Clinoform geometry,geomorphology, facies character and stratigraphic architecture of a sand‐rich subaqueous delta: Jurassic Sognefjord Formation,offshore Norway

The integration of core sedimentology, seismic stratigraphy and seismic geomorphology has enabled interpretation of delta‐scale (i.e. tens of metres high) subaqueous clinoforms in the upper Jurassic Sognefjord Formation of the Troll Field. Mud‐prone subaqueous deltas characterized by a compound clinoform morphology and sandy delta‐scale subaqueous clinoforms are common in recent tide‐influenced, wave‐influenced and current‐influenced settings, but ancient examples are virtually unknown. The data presented help to fully comprehend the criteria for the recognition of other ancient delta‐scale subaqueous clinoforms, as well as refining the depositional model of the reservoir in the super‐giant Troll hydrocarbon field. Two 10 to 60 m thick, overall coarsening‐upward packages are distinguished in the lower Sognefjord Formation. Progressively higher energy, wave‐dominated or current‐dominated facies occur from the base to the top of each package. Each package corresponds to a set of seismically resolved, westerly dipping clinoforms, the bounding surfaces of which form the seismic ‘envelope’ of a clinoform set and the major marine flooding surfaces recognized in cores. The packages thicken westwards, until they reach a maximum where the clinoform ‘envelope’ rolls over to define a topset–foreset–toeset geometry. All clinoforms are consistently oriented sub‐parallel to the edge of the Horda Platform (N005–N030). In the eastern half of the field, individual foresets are relatively gently dipping (1° to 6°) and bound thin (10 to 30 m) clinothems. Core data indicate that these proximal clinothems are dominated by fine‐grained, hummocky cross‐stratified sandstones. Towards the west, clinoforms gradually become steeper (5° to 14°) and bound thicker (15 to 60 m) clinothems that comprise medium‐grained, cross‐bedded sandstones. Topsets are consistently well‐developed, except in the westernmost area. No seismic or sedimentological evidence of subaerial exposure is observed. Deposition created fully subaqueous, near‐linear clinoforms that prograded westwards across the Horda Platform. Subaqueous clinoforms were probably fed by a river outlet in the north‐east and sculpted by the action of currents sub‐parallel to the clinoform strike.     

Determination of the Jenkinson and Collison’s weather types for the western Mediterranean basin over the 1948-2009 period. Temporal analysis

We determined the weather type, according to the Jenkinson and Collison procedure, of the 22 646 days in the 1948-2009 period for the western Mediterranean basin. The analysis is based upon the surface pressure values of the NCEP/NCAR reanalysis, for a grid of nine points with extreme vertices at 45º N, 5º W and 35º N, 15º E, which provides a broad synoptic catalogue for this region. We analyzed the trends of the types and their different groupings during the same period. The most frequent type is U (undetermined), with an annual average of approximately 100 days (99.4, 27.2%), followed by type A (anticyclone), with 75.5 days/ year (20.7%), and C (depression), with 67.8 days/year (18.6%). The high frequency of type U is due to the habitual pressure of baric fields with a low gradient over Mediterranean waters in the warm half of the year. According to their directions, the types from the west are the most frequent and those from the south, the least. The monthly regime of the most frequent types and groupings is quite regular; type C groups, as well as advective and cyclonic curvature groups, present summertime minima and maxima in the cold half of the year, whereas the opposite occurs with types U and A. The main statistically significant annual trends in the 1948-2009 period involve a decrease in type A (–4.19 days/decade, that is, –29.0%) and an increase in type U, the cyclonic types and those presenting an easterly component. On comparing the 31-yr sub-periods 1948-1978 and 1979-2009, the tendencies of A and U were confirmed, and increases can generally be seen in the types presenting an easterly component and a decrease in those with a westerly component. The variation in type A ranged from 2490 days in the first sub-period to 2192 in the second one (p = 0.000), mainly concentrated in summer and autumn. This evident reduction of type A coincides, paradoxically, with an increase in the sea surface pressure variable (+0.31 hPa/decade) throughout the 62 years of analysis. The negative trend found in type A differs from the results of some studies. The different analysis periods, the different scales or areas of study and the variety of methods used to determine the weather types can account for the fact that these results are discordant. Moreover, warming over the last few decades in the waters of the western Mediterranean basin, as well as the clearly cyclogenetic character of the gulfs of Lion and Genoa, might account for the decrease in type A and the increase in the cyclonic curvature types.     

Palaeolithic and Quaternary research in the Trent Valley (UK): contributions by early collectors

A brief history is presented here of the activities of the three most notable collectors of Lower and Middle Palaeolithic artefacts from Quaternary river terrace deposits in the Trent Valley, derived from archival material that has been largely ignored by previous research. Two, Mr. Fred W.G. Davey and Mr. George F. Turton, were local amateur collectors who did not publish the results of their work themselves and were reliant on collaboration with established archaeologists. The third, Mr. A. Leslie Armstrong, was an archaeologist best known for his work at Creswell Crags and Grimes Graves. Armstrong also made many Palaeolithic discoveries in the Trent Valley but published few details of his own material. Although such details of early Palaeolithic research in the Midlands and North of Britain are predominantly of historical interest only, they nonetheless provide a number of insights into the apparent lack of interest shown in areas north of the ‘Severn-Wash Line’ by collectors of Palaeolithic artefacts. Importantly, the dataset assembled by the Trent Valley Palaeolithic Project (TVPP) and summarized here is the only complete record of the known artefacts and archival material from the Trent, a proportion of which is now unavailable to the research community, having entered unknown private ownership since being studied. The second part of the paper relates this early research to current knowledge of the British Palaeolithic at its most northern fringes and to recent developments in reconstructing the Quaternary evolution of the River Trent.     

Temporal trends in abundance of fish in the tidal Delaware River

Water quality in the tidal Delaware River has improved dramatically over the last several decades. Areas near Philadelphia that were once anoxic and formed a pollution block to migratory fish passage now rarely experience dissolved oxygen concentrations less than 3 ppm. To assess whether these improvements in water quality led to increased abundance of juvenile fishes, data from a beach seine survey conducted annually since 1980 were examined. The number of species captured increased throughout the tidal river, but the increase was greatest in the areas downstream of Philadelphia, wheare water quality has improved the most. Abundance of juvenile striped bass and American shad, two important game species in the river whose migratory patterns make them susceptible to water quality problems, both increased more than, 1,000-fold during the last decade. Correlatations between the temporal abundance patterns of these species in the tidal Delaware River and in other East Coast systems were poor, suggesting that increases in their numbers were related more closely to improving conditions within the Delaware than to factors affecting coastal stocks.     

Comparison of water-level,extensometric, DInSAR and simulation data for quantification of subsidence in Murcia City (SE Spain)

Subsidence due to groundwater overexploitation has been recognized in the metropolitan area of Murcia (25 km²) in south-eastern Spain since the early 1990s. Previous published works have focused their attention on land subsidence that occurred during the drought period between 1995 and 2008. This work first analyzes the groundwater recovery that has occurred since 2008 and then determines the kind of associated ground deformation detected by the new extensometric data. Subsequently, subsidence time series are computed on 24 geotechnical boreholes scattered throughout the study area by means of a hydro-mechanical finite element code and a linear-elastic constitutive law. A spatio-temporal interpolation of the numerically modeled surface displacements is performed over the whole domain and compared with extensometers and DInSAR-derived displacement maps in two different periods: the drought period from 2004 to 2008, and the recovery period from 2008 to 2012. In spite of the limited information on the geomechanical parameters characterizing the modelled geological formations, the proposed approach is able to discriminate areas where the soils have an elastic behavior (small differences in the comparisons) or an elasto-plastic behavior (large differences in the comparisons). This zonation enhances the understanding of the subsidence phenomenon in Murcia City and could prevent, from a quantitatively point of view, future severe subsidence due to aquifer overexploitation.     

Crustal contaminants in the Permian Oslo Rift, South Norway: constraints from Precambrian geochemistry

During the late Paleozoic Oslo rifting event, the SW part of the Baltic Shield was penetrated by mantle-derived magmas from a depleted lithospheric or sublithospheric source. Along the way to their final emplacement, these magmas may have interacted with a heterogeneous continental crust, consisting of a mosaic of continental terranes, each with its unique composition and internal crustal history. Information on radiogenic isotope ratios and trace element distributions in the Precambrian terranes surrounding the rift can be used to define characteristic crustal components. These components may be used as endmembers in petrogenetic modelling of the Oslo Rift magmatic system. Based on available data, six endmember components can be identified, and (semi) quantitatively characterized in terms of Sr, Nd and Pb isotopes and selected trace elements. Data on the distribution of rock-types along the rift flanks allow estimates to be made of the relative importance of the components in different parts of the rift. Combining these data with petrological information may allow a realistic understanding of crust–magma interaction in the Oslo Rift magmatic system.     

Lu–Hf and U–Pb isotope systematics of zircons from the Storgangen intrusion, Rogaland Intrusive Complex, SW Norway: implications for the composition and evolution of Precambrian lower crust in the Baltic Shield

The Storgangen orebody is a concordantly layered, sill-like body of ilmenite-rich norite, intruding anorthosites of the Rogaland Intrusive Complex (RIC), SW Norway. 17 zircon grains were separated from ca. 5 kg of sand-size flotation waste collected from the on-site repository from ilmenite mining. These zircons were analysed for major and trace elements by electron microprobe, and for U–Pb and Lu–Hf isotopes by laser ablation microprobe plasma source mass spectrometry. Eight of the zircons define a well-constrained (MSWD=0.37) concordant population with an age of 949±7 Ma, which is significantly older than the 920–930 Ma ages previously reported for zircon inclusions in orthopyroxene megacrysts from the RIC. The remaining zircons, interpreted as inherited grains, show a range of ²⁰⁷Pb/²⁰⁶Pb ages up to 1407±14 Ma, with an upper intercept age at ca. 1520 Ma. The concordant zircons have similar trace element patterns, and a mean initial Hf isotope composition of ¹⁷⁶Hf/¹⁷⁷Hf_{949 Ma}=0.28223±5 (_Hf=+2±2). This is similar to the Hf-isotope composition of zircons in a range of post-tectonic Sveconorwegian granites from South Norway, and slightly more radiogenic than expected for mid-Proterozoic juvenile crust. The older, inherited zircons show Lu–Hf crustal residence ages in the range 1.85–2.04 Ga. One (undated) zircon plots well within the field of Hf isotope evolution of Paleoproterozoic rocks of the Baltic Shield. These findings indicate the presence of Paleoproterozoic components in the deep crust of the Rogaland area, but do not demonstrate that such rocks, or a Sveconorwegian mantle-derived component, contributed significantly to the petrogenesis of the RIC. If the parent magma was derived from a homogeneous, lower crustal mafic granulite source, the lower crustal protolith must be at least 1.5 Ga old, and it must have an elevated Rb/Sr ratio. This component would be indistinguishable in Sr, Nd and Hf isotopes from some intermediate mixtures between Sveconorwegian mantle and Paleoprotoerzoic felsic crust, but it cannot account for the initial ¹⁴³Nd/¹⁴⁴Nd of the most primitive, late Sveconorwegian granite in the region, without the addition of mantle-derived material.     

Genesis and evolution of the lithospheric mantle beneath the Buffalo Head Terrane, Alberta (Canada)

Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m². The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth.

A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions.

Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic ¹⁸⁷Os/¹⁸⁸Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle.

A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions.

If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events.     

Soft X-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions

We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.