Laboratory Study of O(1S) Formation Process in the Photolysis of O3 and its Atmospheric Implications

A high-sensitive technique to detect O(¹S) atoms using vacuum ultraviolet laser-induced fluorescence (VUV-LIF) spectroscopy has been applied to study the O(¹S) production process from the UV photodissociation of O₃, N₂O, and H₂O₂. The quantum yields for O(¹S) formation from O₃ photolysis at 215 and 220 nm are determined to be (1.4 ± 0.4) × 10⁻⁴ and (5 ± 3) × 10⁻⁵, respectively. Based on thermochemical considerations, the O(¹S) formation from O₃ photolysis at 215 and 220 nm is attributed to a spin-forbidden process of O(¹S)+O₂(X³Σ_g ⁻). Analysis of the Doppler profile of O(¹S) produced from O₃ photolysis at 193 nm also indicates that the O(¹S) atoms are produced from the spin-forbidden process. In the photolysis of N₂O and H₂O₂ at 193 nm, no discernible signal of O(¹S) atoms has been detected. The upper limit values of the quantum yields for O(¹S) production from N₂O and H₂O₂ photolysis at 193 nm are estimated to be 8 × 10⁻⁵ and 3 × 10⁻⁵, respectively. Using the experimental results, the impact of the O(¹S) formation from O₃ photolysis on the atmospheric OH radical formation through the reaction of O(¹S)+H₂O has been estimated. The calculated results show that the contribution of the O(¹S)+H₂O reaction to the OH production rate is ∼2% of that of the O(¹D)+H₂O reaction at 30 km altitude in mid-latitude. Implications of the present laboratory experimental results for the terrestrial airglow of O(¹S) at 557.7 nm have also been discussed.     

Cosmic‐ray exposure age and heliocentric distance of the parent body of the Rumuruti chondrite PRE 95410

We measured concentrations and isotopic ratios of noble gases in the Rumuruti (R) chondrite Mount Prestrud (PRE) 95410, a regolith breccia exhibiting dark/light structures. The meteorite contains solar and cosmogenic noble gases. Based on the solar and cosmogenic noble gas compositions, we calculated a heliocentric distance of its parent body, a cosmic‐ray exposure age on the parent body regolith (parent body exposure age), and a cosmic‐ray exposure age in interplanetary space (space exposure age) of the meteorite. Assuming a constant solar wind flux, the estimated heliocentric distance was smaller than 1.4 ± 0.3 au, suggesting inward migration from the asteroid belt regions where the parent body formed. The largest known Mars Trojan 5261 Eureka is a potential parent body of PRE 95410. Alternatively, it is possible that the solar wind flux at the time of the parent body exposure was higher by a factor of 2–3 compared to the lunar regolith exposure. In this case, the estimated heliocentric distance is within the asteroid belt region. The parent body exposure age is longer than 19.1 Ma. This result indicates frequent impact events on the parent body like that recorded for other solar‐gas‐rich meteorites. Assuming single‐stage exposure after an ejection event from the parent body, the space exposure age is 11.0 ± 1.1 Ma, which is close to the peak of ~10 Ma in the exposure age distribution for the solar‐gas‐free R chondrites.     

Heating experiments of the Tagish Lake meteorite: Investigation of the effects of short‐term heating on chondritic organics

We present in this study the effects of short‐term heating on organics in the Tagish Lake meteorite and how the difference in the heating conditions can modify the organic matter (OM) in a way that complicates the interpretation of a parent body's heating extent with common cosmothermometers. The kinetics of short‐term heating and its influence on the organic structure are not well understood, and any study of OM is further complicated by the complex alteration processes of the thermally metamorphosed carbonaceous chondrites—potential analogues of the target asteroid Ryugu of the Hayabusa2 mission—which had experienced posthydration, short‐duration local heating. In an attempt to understand the effects of short‐term heating on chondritic OM, we investigated the change in the OM contents of the experimentally heated Tagish Lake meteorite samples using Raman spectroscopy, scanning transmission X‐ray microscopy utilizing X‐ray absorption near edge structure spectroscopy, and ultraperformance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry. Our experiment suggests that graphitization of OM did not take place despite the samples being heated to 900 °C for 96 h, as the OM maturity trend was influenced by the heating conditions, kinetics, and the nature of the OM precursor, such as the presence of abundant oxygenated moieties. Although both the intensity of the 1s?σ* exciton cannot be used to accurately interpret the peak metamorphic temperature of the experimentally heated Tagish Lake sample, the Raman graphite band widths of the heated products significantly differ from that of chondritic OM modified by long‐term internal heating.     

Simple DEM-Based Methods to Delineate Channel Networks for Hydrogeomorphological Mapping

To delineate channel networks from DEMs regardless of landform type, this article proposes a new method using slope-weighted flow accumulation. To validate the method, SRTM-3, a global DEM dataset with a resolution of approximately 90 m, was used for analysis of the Loess Plateau, China. Channel networks delineated with and without slope-weighted flow accumulation were derived in both uplands and hilly lands for comparison. In the weighted flow accumulation method, the thresholds for delineating the channels were defined by detecting a turning point in the frequency distribution of the weighted flow accumulation function or by visual similarity with drainage channels extracted from topographic maps. The channel networks delineated with weighting showed closer correlation with a topographic map than the channel networks without weighting, despite the differences in thresholds. Moreover, the channel networks delineated with weighting represented the differences between landform types, while the channel networks without weighting did not. Weighting on the basis of the slope angle shows promise as a general channel delineation method which reflects the actual topography due to its hydrogeomorphological functions.     

Impacts of convection schemes on simulating tropical-temperate troughs over southern Africa

This study examines southern African summer rainfall and tropical temperate troughs (TTTs) simulated with three versions of an atmospheric general circulation model differing only in the convection scheme. All three versions provide realistic simulations of key aspects of the summer (November–February) rainfall, such as the spatial distribution of total rainfall and the percentage of rainfall associated with TTTs. However, one version has a large bias in the onset of the rainy season. Results from self-organizing map (SOM) analysis on simulated daily precipitation data reveals that this is because the occurrence of TTTs is underestimated in November. This model bias is not related to westerly wind shear that provides favorable conditions for the development of TTTs. Rather, it is related to excessive upper level convergence and associated subsidence over southern Africa. Furthermore, the model versions are shown to be successful in capturing the observed drier (wetter) conditions over the southern African region during El Niño (La Niña) years. The SOM analysis reveals that nodes associated with TTTs in the southern (northern) part of the domain are observed less (more) often during El Niño years, while nodes associated with TTTs occur more frequently during La Niña years. Also, nodes associated with dry conditions over southern Africa are more (less) frequently observed during El Niño (La Niña) years. The models tend to perform better for La Niña events, because they are more successful in representing the observed frequency of different synoptic patterns.     

How is the Indian Ocean Subtropical Dipole excited?

Based on experiments using a coupled general circulation model which resolves tropical ocean–atmosphere coupled phenomena such as El Niño/Southern Oscillation (ENSO) and the Indian Ocean Dipole, forcing mechanisms of the Indian Ocean subtropical dipole (IOSD) are investigated. In the control experiment, as in the observation, several types of the IOSD are generated by the variations in the Mascarene High during austral summer and characterized by a dipole pattern of sea surface temperature (SST) anomalies in the northeastern and southwestern parts of the southern Indian Ocean. In another experiment, where the SST outside the southern Indian Ocean is nudged toward the monthly climatology of the simulated SST, one type of the IOSD occurs, but it is less frequent and associated with the zonal wavenumber four pattern of equivalently barotropic geopotential height anomalies in high latitudes, suggesting an interesting link with the Antarctic Circumpolar Wave. This indicates that, even without the atmospheric teleconnection from tropical coupled climate modes, the IOSD may develop in association with the atmospheric variability in high latitudes of the Southern Hemisphere. In the other experiment, where only the southern Indian Ocean and the tropical Pacific are freely interactive with the atmosphere, two types of both positive and negative IOSD occur. Since the occurrence frequency of the IOSD significantly increases as compared to the second experiment, this result confirms that the atmospheric teleconnection from ocean-atmosphere coupled modes in the tropical Pacific such as ENSO may also induce the variations in the Mascarene High that generate the IOSD. The present research, even within the realm of model studies, shows clearly that the predictability of the IOSD in mid-latitudes is related to both low and high-latitudes climate variations.     

Respective influences of IOD and ENSO on the Tibetan snow cover in early winter

Using reanalysis data and snow cover data derived from satellite observations, respective influences of Indian Ocean Dipole (IOD) and El Niño/Southern Oscillation (ENSO) on the Tibetan snow cover in early winter are investigated. It is found that the snow cover shows a significant positive partial correlation with IOD. In the pure positive IOD years with no co-occurrences of El Niño, negative geopotential height anomalies north of India are associated with warm and humid southwesterlies to enter the plateau from the Bay of Bengal after rounding cyclonically and supply more moisture. This leads to more precipitation, more snow cover, and resultant lower surface temperature over the plateau. These negative geopotential height anomalies north of India are related to the equivalent barotropic stationary Rossby waves in the South Asian wave guide. The waves can be generated by the IOD-related convection anomalies over the western/central Indian Ocean. In contrast, in the pure El Niño years with no co-occurrences of the positive IOD, the anomalies of moisture supply and surface temperature over the plateau are insignificant, suggesting negligible influences of ENSO on the early winter Tibetan snow cover. Further analyses show that ENSO is irrelevant to the spring/early summer Tibetan snow cover either, whereas the IOD-induced snow cover anomalies can persist long from the early winter to the subsequent early summer.     

Tropical Indian Ocean variability revealed by self-organizing maps

The tropical Indian Ocean climate variability is investigated using an artificial neural network analysis called self-organizing map (SOM) for both observational data and coupled model outputs. The SOM successfully captures the dipole sea surface temperature anomaly (SSTA) pattern associated with the Indian Ocean Dipole (IOD) and basin-wide warming/cooling associated with ENSO. The dipole SSTA pattern appears only in boreal summer and fall, whereas the basin-wide warming/cooling appears mostly in boreal winter and spring owing to the phase-locking nature of these phenomena. Their occurrence also undergoes significant decadal variation. Composite diagrams constructed for nodes in the SOM array based on the simulated SSTA reveal interesting features. For the nodes with the basin-wide warming, a strong positive SSTA in the eastern equatorial Pacific, a negative Southern Oscillation, and a negative precipitation anomaly in East Africa are found. The nodes with the positive IOD are associated with a weak positive SSTA in the central equatorial Pacific or positive SSTA in the eastern equatorial Pacific, a positive (negative) sea level pressure anomaly in the eastern (western) tropical Indian Ocean, and a positive precipitation anomaly over East Africa. The warming in the central equatorial Pacific appears to correspond to El Niño Modoki discussed recently. These results suggest usefulness of SOM in studying large-scale ocean–atmosphere coupled phenomena.     

IOD influence on the early winter tibetan plateau snow cover: diagnostic analyses and an AGCM simulation

Using diagnostic analyses and an AGCM simulation, the detailed mechanism of Indian Ocean Dipole (IOD) influence on the early winter Tibetan Plateau snow cover (EWTPSC) is clarified. In early winter of pure positive IOD years with no co-occurrence of El Ni?o, the anomalous dipole diabatic heating over the tropical Indian Ocean excites the baroclinic response in the tropics. Since both baroclinic and barotropic components of the basic zonal wind over the Arabian Peninsula increase dramatically in early winter due to the equatorward retreat of the westerly jet, the baroclinic mode excites the barotropic Rossby wave that propagates northeastward and induces a barotropic cyclonic anomaly north of India. This enables the moisture transport cyclonically from the northern Indian Ocean toward the Tibetan Plateau. The convergence of moisture over the plateau explains the positive influence of IOD on the EWTPSC. In contrast, the basic zonal wind over the Arabian Peninsula is weak in autumn. This is not favorable for excitation of the barotropic Rossby wave and teleconnection, even though the IOD-related diabatic heating anomaly in autumn similar to that in early winter exists. This result explains the insignificant (significant positive) partial correlation between IOD and the autumn (early winter) Tibetan Plateau snow cover after excluding the influence of ENSO. The sensitivity experiment forced by the IOD-related SST anomaly within the tropical Indian Ocean well reproduces the baroclinic response in the tropics, the teleconnection from the Arabian Peninsula, and the increased moisture supply to the Tibetan Plateau. Also, the seasonality of the atmospheric response to the IOD is simulated.     

Surface morphological features of boulders on Asteroid 25143 Itokawa

On the sub-kilometer S-type asteroid, 25143 Itokawa, some boulders on rough terrains seem to be exposed without any powdery material covering. Based on surface morphological features, there are two major types of boulders: one has rounded edges and corners (rounded boulders), while the other has angular edges and corners (angular boulders). The surface features of the rounded boulders suggest that they have hardness heterogeneity and that some may be breccias. The angular boulders appear to be more resistant to impact disruption than the rounded ones, which may be due to a difference in lithology. The major constituents of Itokawa may be LL chondrite-like brecciated lithology (rounded boulders) along with a remarkable number of boulders suggesting that lithology is atypical among LL chondrites (angular boulders). Some of both types of boulders contain intersecting and stepped planar foliations. Comparison with meteorite ALH76009 suggests that the planar foliations may be marks where rocks were torn apart. As lithified breccias cannot be formed on present-day sub-kilometer-sized Itokawa, it is reasonable that boulders with various lithologies on Itokawa were formed on its large ancestor(s). The rubble-pile structure of Itokawa suggested by its low density (∼1.9 g/cm³) indicates that boulders on Itokawa are reassembled fragments formed by catastrophic disruption of large ancestor(s).