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The density of liquid Fe–S was measured at 4 GPa and 1,923 K using a sink/float method with a composite density marker. The density marker consisted of a Pt rod core and an Al2O3 tube surrounding. The uncertainty in the density of the composite marker is much smaller than that of the composite sphere, which had been used in previous density measurements. The density of liquid Fe–S decreases nonlinearly with increasing sulfur content at 4 GPa and 1,923 K. This tendency is consistent with the results measured at ambient pressure. The molar volume of FeS calculated from the measured density gradually increases with sulfur content. The excess molar volume from ideal mixing of Fe and S at 4 GPa was negative value. The new method proposed here is applicable to the density measurement of other Fe alloys at high pressure. The tendency of the molar volume and the excess molar volume with sulfur content at ambient pressure is consistent with these at high pressure at least up to 4 GPa. The excess molar volume at high pressure is essential for estimating the amount of light elements in the outer core.  相似文献   
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A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO2 and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 × 5 μm2) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction.  相似文献   
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Three-dimensional (3-D) Monte Carlo-based radiative transfer (MCRT) models are usually used for benchmarking in intercomparisons of the canopy radiative transfer (RT) simulations. However, the 3-D MCRT models are rarely applied to develop remote sensing algorithms to estimate essential climate variables of forests, due mainly to the difficulties in obtaining realistic stand structures for different forest biomes over regional to global scales. Fortunately, some of important tree structure parameters such as canopy height and tree density distribution have been available globally. This enables to run the intermediate complexities of the 3-D MCRT models. We consequently developed a statistical approach to generate forest structures with intermediate complexities depending on the inputs of canopy height and tree density. It aims at facilitating applications of the 3-D MCRT models to develop remote sensing retrieval algorithms. The proposed approach was evaluated using field measurements of two boreal forest stands at Estonia and USA, respectively. Results demonstrated that the simulations of bidirectional reflectance factor (BRF) based on the measured forest structures agreed well with the BRF based on the generated structures from the proposed approach with the root mean square error (RMSE) and relative RMSE (rRMSE) ranging from 0.002 to 0.006 and from 0.7% to 19.8%, respectively. Comparison of the computed BRF with corresponding MODIS reflectance data yielded RMSE and rRMSE lower than 0.03 and 20%, respectively. Although the results from the current study are limited in two boreal forest stands, our approach has the potential to generate stand structures for different forest biomes.  相似文献   
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The vertical and horizontal distribution of fluorescent dissolved organic matter (FDOM), determined by fluorescence intensity at 320 nm excitation and 420 nm emission, were clarified in nine stations on two transects at the Southern Ocean, including a subtropical, subantarctic, polar frontal and Antarctic zone. All vertical profiles of fluorescence intensity showed that levels were lowest in the surface waters, increased with increasing the depth in mid-depth waters ( 2000 m), and then stayed within a relatively narrow range from there to the bottom. Such vertical profiles of FDOM were similar to those of nutrients, but were adverse to dissolved oxygen. In water columns below the temperature-minimum subsurface water (dichothermal waters) in the Antarctic zone and below the winter mixed layer in the other zones, we determined the relationships of fluorescence intensity to concentrations of nutrients and apparent oxygen utilization (AOU) over the entire area of the present study, and found significant linear correlations between the levels of fluorescence intensity and nutrient concentrations (r =  0.70 and 0.71 for phosphate and nitrate + nitrite, respectively) and AOU (r = 0.91). From the strong correlation coefficient between fluorescence intensity and AOU, we concluded that FDOM in the Southern Ocean is formed in situ via the biological oxidation of organic matter. The regeneration of the nutrients/consumption of the oxygen/formation of FDOM was active in mid-depth waters. However, the correlations between fluorescence intensities and nutrients and AOU were different in the mid-depth water masses, Subantarctic Mode Water (SAMW), and Antarctic Intermediate Water (AAIW), indicating that the sources of organic matter responsible for FDOM formation were different. A considerable amount of FDOM in the SAMW is thought to be produced by the remineralization of DOM in addition to sinking particulate organic matter, while DOM is less responsible for FDOM formation in the AAIW.  相似文献   
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The spatial structure of the transverse oscillations in the interplanetary magnetic field at 1 AU is studied by comparing the simultaneous observations by Explorer 33 and 35 satellites at the maximum separation of about 200R E. The anisotropy characteristics of these oscillations suggest that the oscillations sampled are Alfvén waves. It is found that the size of the region of the wave coherence is related to the solar wind velocity; the size is 80R E when the wind velocity is lower than 500 km s–1 but becomes less than this when the wind velocity is higher. An inference is made that the solar atmospheric turbulence contributing to the faster solar wind is finer in scale than that associated with the slower wind.A postgraduate student at the Tokai University  相似文献   
90.
We discuss the runaway instability of axisymmetric tori with non-constant specific angular momentum around black holes, taking into account self-gravity of the tori. The distribution of specific angular momentum of the tori is assumed to be a positive power law with respect to the distance from the rotational axis. By employing the pseudo-Newtonian potential for the gravity of the spherical black hole, we have found that self-gravity of the tori causes a runaway instability if the amount of the mass which is transferred from the torus to the black hole exceeds a critical value, i.e. 3 per cent of the mass of the torus. This has been shown by two different approaches: (1) by using equilibrium models and (2) by dynamical simulations. In particular, dynamical simulations using an SPH code have been carried out for both self-gravitating and non-self-gravitating tori. For non-self-gravitating models, all tori are runaway stable. Therefore we come to the conclusion that self-gravity of the tori has a stronger destabilizing effect than the stabilizing effect of the positive power-law distribution of the angular momentum.  相似文献   
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