Rupture of an evaporating liquid bridge between two grains

The study examines rupture of evaporating liquid bridges between two glass spheres. Evolution of the bridge profile has been recorded with the use of high-speed camera. Geometrical characteristics of the bridge were then used to calculate evolution of the variables during the process: Laplace pressure, capillary force, and surface tension force. For the purpose of reference, the bridge evolution is followed also during kinematic extension. During both processes the diameter of the neck decreases, with an acceleration of about 1–2 ms before the rupture. Two distinct rupture modes are observed, depending on the bridge aspect ratio. After the rupture, the mass of liquid splits, forming two separate oscillating drops attached to the spheres, and a suspended satellite droplet. Just before the rupture, an increasing repulsive Laplace pressure, and decreasing negative surface tension force develop. Capillary force follows the trend of the surface tension force, with an accelerating decline. Duration of the whole process and liquid mass stabilization is from 10 to 60 ms.     

Studies of aerosol optical depth with the use of Microtops II sun photometers and MODIS detectors in coastal areas of the Baltic Sea

In this paper we describe the results of a research campaign dedicated to the studies of aerosol optical properties in different regions of both the open Baltic Sea and its coastal areas. During the campaign we carried out simultaneous measurements of aerosol optical depth at 4 stations with the use of the hand-held Microtops II sun photometers. The studies were complemented with aerosol data provided by the MODIS. In order to obtain the full picture of aerosol situation over the study area, we added to our analyses the air mass back-trajectories at various altitudes as well as wind fields. Such complex information facilitated proper conclusions regarding aerosol optical depth and Ångström exponent for the four locations and discussion of the changes of aerosol properties with distance and with changes of meteorological factors. We also show that the Microtops II sun photometers are reliable instruments for field campaigns. They are easy to operate and provide good quality results.     

Various Approaches to Forward and Inverse Wide-Angle Seismic Modelling Tested on Data from DOBRE-4 Experiment

The interpretation of seismic refraction and wide angle reflection data usually involves the creation of a velocity model based on an inverse or forward modelling of the travel times of crustal and mantle phases using the ray theory approach. The modelling codes differ in terms of model parameterization, data used for modelling, regularization of the result, etc. It is helpful to know the capabilities, advantages and limitations of the code used compared to others.This work compares some popular 2D seismic modelling codes using the dataset collected along the seismic wide-angle profile DOBRE-4, where quite peculiar/uncommon reflected phases were observed in the wavefield.The ~505 km long profile was realized in southern Ukraine in 2009, using 13 shot points and 230 recording stations. Double P_MP phases with a different reduced time (7.5–11 s) and a different apparent velocity, intersecting each other, are observed in the seismic wavefield. This is the most striking feature of the data. They are interpreted as reflections from strongly dipping Moho segments with an opposite dip. Two steps were used for the modelling. In the previous work by Starostenko et al. (2013), the trial-and-error forward model based on refracted and reflected phases (SEIS83 code) was published. The interesting feature is the high-amplitude (8–17 km) variability of the Moho depth in the form of downward and upward bends. This model is compared with results from other seismic inversion methods: the first arrivals tomography package FAST based on first arrivals; the JIVE3D code, which can also use later refracted arrivals and reflections; and the forward and inversion code RAYINVR using both refracted and reflected phases. Modelling with all the codes tested showed substantial variability of the Moho depth along the DOBRE-4 profile. However, SEIS83 and RAYINVR packages seem to give the most coincident results.     

Upper lithospheric structure in the central Fennoscandian shield: Constraints from P- and S-wave velocity models and V<Subscript>P</Subscript>/V<Subscript>S</Subscript> ratio distribution of the BALTIC wide-angle seismic profile

The paper presents an analysis of the crust and upper mantle structure in the central Fennoscandian shield based on new P- and S-wave 2D velocity models of the BALTIC wide-angle reflection and refraction profiles. Using reprocessing of the old data, new P- and S-wave velocity models and V _P /V _S ratio distribution were developed. Moving from SW to NE, the thickness of the crust varies strongly, from ∼36 km to extremely thick, 58–64 km, crossing Wiborg rapakivi massif, Saimaa and Outokumpu areas, and Eastern Finland complex. Based on the lateral variations of V _P , V _P /V _S and thickness of the crust, three main blocks of the crust and upper mantle were distinguished from SW to NE: southwestern, associated with Wiborg rapakivi massif; the central, having the highest thickness of the crust; and the northeastern, not well documented, with Archaean basement.     

Late Glacial and Holocene depositional history in the eastern part of the Szczecin Lagoon (Great Lagoon) basin—NW Poland

Analyses on 27 sediment cores taken from the bottom of the Szczecin Lagoon allowed environmental reconstruction of the postglacial main stages of basin development, based on detailed sedimentological, geochemical, diatomological and malacological studies of selected key cores. Studies revealed that during the Late Glacial and Holocene this area developed in several stages. In the Late Glacial the whole study area constituted a low alluvial plain. At the turn from Younger Dryas to Holocene the alluvial plain was cut through by the Odra river to a level of 10–11 m below sea level (b.s.l.). Along with the first phases of the Holocene marine transgression at the southern Baltic Sea's coasts the accumulation of the limnic-swampy deposits began in this lower part of the Odra valley. At ca. 6–6.5 ka BP the transgression proceeded and Littorina Sea waters flooded the area. At that time the Szczecin Lagoon constituted a marine embayment in which series of sands, partly rich in malacofauna, was deposited. The development of the Swina barrier resulted in the isolation of the embayment from the direct inflow of Baltic Sea waters.     

Solubility of pyromorphite Pb5(PO4)3Cl-mimetite Pb5(AsO4)3Cl solid solution series

Pyromorphite Pb₅(PO₄)₃Cl and mimetite Pb₅(AsO₄)₃Cl are isostructural minerals with apatite. Due to their high environmental stability, they have gained considerable attention as metals sequestration agents in water treatment and contaminated soil remediation. Pyromorphite and mimetite can form a continuous solid solution series in near-Earth surface environments. Precipitation of the end members and intermediate members of the series is likely to occur in the areas where the cost-effective in situ immobilization reclamation method, based on phosphate amendments, is applied. In contrast to the widely studied thermodynamic parameters of pyromorphite and mimetite, knowledge of the thermodynamics of their solid solutions is sparse. To supplement the data, a number of compounds from the pyromorphite-mimetite series were synthesized at room temperature using a method to simulate the conditions in the near-Earth surface environments. Afterwards, batch dissolution and dissolution-recrystallization experiments of seven synthesized precipitates were conducted at 25 °C, pH = 2 and in a 0.05 M KNO₃ background electrolyte. The experiments were carried out for a period of 6 (dissolution) and 14 (dissolution-recrystallization) months. A plateau in the [Pb] evolution patterns was used to determine equilibrium. All seven dissolutions were congruent, and the ionic activity products (IAP) of the minerals from the pyromorphite-mimetite solid solution series were calculated based on the dissolution reaction: . The IAPs for pyromorphite and mimetite exhibit a significant difference in values over three orders of magnitude between approximately 10⁻⁷⁹ for pyromorphite and approximately 10⁻⁷⁶ for mimetite. The series appeared to be ideal, and Lippmann and Roozboom diagrams were used for better understanding of its thermodynamics. The results indicated a strong tendency of pyromorphite to partition into the solid phase in the series, which explains some of the naturally observed phenomena. The improvement of the lattice stability of the mimetite due to isostructural phosphate substitutions in anionic sites was observed. The thermodynamic data reported in this study supplement existing databases used in geochemical modeling.     

A late Cenozoic Earth's crust and climate dynamics record from Lake Baikal

The sedimentary record from Lake Baikal (Siberia, Russia) has been an important source of information about paleoclimatic variability in the northern hemisphere and dynamics of continental rift development. A lack of reliable chronology has, however, been a major obstacle to fully utilizing the Baikal archive for time scales beyond about 4-5 Myr. In this paper we use the distribution of ¹⁰Be to establish a new chronology for the longest core drilled in Lake Baikal so far. The ¹⁰Be-based chronology spans the last 8 Myr and provides better constraints on sedimentation rates and consequently on an east-west tectonic extension in the lake, which has been apparently coeval with other rifts in Asia that are related to the Tibetan plateau uplift. Our data also show higher ¹⁰Be flux in the sediment section older then 5 Myr compared with the younger period. This can be explained partly by warm and humid climatic conditions of the Miocene and partly by a high cosmic ray flux to the Earth resulting from possible low geomagnetic field intensity during that time.