Measurements and Observations in the XXI century (MOXXI): innovation and multi-disciplinarity to sense the hydrological cycle

To promote the advancement of novel observation techniques that may lead to new sources of information to help better understand the hydrological cycle, the International Association of Hydrological Sciences (IAHS) established the Measurements and Observations in the XXI century (MOXXI) Working Group in July 2013. The group comprises a growing community of tech-enthusiastic hydrologists that design and develop their own sensing systems, adopt a multi-disciplinary perspective in tackling complex observations, often use low-cost equipment intended for other applications to build innovative sensors, or perform opportunistic measurements. This paper states the objectives of the group and reviews major advances carried out by MOXXI members toward the advancement of hydrological sciences. Challenges and opportunities are outlined to provide strategic guidance for advancement of measurement, and thus discovery.     

Utilization of carbon sources in a northern Brazilian mangrove ecosystem

Carbon and nitrogen stable isotope ratios (¹³C and ¹⁵N) and trophic level (TL) estimates based on stomach content analysis and published data were used to assess the contribution of autotrophic sources to 55 consumers in an intertidal mangrove creek of the Curuçá estuary, northern Brazil. Primary producers showed δ¹³C signatures ranging between −29.2 and −19.5‰ and δ¹⁵N from 3.0 to 6.3‰. The wide range of the isotopic composition of carbon of consumers (−28.6 to −17.1‰) indicated that different autotrophic sources are important in the intertidal mangrove food webs. Food web segregation structures the ecosystem into three relatively distinct food webs: (i) mangrove food web, where vascular plants contribute directly or indirectly via POM to the most ¹³C-depleted consumers (e.g. Ucides cordatus and zooplanktivorous food chains); (ii) algal food web, where benthic algae are eaten directly by consumers (e.g. Uca maracoani, mullets, polychaetes, several fishes); (iii) mixed food web where the consumers use the carbon from different primary sources (mainly benthivorous fishes). An IsoError mixing model was used to determine the contributions of primary sources to consumers, based on δ¹³C values. Model outputs were very sensitive to the magnitude of trophic isotope fractionation and to the variability in ¹³C data. Nevertheless, the simplification of the system by a priori aggregation of primary producers allowed interpretable results for several taxa, revealing the segregation into different food webs.     

First record of Prorocentrum lima (Dinophyceae) inside harbor areas and along the Abruzzo region coast, W Adriatic

Prorocentrum lima (Ehrenberg) Dodge has been found for the first time during the summer of 2007 inside Ortona harbor and along the coast of the Abruzzo region, a slightly eutrophic area influenced by runoff from a nearby river. The investigations were conducted in two harbors and at six coastal sampling stations. Samplings were conducted using a phytoplankton net and with a pump. Average P. lima cellular concentrations were 3.2 × 10⁴ cells L⁻¹. Other well-known toxic and potentially toxic phytoplankton species have been considered. The number of toxic cells from net samples were higher than the numbers of toxic cell samples collected without the net. Occurrences of P. lima with abiotic factors revealed that temperature was positively correlated with P. lima abundance (p = 0.01), while salinity was highly negatively correlated with P. lima presence (p = 0.001). The total phytoplankton community was studied.     

Coastal hazard assessment and mapping in Northern Campania, Italy

In the Northern Campanian coastal zone, over 150 km long, three geomorphic units are recognised: (1) sandy beaches that are well developed in the northern area, where a prominent river mouth (Volturno River) is also present; (2) steep and rocky shores, often with gravelly beaches or debris cones at their base, are mainly diffuse in the southern area (Sorrentine Peninsula); and, lastly, (3) “techno coast”, shorelines stabilized with revetments and seawalls as well as former natural environments no longer clearly operational because of urbanization, as is visible in Naples and in the Vesuvian coast. Six primary hazards are considered in this investigation: shoreline erosion, riverine flooding, storms, landslides, seismicity and volcanism, and man-made structures. These hazards do not have a uniform distribution along this coast in terms of their frequency and intensity; moreover both their interaction and the intensive action of humans, often uncontrolled, makes it difficult to assess the overall coastal hazard. In this paper a semi-quantitative method with which to quantify, rank and map the distribution of hazard is applied along this particular stretch of coast. In such a stretch, previously characterized in terms of types and processes and compartmentalized into geomorphic units, the effect of individual hazards, based on their magnitude and recurrence, is evaluated. Dominant and subordinate hazards for each geomorphic unit are identified, assigning a rank that is also a weighting. Comparison of each weighting through an interaction matrix permits the calculation of a resultant, which is the overall hazard assessment and which can be expressed cartographically. The results obtained for a coastal zone with one of the highest pressures from urbanization in the world, help us to recognise that this approach could become a useful tool to aid decision-making regarding coastal land-use and planning.     

Continuous soil CO<Superscript>2</Superscript> and discrete plume SO<Subscript>2</Subscript> measurements at Mt. Etna (Italy) during 1997–2000: a contribution to volcano monitoring

Continuous monitoring of soil CO₂ dynamic concentration (which is proportional to the CO₂ flux through the soil) was carried out at a peripheral site of Mt. Etna during the period November 1997–September 2000 using an automated station. The acquired data were compared with SO₂ flux from the summit craters measured two to three times a week during the same period. The high frequency of data acquisition with both methods allowed us to analyze in detail the time variations of both parameters. Anomalous high values of soil CO₂ dynamic concentration always preceded periods of increased flux of plume SO₂, and these in turn were followed by periods of summit eruptions. The variations were modeled in terms of gas efflux increase due to magma ascent to shallow depth and its consequent depressurization and degassing. This model is supported by data from other geophysical and volcanological parameters. The rates of increase both of soil CO₂ dynamic concentration and of plume SO₂ flux are interpreted to be positively correlated both to the velocity of magma ascent within the volcano and to lava effusion rate once magma is erupted at the surface. Low rates of the increase were recorded before the nine-month-long 1999 subterminal eruption. Higher rates of increase were observed before the violent summit eruption of September-November 1999, and the highest rates were observed during shorter and very frequent spike-like anomalies that preceded the sequence of short-lived but very violent summit eruptions that started in late January 2000 and continued until late June of the same year. Furthermore, the time interval between the peaks of CO₂ and SO₂ in a single sequence of gas anomalies is likely to be controlled by magma ascent velocity.Editorial responsibility: H. Shinohara     

Saint-Pierre-le-Viger (L5-6) from asteroid 2023 CX1 recovered in the Normandy,France—220 years after the historic fall of L'Aigle (L6 breccia) in the neighborhood

On February 13, 2023, a huge fireball was visible over Western Europe (fireball event 2023 CX₁). After the possible strewn field was calculated, the first of several recovered samples, with a mass of about 100 g, was discovered just 2 days after the fireball event on the ground of the village of Saint-Pierre-le-Viger. Meanwhile, more than 60 samples with a total mass of more than 1 kg were recovered and a piece of one of these is studied here. The fall occurred 220 years after the historic meteorite fall of L'Aigle on April 26, 1803, <120 km south. L'Aigle is the closest meteorite fall to Saint-Pierre-le-Viger and belongs to the same chondrite group. Both meteorites are breccias containing only clasts of high metamorphic degree (type 5 and type 6). Since only 20% of the L chondrites are breccias this coincidence is remarkable. As just mentioned, both samples studied from these rocks in this work are ordinary chondrite breccias and consist of equilibrated and recrystallized lithologies of petrologic type 6. The brecciated texture in L'Aigle, resulting in a remarkable light–dark structure, is more pronounced than the brecciated features in Saint-Pierre-le-Viger, from which also type 5 fragments have been reported. The compositions of low-Ca pyroxene and olivine grains in Saint-Pierre-le-Viger (Fs_21.2 and Fa_23.4, respectively) clearly require an L-group classification. L'Aigle was classified as an L6 breccia in the past, and this has now been confirmed by new data on low-Ca pyroxene and olivine (Fs_20.7 and Fa_23.8, respectively). Saint-Pierre-le-Viger contains local thin shock veins, and both meteorites are moderately shocked. Most olivines in the studied samples have planar fractures, but the estimated abundance of mosaicized olivines of 30%–40% among the large grains require a S4 shock classification. Oxygen isotope and bulk chemical data of Saint-Pierre-le-Viger certainly support the L chondrite classification. Bulk spectral data of Saint-Pierre-le-Viger are dominated by silicate minerals, that is, Fe-bearing low-Ca pyroxene, olivine, and plagioclase. Isotopic, chemical, and spectral data of the L'Aigle meteorite are shown for comparison and are very similar, providing additional circumstantial evidence of Saint-Pierre-le-Viger's L chondritic nature.     

High precision triple oxygen isotope composition of small size urban micrometeorites indicating constant influx composition in the early geologic past

In this study, we present a method for high precision Δ′¹⁷O (Δ′¹⁷O_RL = ln(δ¹⁷O + 1) – λ_RL ln(δ¹⁸O + 1)) analysis of small mass silicate and oxide materials. The analyses were conducted by laser fluorination in combination with gas chromatography and continuous flow isotope ratio monitoring gas spectrometry. We could analyze the oxygen isotope composition of samples down to 1 μg, which corresponded to about 13 nmol O₂. The analytical error (we report the 1σ external reproducibility of a single analysis) in δ¹⁸O increases with decreasing sample sizes from ~0.2‰ for ~20 μg samples to ~0.9‰ for 1 μg samples. For Δ′¹⁷O, we achieved an external reproducibility of 0.04‰ for a sample mass range between 1 and 27 μg. The uncertainty in Δ′¹⁷O is smaller than the uncertainty in δ¹⁸O due to the correlated errors in δ¹⁷O and δ¹⁸O. We applied the method to urban micrometeorites, that is, small meteorites (<2 mm) that were sampled from a rooftop in Berlin, Germany. A total of 10 melted micrometeorites (S-type cosmic spherules, masses between 11 and 22 μg) were analyzed. The oxygen isotope compositions are comparable to that of modern Antarctic collections, indicating that the urban micrometeorites sample the same population. No indication for terrestrial weathering had been identified in the studied set of urban micrometeorites making them suitable materials for the study of micrometeorite origins.     

Presence of plastic debris in loggerhead turtle stranded along the Tuscany coasts of the Pelagos Sanctuary for Mediterranean Marine Mammals (Italy)

This work evaluated the presence and the frequency of occurrence of marine litter in the gastrointestinal tract of 31 Caretta caretta found stranded or accidentally bycaught in the North Tyrrhenian Sea. Marine debris were present in 71% of specimens and were subdivided in different categories according to Fulmar Protocol (OSPAR 2008). The main type of marine debris found was user plastic, with the main occurrence of sheetlike user plastic. The small juveniles showed a mean ± SD of marine debris items of 19.00 ± 23.84, while the adult specimens showed higher values of marine litter if compared with the juveniles (26.87 ± 35.85). The occurrence of marine debris observed in this work confirms the high impact of marine debris in the Mediterranean Sea in respect to other seas and oceans, and highlights the importance of Caretta caretta as good indicator for marine litter in the Marine Strategy Framework Directive (MSFD) of European Union.