Late Pleistocene snowline fluctuations at Nevado Coropuna (15°S), southern Peruvian Andes

Deposits preserved on peaks in the southern Peruvian Andes are evidence for past glacial fluctuations and, therefore, serve as a record of both the timing and magnitude of past climate change. Moraines corresponding to the last major expansion of ice on Nevado Coropuna date to 20‐25 ka, during the last glacial maximum. We reconstructed the snowline at Coropuna for this period using a combined geomorphic‐numeric approach to provide a first‐order estimate of the magnitude of late‐Pleistocene climate change. Our reconstructions show that snowline was approximately 550‐770 m lower during the last glacial maximum than during the late Holocene maximum, which ended in the 19^th century, and ～750 m lower than today. While these values are similar to data from nearby Nevado Solimana, reconstructions from the neighbouring peak of Nevado Firura reveal a smaller snowline depression, suggesting the glacial response to climate forcing in the tropics is strongly influenced by non‐climatic factors. These data constitute some of the first directly dated palaeo‐snowline data from the arid tropics and suggest that the magnitude of the last glaciation in at least parts of the tropical Andes was similar to late‐Pleistocene events at higher latitudes. Copyright © 2011 John Wiley & Sons, Ltd.     

A simple concept for calibrating runoff thresholds in quasi‐distributed variable source area watershed models

Most semi‐distributed watershed water quality models divide the watershed into hydrologic response units (HRU) with no flow among them. This is problematic when watersheds are delineated to include variable source areas (VSAs) because it is the lateral flows from upslope areas to downslope areas that generate VSAs. Although hydrologic modellers have often successfully calibrated these types of models, there can still be considerable uncertainty in model results. In this paper, a topographic‐index‐based method is described and tested to distribute effective soil water holding capacity among HRUs, which can be subsequently adjusted using the watershed baseflow coefficient. The method is tested using a version of the Soil and Water Assessment Tool (SWAT) model that simulates VSA runoff and is applied to two watersheds: a New York State (NYS) watershed, and one in the head waters of the Blue Nile Basin (BNB) in Ethiopia. Daily streamflow predicted using effective soil water storage capacities based only on the topographic index were reassuringly accurate in both the NYS watershed (daily Nash Sutcliffe (E) = 0·73) and in the BNB (E = 0·70). Using the baseflow coefficient to adjust the effective soil water storage capacity only slightly improved streamflow predictions in NYS (E = 0·75) but substantially improved the BNB predictions (E = 0·80). By comparison, the standard SWAT model, which uses the traditional look‐up tables to determine a runoff curve number, performed considerably less accurately in un‐calibrated form (E = 0·51 for NYS and E = 0·45 for BNB), but improved substantially when explicitly calibrated to streamflow measurements (E = 0·76 for NYS and E = 0·67 for the BNB). The calibration method presented here provides a parsimonious, systematic approach to using established models in VSA watersheds that reduces the ambiguity inherent in model calibration. Copyright © 2011 John Wiley & Sons, Ltd.     

Relative timing of last glacial maximum and late-glacial events in the central tropical Andes

Whether or not tropical climate fluctuated in synchrony with global events during the Late Pleistocene is a key problem in climate research. However, the timing of past climate changes in the tropics remains controversial, with a number of recent studies reporting that tropical ice age climate is out of phase with global events. Here, we present geomorphic evidence and an in-situ cosmogenic ³He surface-exposure chronology from Nevado Coropuna, southern Peru, showing that glaciers underwent at least two significant advances during the Late Pleistocene prior to Holocene warming. Comparison of our glacial-geomorphic map at Nevado Coropuna to mid-latitude reconstructions yields a striking similarity between Last Glacial Maximum (LGM) and Late-Glacial sequences in tropical and temperate regions.Exposure ages constraining the maximum and end of the older advance at Nevado Coropuna range between 24.5 and 25.3 ka, and between 16.7 and 21.1 ka, respectively, depending on the cosmogenic production rate scaling model used. Similarly, the mean age of the younger event ranges from 10 to 13 ka. This implies that (1) the LGM and the onset of deglaciation in southern Peru occurred no earlier than at higher latitudes and (2) that a significant Late-Glacial event occurred, most likely prior to the Holocene, coherent with the glacial record from mid and high latitudes. The time elapsed between the end of the LGM and the Late-Glacial event at Nevado Coropuna is independent of scaling model and matches the period between the LGM termination and Late-Glacial reversal in classic mid-latitude records, suggesting that these events in both tropical and temperate regions were in phase.     

MATLAB Algorithm Availability Simulation Tool

This paper describes a set of MATLAB functions currently being developed for Space Based Augmentation System (SBAS) availability analysis. This toolset includes simulation algorithms that are constantly being developed and updated by various working groups. This set of functions is intended for use as a fast, accurate, and highly customizable experimental test bed for algorithm development. A user-friendly interface has also been developed for the tool. It is open source and can be downloaded from the Stanford GPS Research Laboratory web site (). Therefore, it provides a common ground for different working groups to compare their results. This paper demonstrates the utility of this toolset by analyzing the SBAS service volume models for the Conterminous United States. The paper describes the functionality provided within the software, and shows an example set of contour plots which are the means for investigating how different algorithms and parameters impact availability.     

A composite spessartite–appinite intrusion from Port-na-Blagh,County Donegal,Ireland

A sheet-like appinite from Breaghy Head, North Donegal, is closely associated with a spessartite intrusion. Field, mineralogical, and geochemical similarities indicate that the parent magmas were very similar, and the appinite magma may have been derived from the spessartite by small degrees of crystal fractionation. The appinite is divided into an amphibole-rich lower part and a felsic upper part; the mineralogical contrast between the two is best explained by two-pulse intrusion of a batch of spessartitic magma within which amphibole and pyroxene had already segregated due to crystal settling or flow sorting. Unlike other Caledonian appinites, the Breaghy Head intrusion is not one of a cluster, and appears to be an isolated development. Possible reasons for its location are discussed.     

Small Purge Method to Sample Vapor from Groundwater Monitoring Wells Screened Across the Water Table

Groundwater monitoring wells are present at most hydrocarbon release sites that are being assessed for cleanup. If screened across the vadose zone, these wells provide an opportunity to collect vapor samples that can be used in the evaluation of vapor movement and biodegradation processes occurring at such sites. This paper presents a low purge volume method (modified after that developed by the U.S. EPA) for sampling vapor from monitoring wells that is easy to implement and can provide an assessment of the soil gas total petroleum hydrocarbon (TPH) and O₂ concentrations at the base of the vadose zone. As a result, the small purge method allows for sampling of vapor from monitoring wells to support petroleum vapor intrusion (PVI) risk assessment. The small purge volume method was field tested at the Hal's service station site in Green River, Utah. This site is well‐known for numerous soil gas measurements containing high O₂ and high TPH vapor concentrations in the same samples which is inconsistent with well‐accepted biodegradation models for the vapor pathway. Using the low purge volume method, monitoring wells were sampled over, upgradient, and downgradient of the light nonaqueous phase liquid (LNAPL) footprint. Results from our testing at Hal's show that vapor from monitoring wells over LNAPL contained very low O₂ and high TPH concentrations. In contrast, vapor from monitoring wells not over LNAPL contained high O₂ and low TPH concentrations. The results of this study show that a low purge volume method is consistent with biodegradation models especially for sampling at sites where low permeability soils exist in and around a LNAPL source zone.     

Impacts of a Rural Subdivision on Groundwater Quality: Results of Long-Term Monitoring

A rural subdivision in south central Wisconsin was instrumented with monitoring wells and lysimeters before, during, and after its construction to examine the impacts of the unsewered subdivision on groundwater quality and quantity. Prior to construction, the 78-acre (32 ha) site was farmland. Sixteen homes were constructed beginning in 2003. Initial monitoring from 2002 to 2005 showed that groundwater beneath the site had been impacted by previous agricultural use, with nitrate-N values as high as 30 mg/L and some detections of the herbicide atrazine. Our 12-year study shows that the transition from agricultural to residential land use has changed groundwater quality in both negative and positive ways. Although groundwater elevations showed typical seasonal fluctuations each year, there were no measurable changes in groundwater levels or general flow directions during the 12-year study period. Chloride values increased in many wells, possibly as a result of road salting or water softener discharge. Nitrate concentrations varied spatially and temporally over the study period, with some initial concentrations substantially above the drinking water standard. In some wells, nitrate and atrazine levels have declined substantially since agriculture ceased. However, atrazine was still present at trace concentrations throughout the site in 2014. Wastewater tracers show there are small but detectable impacts from septic effluent on groundwater quality. Particle traces based on a groundwater flow model are consistent with the hypothesis that septic leachate has impacted groundwater quality.     

An Instrument for the Determination of a Hydropneumograph in a Bubbling Spring

In order to enable greater accuracy in the determination of the mass discharge of gas and water-gas ratios (WGR) in groundwater from springs, we have developed a field-deployable instrument using commercially available components to independently measure the gas and water mass flow rates in springs with bubbling mixed-phase flow. Collecting and measuring the free gas phase will allow for further compositional analysis that may be useful in improving gas-derived parameters such as recharge temperature and age, as well as quantification of methanogenesis and flux of crustal/mantle gasses. By installing a phase separator at the spring discharge, a thermal mass flow sensor is utilized to measure the gas flow rate (ebullition + flux) generated from a spring. The water flow rate is determined by a standard weir. Field performance of the device was tested on a spring discharging from the Arbuckle-Simpson aquifer near the town of Connerville in south-central Oklahoma, USA.     

Distributions for storm surge extremes

The present paper is an attempt to assess a variety of potential probabilistic models for the meteorologically driven storm surge component of a long term water level observation record at Sandy Hook, New Jersey. Simple assumptions are made with regard to the record, and the fitting of the extreme values of the data are assessed graphically in observation space for determining quality of fit in the upper tail of the data. Results are presented which show a comparison of typical distributions utilized along with some distributions not before utilized for coastal storm surge.     

Optical off-nuclear spectra of quasar hosts and radio galaxies

We present optical (∼3200 to ∼9000 Å) off-nuclear spectra of 26 powerful active galaxies in the redshift range 0.1≤ z ≤0.3, obtained with the Mayall and William Herschel 4-m class telescopes. The sample consists of radio-quiet quasars, radio-loud quasars (all with −23≥ M _V ≥−26) and radio galaxies of Fanaroff–Riley Type II (with extended radio luminosities and spectral indices comparable to those of the radio-loud quasars). The spectra were all taken approximately 5 arcsec off-nucleus, with offsets carefully selected so as to maximize the amount of galaxy light falling into the slit, whilst simultaneously minimizing the amount of scattered nuclear light. The majority of the resulting spectra appear to be dominated by the integrated stellar continuum of the underlying galaxies rather than by light from the non-stellar processes occurring in the active nuclei, and in many cases a 4000-Å break feature can be identified. The individual spectra are described in detail, and the importance of the various spectral components is discussed. Stellar population synthesis modelling of the spectra will follow in a subsequent paper.