源岩热史及成熟史模拟

北部湾盆地涠西南凹陷C洼流沙港组烃源岩热史及成熟史研究,对C洼深水油气勘探具有指导意义。在恢复涠西南凹陷C洼地史和热史的基础上,利用EASY%Ro模型计算了流沙港组烃源岩的成熟度史。研究结果表明,在涠西南凹陷发展的裂陷阶段初始期热流值较高,最大值约为77mW/m2,其后热流值逐渐减小,现今热流值约为54mW/m2;涠西南凹陷C洼流沙港组烃源岩开始生烃(Ro=0.5%)时间为51MaBP,达到生烃高峰(Ro=1%)时间为42MaBP,达到高成熟演化阶段(Ro=1.3%)时间为17MaBP;对比涠1井流沙港组烃源岩演化特征,处于C洼深水勘探区的流沙港组烃源岩成熟度较高,生烃能力较强,拥有广阔的油气勘探前景。     

Distributions and seasonal variations of dissolved carbohydrates in the Jiaozhou Bay,China

Surface seawater samples were collected in the Jiaozhou Bay, a typical semi-closed basin located at the western part of the Shandong Peninsula, China, during four cruises. Concentrations of monosaccharides (MCHO), polysaccharides (PCHO) and total dissolved carbohydrates (TCHO) were measured with the 2,4,6-tripyridyl-s-triazine spectroscopic method. Concentrations of TCHO varied from 10.8 to 276.1 μM C for all samples and the ratios of TCHO to dissolved organic carbon (DOC) ranged from 1.1 to 67.9% with an average of 10.1%. This result indicated that dissolved carbohydrates were an important constituent of DOC in the surface seawater of the Jiaozhou Bay. In all samples, the concentrations of MCHO ranged from 2.9 to 65.9 μM C, comprising 46.1 ± 16.6% of TCHO on average, while PCHO ranged from 0.3 to 210.2 μM C, comprising 53.9 ± 16.6% of TCHO on average. As a major part of dissolved carbohydrates, the concentrations of PCHO were higher than those of MCHO. MCHO and PCHO accumulated in January and July, with minimum average concentration in April. The seasonal variation in the ratios of TCHO to DOC was related to water temperature, with high values in January and low values in July and October. The concentrations of dissolved carbohydrates displayed a decreasing trend from the coastal to the central areas. Negative correlations between concentrations of TCHO and salinity in July suggested that riverine input around the Jiaozhou Bay had an important effect on the concentrations of dissolved carbohydrates in surface seawater. The pattern of distributions of MCHO and PCHO reported in this study added to the global picture of dissolved carbohydrates distribution.