Decoding the complex internal chemical structure of garnet porphyroblasts from the Zermatt area,Western Alps

Garnet is a prototypical mineral in metamorphic rocks because it commonly preserves chemical and textural features that can be used for untangling its metamorphic development. Large garnet porphyroblasts may show extremely complex internal structures as a result of a polycyclic growth history, deformation, and modification of growth structures by intra‐ and intercrystalline diffusion. The complex internal structure of garnet porphyroblasts from garnet–phengite schists (GPS) of the Zermatt area (Western Alps) has been successfully decoded. The centimetre‐sized garnet porphyroblasts are composed of granulite facies garnet fragments overgrown by a younger generation of grossular‐rich eclogite facies garnet. The early granulite facies garnet (G‐Grt) formed from low‐P, high‐T metamorphism during a pre‐Alpine orogenic event. The late garnet (E‐Grt) is typical of high‐pressure, low‐temperature (HPLT) metamorphism and can be related to Alpine subduction of the schists. Thus, the garnet of the GPS are polycyclic (polymetamorphic). G‐Grt formation occurred at ~670 MPa and 780°C, E‐Grt formed at ~1.7 GPa and 530°C. The G‐Grt is relatively rich in Prp and poor in Grs, while E‐Grt is rich in Grs and poor in Prp. The Alm content (mol.%) of G‐Grt is 68 of E‐Grt 55. After formation of E‐Grt between and around fragmented G‐Grt at 530°C, the GPS have been further subducted and reached a maximum temperature of 580°C before exhumation started. Garnet composition profiles indicate that the initially very sharp contacts between the granulite facies fragments of G‐Grt and fracture seals of HPLT garnet (E‐Grt) have been modified by cation diffusion. The profiles suggest that Ca did not exchange at the scale of 1 µm, whereas Fe and Mg did efficiently diffuse at the derived maximum temperature of 580°C for the GPS at the scale of 7–8 µm. The Grt–Grt diffusion profiles resulted from spending c. 10 Ma at 530–580°C along the P–T–t path. The measured Grt composition profiles are consistent with diffusivities of log D_MgFe = ?25.8 m²/s from modelled diffusion profiles. Mg loss by diffusion from G‐Grt is compensated by Fe gain by diffusion from E‐Grt to maintain charge balance. This leads to a distinctive Fe concentration profile typical of uphill diffusion.     

New VLBI2010 scheduling strategies and implications on the terrestrial reference frames

In connection with the work for the next generation VLBI2010 Global Observing System (VGOS) of the International VLBI Service for Geodesy and Astrometry, a new scheduling package (Vie_Sched) has been developed at the Vienna University of Technology as a part of the Vienna VLBI Software. In addition to the classical station-based approach it is equipped with a new scheduling strategy based on the radio sources to be observed. We introduce different configurations of source-based scheduling options and investigate the implications on present and future VLBI2010 geodetic schedules. By comparison to existing VLBI schedules of the continuous campaign CONT11, we find that the source-based approach with two sources has a performance similar to the station-based approach in terms of number of observations, sky coverage, and geodetic parameters. For an artificial 16 station VLBI2010 network, the source-based approach with four sources provides an improved distribution of source observations on the celestial sphere. Monte Carlo simulations yield slightly better repeatabilities of station coordinates with the source-based approach with two sources or four sources than the classical strategy. The new VLBI scheduling software with its alternative scheduling strategy offers a promising option with respect to applications of the VGOS.     

Earthquakes in Switzerland and surrounding regions during 2012

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2012. During this period, 497 earthquakes and 88 quarry blasts were detected and located in the region under consideration. With a total of only 13 events with M_L ≥ 2.5, the seismic activity in the year 2012 was far below the average over the previous 37 years. Most noteworthy were the earthquake sequence of Filisur (GR) in January with two events of M_L 3.3 and 3.5, the M_L 4.2 and M_L 3.5 earthquakes at a depth of 32 km below Zug in February and the M_L 3.6 event near Vallorcine in October. The epicentral intensity of the M_L 4.2 event close to Zug was IV, with a maximum intensity of V reached in a few areas, probably due to site amplification effects.     

Geochemical and isotopic evidence for seawater contamination of the hydrothermal system of Taal Volcano, Luzon, the Philippines

 The hydrologic structure of Taal Volcano has favored development of an extensive hydrothermal system whose prominent feature is the acidic Main Crater Lake (pH<3) lying in the center of an active vent complex, which is surrounded by a slightly alkaline caldera lake (Lake Taal). This peculiar situation makes Taal prone to frequent, and sometimes catastrophic, hydrovolcanic eruptions. Fumaroles, hot springs, and lake waters were sampled in 1991, 1992, and 1995 in order to develop a geochemical model for the hydrothermal system. The low-temperature fumarole compositions indicate strong interaction of magmatic vapors with the hydrothermal system under relatively oxidizing conditions. The thermal waters consist of highly, moderately, and weakly mineralized solutions, but none of them corresponds to either water–rock equilibrium or rock dissolution. The concentrated discharges have high Na contents (>3500 mg/kg) and low SO₄/Cl ratios (<0.3). The Br/Cl ratio of most samples suggests incorporation of seawater into the hydrothermal system. Water and dissolved sulfate isotopic compositions reveal that the Main Crater Lake and spring discharges are derived from a deep parent fluid (T≈300  °C), which is a mixture of seawater, volcanic water, and Lake Taal water. The volcanic end member is probably produced in the magmatic-hydrothermal environment during absorption of high-temperature gases into groundwater. Boiling and mixing of the parent water give rise to the range of chemical and isotopic characteristics observed in the thermal discharges. Incursion of seawater from the coastal region to the central part of the volcano is supported by the low water levels of the lakes and by the fact that Lake Taal was directly connected to the China sea until the sixteenth century. The depth to the seawater-meteoric water interface is calculated to be 80 and 160 m for the Main Crater Lake and Lake Taal, respectively. Additional data are required to infer the hydrologic structure of Taal. Geochemical surveillance of the Main Crater Lake using the SO₄/Cl, Na/K, or Mg/Cl ratio cannot be applied straightforwardly due to the presence of seawater in the hydrothermal system. Received: 12 February 1997 / Accepted: 26 January 1998     

Active width of gravel‐bed braided rivers

Previous analyses have identified the active width of braided rivers, the bed area over which bed load flux and short‐term morphological change occurs, as an important element of braiding dynamics and predictions of bed load flux. Here we compare theoretical predictions of active width in gravel‐bed braided rivers with observations from Sunwapta River, and from a generic physical model of gravel braided rivers, to provide general observations of the variation in active width, and to develop an understanding of the causes of variation. Bed topography was surveyed daily along a 150 m reach of the pro‐glacial Sunwapta River for a total of four weeks during summer when flow was above threshold for morphological activity. In the laboratory, detailed digital elevation models (DEMs) were derived from photogrammetric survey at regular intervals during a constant discharge run. From the field and flume observations there is considerable local and circumstantial variation in active width, but also a general trend in average active width with increasing discharge. There is also a clear relationship of active width with active braiding index (number of active branches in the braided channel network), and with dimensionless stream power, which appears to be consistent across the range of data from field and physical models. Thus there is a link between active width and the river morphology and dynamics, and the possibility of a general relationship for estimating active width from channel pattern properties or reach‐scale stream power values, from which approximate bedload flux calculations may be made. The analysis also raises questions about differences between hydraulically‐based numerical model computations of instantaneous active width and observation of time‐integrated morphological active width. Understanding these differences can give insight into the nature of bedload transport in braided rivers and the relationship to morphological processes of braiding. Copyright © 2011 John Wiley & Sons, Ltd.     

Quantitative evaluation of different hydrological modelling approaches in a partly glacierized Swiss watershed

Mountain water resources management often requires hydrological models that need to handle both snow and ice melt. In this study, we compared two different model types for a partly glacierized watershed in central Switzerland: (1) an energy‐balance model primarily designed for snow simulations; and (2) a temperature‐index model developed for glacier simulations. The models were forced with data extrapolated from long‐term measurement records to mimic the typical input data situation for climate change assessments. By using different methods to distribute precipitation, we also assessed how various snow cover patterns influenced the modelled runoff. The energy‐balance model provided accurate discharge estimations during periods dominated by snow melt, but dropped in performance during the glacier ablation season. The glacier melt rates were sensitive to the modelled snow cover patterns and to the parameterization of turbulent heat fluxes. In contrast, the temperature‐index model poorly reproduced snow melt runoff, but provided accurate discharge estimations during the periods dominated by glacier ablation, almost independently of the method used to distribute precipitation. Apparently, the calibration of this model compensated for the inaccurate precipitation input with biased parameters. Our results show that accurate estimates of snow cover patterns are needed either to correctly constrain the melt parameters of the temperature‐index model or to ensure appropriate glacier surface albedos required by the energy‐balance model. Thus, particularly when only distant meteorological stations are available, carefully selected input data and efficient extrapolation methods of meteorological variables improve the reliability of runoff simulations in high alpine watersheds. Copyright © 2011 John Wiley & Sons, Ltd.     

Influence of glacier advance on the development of the multipart Riffeltal rock glacier,Central Austrian Alps

The multipart Riffeltal rock glacier, located in a tributary valley of the Kaunertal, Tyrol, Austria is investigated to enlarge the knowledge about spatial and temporal development of rock glaciers in and at the margins of pro‐glacial areas and to get a better understanding of glacier–rock glacier interactions. The subject of interest consists of a complex system of two adjacent rock glacier tongues and various superposed lobes with differing ages, origin and root zones, and therefore diverse development. To determine the reasons for their diverging development, the internal structure and permafrost occurrence on and in the surrounding area of the rock glacier were studied by application of geomorphological mapping, geophysical methods and measurement of the basal temperature of the winter snow cover (BTS). Permafrost modelling was performed on the basis of BTS data and land surface parameters derived from a high resolution airborne laser scanning (ALS) digital elevation model (DEM). Additionally, the ALS data were used to measure vertical and horizontal changes of the rock glacier surface between 2006 and 2012. Glacier–rock glacier interactions during and since the Little Ice Age (LIA) are evident for the development of the studied rock glacier. A geomorphic map gives important information about the connection between glacial advance or retreat and permafrost or ground ice occurrence. The combination of all information helps in the analysis of diverse kinematic action of neighbouring rock glacier tongues. Copyright © 2014 John Wiley & Sons, Ltd.     

The biogeochemistry of sorbed methane in marine sediments

Sorption of volatile hydrocarbon gases (VHCs) to marine sediments is a recognized phenomenon that has been investigated in the context of petroleum exploration. However, little is known about the biogeochemistry of sorbed methane and higher VHCs in environments that are not influenced by thermogenic processes. This study evaluated two different extraction protocols for sorbed VHCs, used high pressure equipment to investigate the sorption of methane to pure clay mineral phases, and conducted a geochemical and mineralogical survey of sediment samples from different oceanographic settings and geochemical regimes that are not significantly influenced by thermogenic gas. Extraction of sediments under alkaline conditions yielded higher concentrations of sorbed methane than the established protocol for acidic extraction. Application of alkaline extraction in the environmental survey revealed the presence of substantial amounts of sorbed methane in 374 out of 411 samples (91%). Particularly high amounts, up to 2.1 mmol kg⁻¹ dry sediment, were recovered from methanogenic sediments. Carbon isotopic compositions of sorbed methane suggested substantial contributions from biogenic sources, both in sulfate-depleted and sulfate-reducing sediments. Carbon isotopic relationships between sorbed and dissolved methane indicate a coupling of the two pools. While our sorption experiments and extraction conditions point to an important role for clay minerals as sorbents, mineralogical analyses of marine sediments suggest that variations in mineral composition are not controlling variations in quantities of sorbed methane. We conclude that the distribution of sorbed methane in sediments is strongly influenced by in situ production.     

Perceptual models of uncertainty for socio-hydrological systems: a flood risk change example

Characterizing, understanding and better estimating uncertainties are key concerns for drawing robust conclusions when analyzing changing socio-hydrological systems. Here we suggest developing a perceptual model of uncertainty that is complementary to the perceptual model of the socio-hydrological system and we provide an example application to flood risk change analysis. Such a perceptual model aims to make all relevant uncertainty sources – and different perceptions thereof – explicit in a structured way. It is a first step to assessing uncertainty in system outcomes that can help to prioritize research efforts and to structure dialogue and communication about uncertainty in interdisciplinary work.