Iron isotopes constrain biologic and abiologic processes in banded iron formation genesis

The voluminous 2.5 Ga banded iron formations (BIFs) from the Hamersley Basin (Australia) and Transvaal Craton (South Africa) record an extensive period of Fe redox cycling. The major Fe-bearing minerals in the Hamersley-Transvaal BIFs, magnetite and siderite, did not form in Fe isotope equilibrium, but instead reflect distinct formation pathways. The near-zero average δ⁵⁶Fe values for magnetite record a strong inheritance from Fe³⁺ oxide/hydroxide precursors that formed in the upper water column through complete or near-complete oxidation. Transformation of the Fe³⁺ oxide/hydroxide precursors to magnetite occurred through several diagenetic processes that produced a range of δ⁵⁶Fe values: (1) addition of marine hydrothermal , (2) complete reduction by bacterial dissimilatory iron reduction (DIR), and (3) interaction with excess that had low δ⁵⁶Fe values and was produced by DIR. Most siderite has slightly negative δ⁵⁶Fe values of ∼ −0.5‰ that indicate equilibrium with Late Archean seawater, although some very negative δ⁵⁶Fe values may record DIR. Support for an important role of DIR in siderite formation in BIFs comes from previously published C isotope data on siderite, which may be explained as a mixture of C from bacterial and seawater sources.Several factors likely contributed to the important role that DIR played in BIF formation, including high rates of ferric oxide/hydroxide formation in the upper water column, delivery of organic carbon produced by photosynthesis, and low clastic input. We infer that DIR-driven Fe redox cycling was much more important at this time than in modern marine systems. The low pyrite contents of magnetite- and siderite-facies BIFs suggests that bacterial sulfate reduction was minor, at least in the environments of BIF formation, and the absence of sulfide was important in preserving magnetite and siderite in the BIFs, minerals that are poorly preserved in the modern marine record. The paucity of negative δ⁵⁶Fe values in older (Early Archean) and younger (Early Proterozoic) BIFs suggests that the extensive 2.5 Ga Hamersley-Transvaal BIFs may record a period of maximum expansion of DIR in Earth’s history.     

Observations with the Visual and Infrared Mapping Spectrometer (VIMS) during Cassini's flyby of Jupiter

The Cassini Visual and Infrared Mapping Spectrometer (VIMS) is an imaging spectrometer covering the wavelength range 0.3-5.2 μm in 352 spectral channels, with a nominal instantaneous field of view of 0.5 mrad. The Cassini flyby of Jupiter represented a unique opportunity to accomplish two important goals: scientific observations of the jovian system and functional tests of the VIMS instrument under conditions similar to those expected to obtain during Cassini's 4-year tour of the saturnian system. Results acquired over a complete range of visual to near-infrared wavelengths from 0.3 to 5.2 μm are presented. First detections include methane fluorescence on Jupiter, a surprisingly high opposition surge on Europa, the first visual-near-IR spectra of Himalia and Jupiter's optically-thin ring system, and the first near-infrared observations of the rings over an extensive range of phase angles (0-120°). Similarities in the center-to-limb profiles of H⁺₃ and CH₄ emissions indicate that the H⁺₃ ionospheric density is solar-controlled outside of the auroral regions. The existence of jovian NH₃ absorption at 0.93 μm is confirmed. Himalia has a slightly reddish spectrum, an apparent absorption near 3 μm, and a geometric albedo of 0.06±0.01 at 2.2 μm (assuming an 85-km radius). If the 3-μm feature in Himalia's spectrum is eventually confirmed, it would be suggestive of the presence of water in some form, either free, bound, or incorporated in layer-lattice silicates. Finally, a mean ring-particle radius of 10 μm is found to be consistent with Mie-scattering models fit to VIMS near-infrared observations acquired over 0-120° phase angle.     

Predicted relative sea-level changes (18,000 years B.P. to present) caused by late-glacial retreat of the Antarctic Ice Sheet

Predictions of global changes in relative sea level caused by retreat of the Antarctic Ice Sheet from its 18,000 yr B.P. maximum to its present size are calculated numerically. When combined with the global predictions of relative sea-level change resulting from retreat of the Northern Hemisphere ice sheets, the results may be compared directly to observations of sea-level change on the Antarctic continent as well as at distant localities. The comparison of predictions to the few observations of sea-level change on Antarctica supports the view that the Antarctic Ice Sheet was larger 18,000 years ago than at present. The contribution of the Antarctic Ice Sheet to the total eustatic sea-level rise is assumed to be 25 m (25% of the assumed total eustatic rise). If as little as 0.7 m of this 25-m rise occurred between 5000 yr B.P. and the present, few mid-oceanic islands would emerge. If the Antarctic Ice Sheet attained its present dimensions by 6000 yr B.P., however, and if the volume of the ocean has remained constant for the past 5000 years, numerous islands throughout the Southern Hemisphere would emerge. It is suggested that a thorough study of Pacific islands, believed by some to have slightly emerged shorelines of Holocene age, would yield useful information about ocean volume changes during the past 5000 years, and hence on the glacial history of the Antarctic Ice Sheet.     

Behaviour of quartz gravity meters under high frequency vertical motion

Summary Tests on the vertical vibrating table in the frequency range of70–110 Hz indicate that quartz gravity meters are10–100 times more sensitive at some frequencies than under low-frequency excitation. At high frequencies, the reading beam is at rest and deflected from the correct position. Slow fluctuations of amplitude and frequency near resonance could cause slow irregular motion of the beam with absence of low-frequency ground motion of sufficient intensity.

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unmauaum a mua um¶rt; ¶rt;uana amm 70–110u mam, m a m ammaaum 10–100 a mum nu uamm au. u amm au u a¶rt;um n m mu m nu. ¶rt; auauu anum¶rt; u amm au uu aa m am uamm u ua ¶rt;a mmmm uamm au n ¶rt;mam umumu.

     

Strong variation in weathering of layered rock maintains hillslope‐scale strength under high precipitation

The evolution of volcanic landscapes and their landslide potential are both dependent upon the weathering of layered volcanic rock sequences. We characterize critical zone structure using shallow seismic V_p and V_s profiles and vertical exposures of rock across a basaltic climosequence on Kohala peninsula, Hawai’i, and exploit the dramatic gradient in mean annual precipitation (MAP) across the peninsula as a proxy for weathering intensity. Seismic velocity increases rapidly with depth and the velocity–depth gradient is uniform across three sites with 500–600 mm/yr MAP, where the transition to unaltered bedrock occurs at a depth of 4 to 10 m. In contrast, velocity increases with depth less rapidly at wetter sites, but this gradient remains constant across increasing MAP from 1000 to 3000 mm/yr and the transition to unaltered bedrock is near the maximum depth of investigation (15–25 m). In detail, the profiles of seismic velocity and of weathering at wet sites are nowhere monotonic functions of depth. The uniform average velocity gradient and the greater depths of low velocities may be explained by the averaging of velocities over intercalated highly weathered sites with less weathered layers at sites where MAP > 1000 mm/yr. Hence, the main effect of climate is not the progressive deepening of a near‐surface altered layer, but rather the rapid weathering of high permeability zones within rock subjected to precipitation greater than ~1000 mm/yr. Although weathering suggests mechanical weakening, the nearly horizontal orientation of alternating weathered and unweathered horizons with respect to topography also plays a role in the slope stability of these heterogeneous rock masses. We speculate that where steep, rapidly evolving hillslopes exist, the sub‐horizontal orientation of weak/strong horizons allows such sites to remain nearly as strong as their less weathered counterparts at drier sites, as is exemplified by the 50°–60° slopes maintained in the amphitheater canyons on the northwest flank of the island. Copyright © 2017 John Wiley & Sons, Ltd.     

Three-dimensional simulations of air flow and momentum transfer in partially harvested forests

In order to predict wind loading on trees (canopy height h) in partially harvested forests, it is necessary to characterize air flow and momentum transfer in progressively more complex patterns where groups of trees (or aggregates) are retained. In this study, we used large-eddy simulation to explore the effects of aggregate size, inter-aggregate spacing, and the ratio between the aggregate size and inter-aggregate spacing on air flow and momentum transfer. Forty-five grid points across an aggregate were needed to achieve an adequate level of turbulence. Using grid sizes of h/15 throughout was too viscous for the smaller aggregates. Vertical and horizontal flow deflection by the leading aggregates sheltered some of the downstream aggregates to varying degrees where turbulence increased for subsequent rows. The number of rows of protected aggregates decreased as aggregate dimensions and the space between aggregates increased. A theoretical treatment of time-dependent wind is presented for the lead aggregate and a simulation case is presented for the case of a gust of reduced wind passing through the aggregate pattern. The leading aggregate responded with decreasing moment for decreasing ambient wind speed as predicted by theory. However, downwind aggregates experienced substantial increases in bending moment. The overall results of the disruptive aspects of time dependence agrees with arguments regarding the role of irrotational (potential) flow to this problem. Our treatment of retention pattern design is only a first step and further research suggestions are presented.     

http://www.sciencedirect.com/science/article/pii/S1674987114001601

Data from a migmatised metapelite raft enclosed within charnockite provide quantitative constraints on the pressure-temperature-time[P-T-t) evolution of the Nagercoil Block at the southernmost tip of peninsular India.An inferred peak metamorphic assemblage of garnet,K-feldspar.sillimanite,plagioclase,magnetite,ilmenite,spinel and melt is consistent with peak metamorphic pressures of 6-8 kbar and temperatures in excess of 900℃.Subsequent growth of cordierite and biotite record high-temperature retrograde decompression to around 5 kbar and 800 C.SHRIMP U-Pb dating of magmatic zircon cores suggests that the sedimentary protoliths were in part derived from felsic igneous rocks with Palaeoproterozoic crystallisation ages.New growth of metamorphic zircon on the rims of detrital grains constrains the onset of melt crystallisation,and the minimum age of the metamorphic peak,to around560 Ma.The data suggest two stages of monazite growth.The first generation of REE-enriched monazite grew during partial melting along the prograde path at around 570 Ma via the incongruent breakdown of apatite.Relatively REE-depleted rims,which have a pronounced negative europium anomaly,grew during melt crystallisation along the retrograde path at around 535 Ma.Our data show the rocks remained at suprasolidus temperatures for at least 35 million years and probably much longer,supporting a long-lived high-grade metamorphic history.The metamorphic conditions,timing and duration of the implied clockwise P-T-t path are similar to that previously established for other regions in peninsular India during the Ediacaran to Cambrian assembly of that part of the Gondwanan supercontinent.     

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.     

X-ray absorption contrast images of binary chemical reactions

Low-divergence synchrotron-sourced X-rays enable a radiographic imaging scheme for full characterization of binary chemical reactions and characterization by type of more complex reactions, in situ, in diamond anvil cells (DAC). Spatially resolved reactants are induced to react by laser heating of their interface. The spatially intermediate products are observed through X-ray absorption contrast. Limits to the technique include the ability to maintain controlled experiment geometry during compression and the ability to resolve chemical differences between reactants and products by X-ray absorption. The ability to make in situ observations at experimental pressure and temperature obviates the problem with quenching techniques for capturing liquid compositions in experiments with dimensions smaller than the diffusion length during quenching time. Partially molten Fe-alloy systems, of poor quenchability, are examined at DAC pressures and temperatures for relevance to Earth's core constitution and evolution. Determinations of eutectic melting in Fe–FeS match known results. Of the probable light elements that may alloy with Fe in the Earth's liquid outer core, Fe–FeS experiments show only modest quenching problems, but C and Si alloy experiments are highly vulnerable to quenching artifacts. The observed reactivity of FeS, Fe₃C, FeSi, and FeO(OH) with Fe in DAC makes the observed non-reactivity between Fe and FeO more significant, reducing the probability that oxygen alone is the major alloy in Earth's molten outer core.     

High-Resolution Forecast Models of Water Vapor Over Mountains: Comparison With MERIS and Meteosat Data

Propagation delay due to variable tropospheric water vapor (WV) is one of the most intractable problems for radar interferometry, particularly over mountains. The WV field can be simulated by an atmospheric model, and the difference between the two fields is used to correct the radar interferogram. Here, we report our use of the U.K. Met Office Unified Model in a nested mode to produce high-resolution forecast fields for the 3-km-high Mount Etna volcano. The simulated precipitable-water field is validated against that retrieved from the Medium-Resolution Imaging Spectrometer (MERIS) radiometer on the Envisat satellite, which has a resolution of 300 m. Two case studies, one from winter (November 24, 2004) and one from summer (June 25, 2005), show that the mismatch between the model and the MERIS fields ( rms = 1.1 and 1.6 mm, respectively) is small. One of the main potential sources of error in the models is the timing of the WV field simulation. We show that long-wavelength upper tropospheric troughs of low WV could be identified in both the model output and Meteosat WV imagery for the November 24, 2004 case and used to choose the best time of model output.