Potential of submarine-cave sediments and oxygen isotope composition of cavernicolous micro-bivalve as a late Holocene paleoenvironmental record

A sediment layer (43 cm thick) and surface sediments (5 cm thick) in a submarine limestone cave (31 m water depth) on the fore-reef slope of Ie Island, off Okinawa mainland, Japan, were examined by visual, mineralogical and geochemical means. Oxygen isotope analysis was performed on the cavernicolous micro-bivalve Carditella iejimensis from both cored sediments and surface sediments, and the water temperature within the cave was recorded for nearly one year. These data show that: (1) water temperature within the cave is equal to that at 30 m deep in the open sea; (2) the biotic and non-biotic environments within the cave have persisted for the past 2000 years; (3) mud-size carbonate detritus is a major constituent of the submarine-cave deposit, and may have come mainly from the suspended carbonate mud produced on the emergent Holocene reef flat over the past two millennia; (4) the δ¹⁸O-derived temperature (T_δ18_O) of C. iejimensis suggests that the species grows between April and July; (5) the T_δ18_O of C. iejimensis from cored sediments implies that there were two warmer intervals, at AD 340 ± 40 and AD 1000 ± 40, which correspond to the Roman Warm Period and Medieval Warm Period, respectively. These suggest that submarine-cave sediments provide unique information for Holocene reef development. In addition, oxygen isotope records of cavernicolous C. iejimensis are a useful tool to reconstruct century-scale climatic variability for the Okinawa Islands during the Holocene.     

A primitive dark inclusion with radiation‐damaged silicates in the Ningqiang carbonaceous chondrite

Abstract— A petrologic and TEM study of a remarkable dark inclusion (DI) in the Ningqiang CV3 chondrite reveals that it is a mixture of highly primitive solar nebula materials. The DI contains two lithologies. The first, lithology A, contains micron‐sized olivine and pyroxene grains rimmed by amorphous materials with compositions similar to the underlying crystalline grains. The second, lithology B, appears to preserve the mineralogy of lithology A before formation of the amorphous rims. Overall, the Ningqiang DI appears to record the following processes: 1) formation (condensation and Fe‐enrichment) of olivine crystals in the nebula with compositions of Fo_42–62; 2) irradiation, resulting in amorphitization of the olivine and pyroxene to varying degrees; 3) partial annealing, resulting in formation of fairly large, euhedral olivine and pyroxene grains with remnant amorphous sharply‐bounded rims; 4) in some cases, prolonged annealing, resulting in the formation of microcrystalline olivine or pyroxene rims. The latter annealing would have been a natural consequence of irradiation near the critical temperature for olivine; and 5) mixture of the above materials (lithology A) with nebular condensate high‐Ca pyroxene and olivine, which escaped nebular processing, to become lithology B. We suggest that the amorphous rims in lithology A formed in an energetic solar event such as a bi‐polar outflow or FU‐orionis flare.     

Noble gas isotopes and mineral assemblages of Antarctic micrometeorites collected at the meteorite ice field around the Yamato Mountains

Abstract— From November 1998 to January 1999, the 39th Japanese Antarctic Research Expedition (JARE) conducted a large‐scale micrometeorite collection at 3 areas in the meteorite ice field around the Yamato Mountains, Antarctica. The Antarctic micrometeorites (AMMs) collected were ancient cosmic dust particles. This is in contrast with the Dome Fuji AMMs, which were collected previously from fresh snows in 1996 and 1997 and which represent modern micrometeorites. To determine the noble gas concentrations and isotopic compositions of individual AMMs, noble gas analyses were carried out using laser‐gas extraction for 35 unmelted Yamato Mountains AMMs and 3 cosmic spherules. X‐ray diffraction analyses were performed on 13 AMMs before the noble gas measurement and mineral compositions were determined. AMMs are classified into 4 main mineralogical groups, defined from the heating they suffered during atmospheric entry. Heating temperatures of AMMs, inferred from their mineral compositions, are correlated with ⁴He concentrations and reflect the effect of degassing during atmospheric entry. Jarosite, an aqueous alteration product, is detected for 4 AMMs, indicating the aqueous alteration during long‐time storage in Antarctic ice. Jarosite‐bearing AMMs have relatively low concentrations of 4He, which is suggestive of loss during the alteration. High ³He/⁴He ratios are detected for AMMs with high ²⁰Ne/⁴He ratios, showing both cosmogenic ³He and preferential He loss. SEP (solar energetic particles)‐He and Ne, rather than the solar wind (SW), were dominant in AMMs, presumably showing a preferential removal of the more shallowly implanted SW by atmospheric entry heating. The mean ²⁰Ne/²²Ne ratio is 11.27 ± 0.35, which is close to the SEP value of 11.2. Cosmogenic ²¹Ne is not detected in any of the particles, which is probably due to the short cosmic ray exposure ages. Ar isotopic compositions are explained by 3‐component mixing of air, Q, and SEP‐Ar. Ar isotopic compositions can not be explained without significant contributions of Q‐Ar. SEP‐Ne contributed more than 99% of the total Ne. As for ³⁶Ar and ³⁸Ar, the abundance of the Q component is comparable to that of the SEP component. ⁸⁴Kr and ¹³²Xe are dominated by the primordial component, and solar‐derived Xe is almost negligible.     

Equivalent forcing depth in tropical oceans

The forcing efficiency for the first and the second baroclinic modes by the wind stress in tropical oceans has been discussed by calculating equivalent forcing depth from annual mean, seasonal, and pentadal density profiles of the observational data. In the annual mean field, the first mode is forced preferentially in the western Pacific and the Indian Ocean, whereas the second mode is more strongly excited in the Atlantic and the eastern Pacific. This difference is mostly due to the pycnocline depth; the second mode is more dominantly forced where the pycnocline depth is shallower. We also revealed large seasonal variations of the second mode's equivalent forcing depth in the western Indian Ocean. The first mode is more dominantly forced during boreal spring and fall in the western Indian Ocean, while the second mode becomes more dominantly forced during boreal summer and winter. Those are due to seasonal variations of both the zonal wind and the pycnocline depth. Moreover, we show that the excitation of the second mode in the western Pacific increases after the late 1970s, which is associated with the decreasing trend of the zonal pycnocline gradient. Revealing the variation of the equivalent forcing depth will be useful for understanding the oceanic response to winds in tropical oceans and the improvement in the predictability of air-sea coupled climate variability in the tropics.     

Measurements of east Tushima Current in winter and estimation of its seasonal variability

The Tushima Current in the east channel was measured in a site of the strong current between Tushima and Iki Islands for 43 days of the winter in 1986. The primary results are:First, it was highly barotropic and flowed northeastward with a mean speed of about 20 cm sec^–1. Second, it was decelerated by northeast winds rather than by northwest winds in a frequency range of 0.3 and 0.4 cpd. Third, the scale analysis showed that the Tushima Current is approximately in geostrophic balance. The best empirical relationship between the measured Tushima Current and cross-channel adjusted sea level difference is given by

Reconstruction of paleotemperatures in the Northwest Pacific over the past 3000 years from δO values of the micro-bivalvia Carditella iejimensis found in a submarine cave

We measured the δ¹⁸O values of the whole shells of the cavernicolous micro-bivalvia Carditella iejimensis obtained from sediments within a submarine cave (31 m water depth) at Ie Island (Okinawa Island, Japan) in the subtropical Northwest Pacific. Our results show no significant millennial-scale trend in the δ¹⁸O record, implying that both springtime temperature and the δ¹⁸O of sea water at 30 m depth around the Okinawa Islands have been stable for the past 3000 years at values similar to those of today. Moreover, we found one exceptionally light δ¹⁸O value from specimens spanning the past 250 years. The δ¹⁸O-derived temperature represents a departure of 2.1 °C from the average value for the past 250 years, being equal to the departure recorded during unusually high temperatures in the spring of 1998. This finding may imply that such high springtime sea surface temperature has been a rare event over the past 3000 years.     

Impact-induced chondrule flattening in the Allende CV3 carbonaceous chondrite: Shock experiments

Abstract— We have carried out shock-recovery experiments on the Allende CV3 carbonaceous chondrite using a single-stage propellant gun and succeeded in reproducing oriented, flattened chondrules like those observed in some natural CV3 chondrites. The Allende samples were shocked at equilibrium pressures of 11 and 21 GPa, which are close to the highest values in shock stages S2 and S3, respectively (Stöffler et al., 1991). Chondrules are flattened nearly perpendicular to the compaction axis with mean aspect ratios of 1.34 and 1.62 at pressures of 11 and 21 GPa, respectively; thus, the degree of chondrule flattening is proportional to the shock intensity. The chondrule flattening and foliation are mainly due to collapse of pores in the matrix under shock pressure. High matrix abundance of CV3 chondrites could result in much apparent chondrule flattening relative to ordinary chondrites. Optical and electron microscope observations show that textural and mineralogical characteristics of chondrules and matrix in the shock-loaded samples are very similar to those observed in naturally shocked CV3 chondrites. Our results provide strong support for the interpretation that the chondrule flattening and foliation in CV3 chondrites were caused by shock-induced pressure due to hypervelocity impacts on the meteorite parent bodies.     

Dynamical seasonal prediction of Southern African summer precipitation

Prediction skill for southern African (16°–33°E, 22°–35°S) summer precipitation in the Scale Interaction Experiment-Frontier coupled model is assessed for the period of 1982–2008. Using three different observation datasets, deterministic forecasts are evaluated by anomaly correlation coefficients, whereas scores of relative operating characteristic and relative operating level are used to evaluate probabilistic forecasts. We have found that these scores for December–February precipitation forecasts initialized on October 1st are significant at 95 % confidence level. On a local scale, the level of prediction skill in the northwestern and central parts of southern Africa is higher than that in northeastern South Africa. El Niño/Southern Oscillation (ENSO) provides the major source of predictability, but the relationship with ENSO is too strong in the model. The Benguela Niño, the basin mode in the tropical Indian Ocean, the subtropical dipole modes in the South Atlantic and the southern Indian Oceans and ENSO Modoki may provide additional sources of predictability. Within the wet season from October to the following April, the precipitation anomalies in December-February are the most predictable. This study presents promising results for seasonal prediction of precipitation anomaly in the extratropics, where seasonal prediction has been considered a difficult task.     

Space weathered rims found on the surfaces of the Itokawa dust particles

On the basis of observations using Cs‐corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2–3 nm), (2) composite rims (30–60 nm), and (3) composite vesicular rims (60–80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two‐layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation‐induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa.