Bioremediation of Chlorinated Pesticides in Field‐Contaminated Soils and Suitability of Tenax Solid‐Phase Extraction as a Predictor of Its Effectiveness

Bioremediation is intensively studied today as a treatment method for soil contaminated with chlorinated pesticides, chemicals counted among persistent organic pollutants. In the presented work, results of desorption kinetics study using consecutive Tenax TA solid phase extraction (SPE) were tested as predictors of 3‐wk anaerobic soil bioremediation effectiveness for chlorinated pesticides γ‐HCH, DDT, and methoxychlor. Field‐contaminated samples were used in these experiments, and conditions of bioremediation tests were based on previous research. Amounts of pesticides removed during bioremediation (43–98% of initial concentrations) were in most cases much larger (average ratio 1.37) than rapidly desorbing fractions estimated in SPE using two‐compartment model of desorption kinetics. The scatter of results was also considerable (standard deviation 0.45). However, there was a statistically significant correlation between amounts removed and rapidly desorbing fractions (R² = 0.64), indicating a relationship between degradability and desorbability. Nonetheless, determination of rapidly desorbing fractions was considered rather a poor indicator of soil bioremediation efficiency for chlorinated pesticides. The total amounts of pesticides desorbed by Tenax in 72 h performed better in this respect (R² = 0.73, fraction removed/desorbed = 1.10 ± 0.20, average ± standard deviation). Disappearance of DDT during bioremediation was accompanied by DDD formation but this was considerably lower than results expected from stoichiometry.     

Trace metals distribution pattern in floodplain sediments of a lowland river in relation to contemporary valley bottom morphodynamics

The distribution of trace metals in alluvial sediments depends on their natural background concentrations, and on the dynamics of contemporary depositional and erosional (mainly flood‐induced) processes. Geological and geochemical investigations were carried out in the valley of Vistula River near Magnuszew (central Poland). Sediment samples were collected from a depth of 35 cm and comprise sediments of all defined geomorphological features. Identification and geological interpretation of the morphodynamic sediment features was supported by aerial photographs and high‐resolution satellite images. These studies revealed that the distribution of trace metals is closely linked to the morphogenesis of the alluvial floodplain. The highest concentrations of Cu, Co, Zn, V, Cr and Ni were observed in crevasse‐splays deposits. By contrast, Sr, Pb and As were concentrated in deposits which fill oxbow lakes (partly infilled with organic deposits). The lowest concentrations of trace metals were detected in flood sediments deposited within erosional troughs. The geomorphological and sedimentological history of the fluvial features explains the pattern of heavy metal distribution on the current floodplain surface. Copyright © 2014 John Wiley & Sons, Ltd.     

Land use and land cover changes in small Carpathian catchments between the mid-19<Superscript>th</Superscript> and early 21<Superscript>st</Superscript> centuries and their record on the land surface

Land use and land cover (LULC) changes and their impact on the mountain environment were studied in six catchments (~10 km² each) in the Polish Western Carpathians from the mid-19^th century to the early 21^st century. The analysis of cadastral and orthophoto maps indicates that during the investigated period, the forest area increased, quantified by an annual change index (Annch), between +0.12% to +0.27%, with a decrease of arable land index to–0.45% and–2.28% in the analysed catchments. LULC changes were accompanied by a continuous increase in settlement developments (residential and farming houses) by 50%-140% as well as significant changes related to their spatial distribution. Abandonment of arable land and forest succession have resulted in the geomorphological transformation of hillslopes, which predominantly includes a decrease in used road density, their transformation to road cuts and gorges. Overpopulation and the domination agriculture in the past caused the expansion of unpaved roads density and then the fragmentation of hillslopes, as well as the development of agricultural terraces.     

Holocene floristic diversity and richness in northeast Norway revealed by sedimentary ancient DNA (sedaDNA) and pollen

We present a Holocene record of floristic diversity and environmental change for the central Varanger Peninsula, Finnmark, based on ancient DNA extracted from the sediments of a small lake (sedaDNA). The record covers the period c. 10 700 to 3300 cal. a BP and is complemented by pollen data. Measures of species richness, sample evenness and beta diversity were calculated based on sedaDNA sampling intervals and 1000‐year time windows. We identified 101 vascular plant and 17 bryophyte taxa, a high proportion (86%) of which are still growing within the region today. The high species richness (>60 taxa) observed in the Early Holocene, including representatives from all important plant functional groups, shows that modern shrub‐tundra communities, and much of their species complement, were in place as early as c. 10 700 cal. a BP. We infer that postglacial colonization of the area occurred prior to the full Holocene, during the Pleistocene‐Holocene transition, Younger Dryas stadial or earlier. Abundant DNA of the extra‐limital aquatic plant Callitriche hermaphroditica suggests it expanded its range northward between c. 10 200 and 9600 cal. a BP, when summers were warmer than present. High values of Pinus DNA occur throughout the record, but we cannot say with certainty if they represent prior local presence; however, pollen influx values >500 grains cm^?2 a^?1 between c. 8000 and 7300 cal. a BP strongly suggest the presence of pine woodland during this period. As the site lies beyond the modern tree limit of pine, it is likely that this expansion also reflects a response to warmer Early Holocene summers.     

The Bølling‐age Blomvåg Beds,western Norway: implications for the Older Dryas glacial re‐advance and the age of the deglaciation

Blomvåg, on the western coast of Norway north of Bergen, is a classical site in Norwegian Quaternary science. Foreshore marine sediments, named the Blomvåg Beds and now dated to the Bølling‐Allerød from 14.8 to 13.3 cal. ka BP, contain the richest Lateglacial bone fauna in Norway, numerous mollusc shells, driftwood, and flint that some archaeologists consider as the oldest traces of humans in Norway. The main theme of this paper is that the Blomvåg Beds are overlain by a compact diamicton, named the Ulvøy Diamicton, which was interpreted previously as a basal till deposited during a glacial re‐advance into the ocean during the Older Dryas (c. 14 cal. ka BP). Sediment sections of the Blomvåg Beds and the Ulvøy Diamicton were exposed in ditches in a cemetery that was constructed in 1941–42 and have subsequently not been accessible. A number of radiocarbon and cosmogenic ¹⁰Be exposure ages demonstrate that the diamicton is not likely to be a till because minimum deglaciation ages (14.8–14.5 cal. ka BP) from the vicinity pre‐date the Ulvøy Diamicton. We now consider that sea ice and icebergs formed the Ulvøy Diamicton during the Younger Dryas. The Scandinavian Ice Sheet margin was located on the outermost coastal islands between at least c. 18.5 and 14.8 cal. ka BP; however, no ice‐marginal deposits have been found offshore from this long period. The Older Dryas ice margin in this area was located slightly inside the Younger Dryas margin, whereas farther south it was located slightly beyond the Younger Dryas margin.     

Distribution of compact object mergers around galaxies

Compact object mergers are one of the currently favoured models for the origin of gamma-ray bursts (GRBs). The discovery of optical afterglows and identification of the nearest, presumably host, galaxies allow the analysis of the distribution of burst sites with respect to these galaxies. Using a model of stellar binary evolution we synthesize a population of compact binary systems which merge within the Hubble time. We include the kicks in the supernovae explosions and calculate orbits of these binaries in galactic gravitational potentials. We present the resulting distribution of merger sites and discuss the results in the framework of the observed GRB afterglows.     

An experimental model for the tektite fluvial transport based on the most distal Polish moldavite occurrences

Reworking and redeposition of tektites is a highly complex and multistage geological process including many factors. A tumbling experiment was therefore undertaken with the aim of estimating a distance of transport that such moldavites can withstand. Though the experiment probably did not accurately mimic natural conditions, our results proved that moldavites can withstand considerable transport only over a distance of a few kilometers. Observed abrasion of tektites was significant in the early stage of experimental transport; the rate of abrasion decreased correlatively with increasing distance of transport as usual. Overall, given the results obtained from this experimental study and their state of preservation described in the literature, it is very likely that Polish tektites were reworked and redeposited by rivers from the Sudetes Mountains. Based on the paleoreconstruction of river flows, it can be assumed that the Polish tektites originated from two independent sediment supply areas.     

What can we learn from the projections of changes of flow patterns? Results from Polish case studies

River flow projections for two future time horizons and RCP 8.5 scenario, generated by two projects (CHASE-PL and CHIHE) in the Polish-Norwegian Research Programme, were compared. The projects employed different hydrological models over different spatial domains. The semi-distributed, process-based, SWAT model was used in the CHASE-PL project for the entire Vistula and Odra basins area, whilst the lumped, conceptual, HBV model was used in the CHIHE project for eight Polish catchments, for which the comparison study was made. Climate projections in both studies originated from the common EURO-CORDEX dataset, but they were different, e.g. due to different bias correction approaches. Increases in mean annual and seasonal flows were projected in both studies, yet the magnitudes of changes were largely different, in particular for the lowland catchments in the far future. The HBV-based increases were significantly higher in the latter case than the SWAT-based increases in all seasons except winter. Uncertainty in projections is high and creates a problem for practitioners.     

Real-time precise point positioning augmented with high-resolution numerical weather prediction model

GPS Solutions - The tropospheric delay is one of the major error sources in precise point positioning (PPP), affecting the accuracy and precision of estimated coordinates and convergence time,...