Partial melting of metagreywackes, Part II. Compositions of minerals and melts

A series of experiments on the fluid-absent melting of a quartz-rich aluminous metagreywacke has been carried out. In this paper, we report the chemical composition of the phases present in the experimental charges as determined by electron microprobe. This analytical work includes biotite, plagioclase, orthopyroxene, garnet, cordierite, hercynite, staurolite, gedrite, oxide, and glass, over the range 100–1000 MPa, 780–1025 °C. Biotites are Na- and Mg-rich, with Ti contents increasing with temperature. The compositions of plagioclase range from An₁₇ to An₃₅, with a significant orthoclase component, and are always different from the starting minerals. At high temperature, plagioclase crystals correspond to ternary feldspars with Or contents in the range 11–20 mol%. Garnets are almandine pyrope grossular spessartine solid solutions, with a regular and significant increase of the grossular content with pressure. All glasses are silicic (SiO₂ = 67.6–74.4 wt%), peraluminous, and leucocratic (FeO + MgO = 0.9–2.9 wt%), with a bulk composition close to that of peraluminous leucogranites, even for degrees of melting as high as 60 vol.%. With increasing pressure, SiO₂ contents decrease while K₂O increases. At any pressure, the melt compositions are more potassic than the water-saturated granitic minima. The H₂O contents estimated by mass balance are in the range 2.5–5.6 wt%. These values are higher than those predicted by thermodynamic models. Modal compositions were estimated by mass balance calculations and by image processing of the SEM photographs. The positions of the 20 to 70% isotects (curves of equal proportion of melt) have been located in the pressure-temperature space between 100 MPa and 1000 MPa. With increasing pressure, the isotects shift toward lower temperature between 100 and 200 MPa, then bend back toward higher temperature. The melting interval increases with pressure; the difference in temperature between the 20% and the 70% isotects is 40 °C at 100 MPa, and 150 °C at 800 MPa. The position of the isotects is interpreted in terms of both the solubility of water in the melt and the nature of the reactions involved in the melting process. A comparison with other partial melting experiments suggests that pelites are the most fertile source rocks above 800 MPa. The difference in fertility between pelites and greywackes decreases with decreasing pressure. A review of the glass compositions obtained in experimental studies demonstrates that partial melting of fertile rock types in the crust (greywackes, pelites, or orthogneisses) produces only peraluminous leucogranites. More mafic granitic compositions such as the various types of calk-alkaline rocks, or mafic S-type rocks, have never been obtained during partial melting experiments. Thus, only peraluminous leucogranites may correspond to liquids directly formed by partial melting of metasediments. Other types of granites involve other components or processes, such as restite unmixing from the source region, and/or interaction with mafic mantle-derived materials. Received: 11 July 1995 / Accepted: 27 February 1997     

Harmonic Analysis of Sedimentary Cyclic Sequences in Kansas, Midcontinent, USA

Several stratigraphic sequences in the Upper Carboniferous (Pennsylvanian) in Kansas (Midcontinent, USA) were analyzed quantitatively for periodic repetitions. The sequences were coded by lithologic type into strings of datasets. The strings then were analyzed by an adaptation of a one-dimensional Fourier transform analysis and examined for evidence of periodicity. The method was tested using different states in coding to determine the robustness of the method and data. The most persistent response is in multiples of 8–10 ft (2.5–3.0 m) and probably is dependent on the depositional thickness of the original lithologic units. Other cyclicities occurred in multiples of the basic frequency of 8–10 with persistent ones at 22 and 30 feet (6.5–9.0 m) and large ones at 80 and 160 feet (25–50 m). These levels of thickness relate well to the basic cyclothem and megacyclothem as measured on outcrop. We propose that this approach is a suitable one for analyzing cyclic events in the stratigraphic record.     

Research on Relationship Between Fluorine in Tap Water and That in Urine of Chinese Residents

In this study, the relationship between fluorine in drinking water and that in urine of urban residents in China is assessed. Fluorine concentrations in tap water and those in urine show a good correlation with a linear regression coefficient of 0. 9798, indicating that the fluorine concentrations in big cities under investigation are extremely low, and the main source of fluorine is tap water. The weather effect on the intake amount of fluorine is also discussed. When air temperature is above 15℃, people would intake more fluorine through drinking water with the rise of air temperature. When temperature is below 15℃, no remarkable relationship is observed between air temperature and the intake amount of fluorine. This phenomenon indicates that the main source of fluorine in China is tap water instead of foodstuff.     

Organic Petrological Studies on Immature Source Rocks

Organic petrology is a marginal science that is quite practicable. At present, it has developed into a routine research tool that is widely applied in petroleum exploration and assessment. Based on several years‘ research of the authors, this paper presents the advances in organic petrological studies on immature source rocks, including the classification and characteristics of macerals, the composition of macerals and types of organic matter, the abundance and evolution of organic matter, oil-prone macerals, hydrocarbon generation and expulsion. All these results show that organic petrology is of considerable value pertaining to its application in the assessment of immature oil and gas. The immature source rocks consist of various macerals with obvious heterogeneity, contain different hydrocarbon-generating macerals with different oil thresholds and oil peaks, and show a two-staged evolutionary pattern of organic matter.     

Migration Fractionation of Neutral Nitrogen Compounds of Crude Oils from Tabei Oilfield in the Tarim Basin, China

The absolute amounts and relative distributions of neutral nitrogen compounds in the Tabei oilfield (e. G. Blocks Ln1-Ln1 1) showed remarkable migration fractionation in the vertical direction. From Ordovician reservoirs (O) to oil legs TⅢ and T Ⅰ of Triassic reservoirs in blocks LN1-LN11, the concentrations of [a] [c] decreased from 1. 59μg/g, 0.49μg/g to 0.17 μg/g (oil). The ratios of various alkylcarbazole isomers, such as 1,8-dimethylcarbazole/nitrogenpartially shielded isomers and 1,8-dimethylcarbazole/nitrogen-exposed isomers, were adopted as the indicators of petroleum migration. The ratios increased from 0.13, 0.20 to 0.67 and from going from the south to the north of the Tabei oilfield, the absolute concentrations of neutral nitrogen compounds decreased drastically, and the nitrogen-shielded isomers were enriched relative to nitrogen-exposed isomers and nitrogen-partially shielded isomers. Crude oils in the Tabei oilfield migrated laterally from the Jilake structure to the Sangtamu fault uplift and Lunnan fault uplift, and crude oils in the same fault uplift migrated and remigrated vertically from Ordovician reservoirs, to oil legs TⅢ to TⅠ of Triassic reservoirs.     

Composition of Kerogen in Kupferschiefer from Southwest Poland

Thirty-seven Kupferschiefer samples from southwestern Poland were analyzed by microscopy, Rock-Eval approach and instrumental neutron activation analysis to understand the geochemical and morphological characteristics of kerogen present in the samples. The analytical results indicate that there are two different types of kerogens. One type was only subjected to thermal alteration processes, and the other was further oxidized after deposition of the sediment.In the oxidized samples migrabitumen was transformed into pyrobitumen. Rock-Eval analyses show a significant decrease in HI values in the oxidized samples and an increase in OI values in relation to the samples that were not influenced by oxidation. Variations in S2 versus Corg contents indicate a change in kerogen from Type II to Type III with progressing oxidation. The presence of pyrobitumen and the depletion of hydrogen in the altered kerogen allow one to conclude that the kerogen was used as hydrogen donor for thermochemical sulfate reduction(TSR).     

Isotopic Characteristics and Key Factors Favoring the Formation of Fuwan Super-large Silver Deposit in Guangdong Province

Rb-Sr isochron age of fluid inclusions in quartz from the Fuwan super-large silver deposit is 68 - 6 Ma, the silver deposit is characterized by high μ values (10.67 - 10.95 ), which are much higher than those of the ore-hosted Paleozoic strata and are close to those of ores hosted in the Proterozoic metamorphic basement in western Guangdong Province. Based on the Pb isotopic characteristics, coupled with much high background silver contents (200-1000ng/g) in the Proterozoic basement and relatively low silver contents in the Paleozoic strata in the region of the Sanshui Basin, it is concluded that the ore-forming material of the super-large silver deposit came mainly from the old basement. The super-large silver deposit related genetically to the intense volcanic activities during the Upper Cretaceous to Eogene. The formation of the Fuwan super-large silver deposit is controlled by the following favorable geological conditions : ( 1 ) The intersection of deep faults and contemporaneous faults at the margin of the Sanshui Basin led to the formation of an excellent structure as passageway for ore fluids; (2) The special ore-hosted rock association forms a ore gathering-trap structure that favors the precipitation of ore; (3) The silver-rich old basement, multi-stage mineralization and multi-episode volcanic activities which constitute a geothermal convection system.     

Biomarkers in the Molar Tooth （MT）-Bearing Limestones in the Jilin-Liaoning Area of China

The origin of Molar Tooth (MT) carbonates has been argued for more than 100 years, which are a kind of Proterozoic carbonates especially composed of microsparite with ptygmatically folded and sheet-like structures. Biomarkers detected in the microcalcsparite from the Wanlong and Xingmincun formations in the Jilin-Liaoning area showed there are abundant normal alkanes, isoprenoids, hopanes, steranes, alkylmethylcyclohexanes, and alkyleyclohexanes, indicating a diversity of biological source: long-chain isoprenoids, the major components of chlorophyll, such as C19, C20, a kind of major biomarkers synthesized early by isoprenoid monomers; hopanes a type of characteristic biomarkers from prokaryote, such as archaebacteria and cyanobacteria; sterane a biomarker for eukaryote; and two kinds of alkanes with C17, C18 as the main peaks representing aquatic bacteria and with C23, C24 as the main peaks representing fungi, respectively. Biomarker analysis showed that MT is the result of bacterial and algal activities, which is a kind of organisms between aerobic and anaerobic bacteria, reproducing well in normal or slightly saline sea water under weak oxidation-reduction conditions, resulting in rapid deposition of calcite as microsparite clue to some mechanisms.