Impact of ocean model resolution on CCSM climate simulations

The current literature provides compelling evidence suggesting that an eddy-resolving (as opposed to eddy-permitting or eddy-parameterized) ocean component model will significantly impact the simulation of the large-scale climate, although this has not been fully tested to date in multi-decadal global coupled climate simulations. The purpose of this paper is to examine how resolved ocean fronts and eddies impact the simulation of large-scale climate. The model used for this study is the NCAR Community Climate System Model version 3.5 (CCSM3.5)—the forerunner to CCSM4. Two experiments are reported here. The control experiment is a 155-year present-day climate simulation using a 0.5° atmosphere component (zonal resolution 0.625 meridional resolution 0.5°; land surface component at the same resolution) coupled to ocean and sea-ice components with zonal resolution of 1.2° and meridional resolution varying from 0.27° at the equator to 0.54° in the mid-latitudes. The second simulation uses the same atmospheric and land-surface models coupled to eddy-resolving 0.1° ocean and sea-ice component models. The simulations are compared in terms of how the representation of smaller scale features in the time mean ocean circulation and ocean eddies impact the mean and variable climate. In terms of the global mean surface temperature, the enhanced ocean resolution leads to a ubiquitous surface warming with a global mean surface temperature increase of about 0.2?°C relative to the control. The warming is largest in the Arctic and regions of strong ocean fronts and ocean eddy activity (i.e., Southern Ocean, western boundary currents). The Arctic warming is associated with significant losses of sea-ice in the high-resolution simulation. The sea surface temperature gradients in the North Atlantic, in particular, are better resolved in the high-resolution model leading to significantly sharper temperature gradients and associated large-scale shifts in the rainfall. In the extra-tropics, the interannual temperature variability is increased with the resolved eddies, and a notable increases in the amplitude of the El Ni?o and the Southern Oscillation is also detected. Changes in global temperature anomaly teleconnections and local air-sea feedbacks are also documented and show large changes in ocean–atmosphere coupling. In particular, local air-sea feedbacks are significantly modified by the increased ocean resolution. In the high-resolution simulation in the extra-tropics there is compelling evidence of stronger forcing of the atmosphere by SST variability arising from ocean dynamics. This coupling is very weak or absent in the low-resolution model.     

Detection of organic biomarkers in crude oils using ToF-SIMS

In this study, we show that time of flight-secondary ion mass spectrometry (ToF-SIMS) can be used to detect organic biomarkers, such as hopanes and steranes, in non-fractionated crude oils, without extraction and chemical preparation. Hopanes and steranes may provide valuable information on the history of life on early Earth, particularly if they are present in fluid inclusions in ancient rocks. Due to the presence of different generations of inclusions in even very small rock samples, it would be advantageous to find a method capable of detecting biomarkers in single oil rich fluid inclusions. The capability of ToF-SIMS for detailed chemical analysis of very small sample amounts makes it a potential technique for such analysis, and in this work this possibility is explored. The presence of hopanes and steranes in four different crude oils of different ages and stages of biodegradation was investigated using ToF-SIMS and GC–MS. By combining analyses of biomarker standards, crude oils and chromatographic oil fractions, specific peaks for the different biomarkers were identified in the ToF-SIMS spectra. The presence of these peaks in the spectra from the crude oil samples could be attributed to the biomarkers based on exact mass determination and by comparison with the spectra from the biomarker containing and biomarker lacking fractions, respectively. In addition, the results show that a significant biomarker signal may be obtained from a 10 μm² oil sample, demonstrating the potential of ToF-SIMS for analysis of single oil bearing fluid inclusions, which in turn may contribute to a better understanding of the early history of life on Earth.     

Observing the critical zone on a critical budget: The Peri Lake experimental catchment

The Peri Lake Experimental Catchment, in Southern Brazil, is a small coastal lake (5 km², 7 m depth) with a total catchment area of 20 km². The catchment is mainly covered by subtropical Atlantic Forest. Peri Lake is a recreational destination, an important ecosystem for biodiversity preservation, and a major water supply source. Even though there is a clear social and economic relevance, the information on this ecosystem is scarce, especially regarding the dynamics of water balance and water quality. We built this observatory using a low-cost, low-technology monitoring system to estimate the major components of the water budget on what we called a critical budget. We monitor meteorology, rainfall interception in two plots, overland flow and groundwater connectivity in a representative hillslope; and streamflow and velocity are measured in several small headwater rivers mostly starting during 2015. Geographic information on topography, land cover, geology, soil characteristics and the location of all the equipment installed in the field are also provided. The data set can be used to understand rainfall interception in Atlantic forests, catchment connectivity and streamflow permanence in coastal areas, spatial patterns of baseflow, and the modelling of complex processes in the critical zone involving the interaction between surface and groundwater, that are important in coastal lake ecosystems. Besides being used for research and education, we hope this observatory built on a shoestring budget will encourage fieldwork particularly in underrepresented and underfunded regions of the world.     

Feedback Mechanisms Between Cyanobacterial Blooms,Transient Hypoxia,and Benthic Phosphorus Regeneration in Shallow Coastal Environments

We investigated the dissolved oxygen metabolism of the Curonian Lagoon (Baltic Sea) to assess the relative contributions of pelagic and benthic processes to the development of transient hypoxic conditions in shallow water habitats. Metabolism measurements along with the remote sensing-derived estimates of spatial variability in chlorophyll a were used to evaluate the risk of hypoxia at the whole lagoon level. Our data demonstrate that cyanobacterial blooms strongly inhibit light penetration, resulting in net heterotrophic conditions in which pelagic oxygen demand exceeds benthic oxygen demand by an order of magnitude. The combination of bloom conditions and reduced vertical mixing during calm periods resulted in oxygen depletion of bottom waters and greater sediment nutrient release. The peak of reactive P regeneration (nearly 30 μmol m^?2 h^?1) coincided with oxygen depletion in the water column, and resulted in a marked drop of the inorganic N:P ratio (from >40 to <5, as molar). Our results suggest a strong link between cyanobacterial blooms, pelagic respiration, hypoxia, and P regeneration, which acts as a feedback in sustaining algal blooms through internal nutrient cycling. Meteorological data and satellite-derived maps of chlorophyll a were used to show that nearly 70 % of the lagoon surface (approximately 1,000 km²) is prone to transient hypoxia development when blooms coincide with low wind speed conditions.     

3s23p–3s3p2 transitions in S iv

We use both the civ3 and mchf codes to calculate oscillator strengths of allowed and intercombination lines in the  3s²3p–3s3p²  multiplets. Valence, core–valence and some core–core correlation effects are included. The two approaches give results in excellent agreement. Core effects are particularly important for the intercombination lines, though relatively minor for allowed transitions.
We obtain a branching ratio of 1.42 with an estimated accuracy of 0.02 for the     transitions, compared with an experimental value of  1.12±0.1  . The A -values of the     intercombination lines are substantially different from those of previous calculations.     

Estimation of baseflow residence times in watersheds from the runoff hydrograph recession: method and application in the Neversink watershed,Catskill Mountains,New York

A method for estimation of mean baseflow residence time in watersheds from hydrograph runoff recession characteristics was developed. Runoff recession characteristics were computed for the period 1993–96 in the 2 km² Winnisook watershed, Catskill Mountains, southeastern New York, and were used to derive mean values of subsurface hydraulic conductivity and the storage coefficient. These values were then used to estimate the mean baseflow residence time from an expression of the soil contact time, based on watershed soil and topographic characteristics. For comparison, mean baseflow residence times were calculated for the same period of time through the traditional convolution integral approach, which relates rainfall δ¹⁸O to δ¹⁸O values in streamflow. Our computed mean baseflow residence time was 9 months by both methods. These results indicate that baseflow residence time can be calculated accurately using recession analysis, and the method is less expensive than using environmental and/or artificial tracers. Published in 2002 by John Wiley & Sons, Ltd.     

Numerical Simulation of Groundwater Flow and Vulnerability in Wadi El-Natrun Depression and Vicinities,West Nile Delta,Egypt

During the last 25 years, rapid and unplanned land reclamation activity has been carried out in the areas located in both south and east of Wadi El - Natrun Depression of Egypt. Accordingly, negative effects on groundwater levels and vulnerability are frequently caused by localized high levels of abstraction and the return-flow of polluted irrigation water respectively. A groundwater model is a computational method that presents an approximation of an underground water system. In this study the groundwater system is simulated both in quantity and quality by using Mass Balance Transfer Model (NETPATH), Groundwater Modeling System (GMS) and DRASTIC Model to investigate the water - rock interactions, groundwater levels drawdown and vulnerability respectively. Three main geochemical processes namely dedolomitisation, dissolution of halite and silicate weathering were estimated during the flow path. The present over-abstraction of groundwater (105.84 million m³/year) has induced a general head drawdown from 3 to 40 m in years 2015 and 2050 respectively. Best estimate using a 3D GMS hydraulic model was (157000 m³/day) a strategy proposed for the management of groundwater without critical depletion (second scenario). The results document the extent to which a high drawdown can greatly reach 4 m by the end of simulation year 2050. The vulnerability maps of groundwater were constructed using the DRASTIC index method. The results indicated that, the southeastern and central portions of the study area are having high vulnerability rate (> 110). Modified DRASTIC map showed many more dominant high risk areas in the eastern parts of the study area that were low risk, which may be attributed to return flow of polluted irrigation water.     

Genetic seascape of the threatened Caribbean elkhorn coral,Acropora palmata,on the Puerto Rico Shelf

It has been proposed that the elkhorn coral Acropora palmata is genetically separated into two distinct provinces in the Caribbean, an eastern and a western population admixing in Western Puerto Rico and around the Mona Passage. In this study, the genetic structure of A. palmata sampled at 11 Puerto Rican localities and localities from Curaçao, the Bahamas and Guadeloupe were examined. Analyses using five microsatellite markers showed that 75% of sampled colonies had unique genotypes, the rest being clone mates. Genetic diversity among genets was high (H_E = 0.761) and consistent across localities (0.685–0.844). F_ST ranged from ?0.011 to 0.047, supporting low but significant genetic differentiation between localities within the previously reported eastern and western genetic provinces. Plots of genetic per geographic distances and significant Mantel tests supported isolation‐by‐distance (IBD) within Puerto Rico. Analysis with the software STRUCTURE favored a scenario with weak differentiation between two populations, assigning Eastern Puerto Rican locations (Fajardo and Culebra), Guadeloupe and Curaçao to the Caribbean eastern population and Western Puerto Rican locations (west of Vega Baja and Ponce), Mona and the Bahamas to the Caribbean western population. Vieques and San Juan area harbored admixed profiles. Standardized F_ST per 1000 km unit further supported higher differentiation between localities belonging to different STRUCTURE populations, with IBD being stronger within Puerto Rico than on larger regional scales. This stronger genetic transition seems to separate localities between putative eastern and western provinces in the Eastern Puerto Rican region, but not around the Mona Passage.