Sources of variability in springwater chemistry in Fool Creek,a high-elevation catchment of the Rocky Mountains,Colorado, USA

Springs are the point of origin for most headwater streams and are important regulators of their chemical composition. We analysed solute concentrations of water emerging from 57 springs within the 3 km² Fool Creek catchment at the Fraser Experimental Forest and considered sources of spatial variation among them and their influence on the chemical composition of downstream water. On average, calcium and acid neutralizing capacity (bicarbonate-ANC) comprised 50 and 90% of the cation and anion charge respectively, in both spring and stream water. Variation in inorganic chemical composition among springs reflected distinct groundwater sources and catchment geology. Springs emerging through glacial deposits in the upper portion of the catchment were the most dilute and similar to snowmelt, whereas lower elevation springs were more concentrated in cations and ANC. Water emerging from a handful of springs in a geologically faulted portion of the catchment were more concentrated than all others and had a predominant effect on downstream ion concentrations. Chemical similarity indicated that these springs were linked along surface and subsurface flowpaths. This survey shows that springwater chemistry is influenced at nested spatial scales including broad geologic conditions, elevational and spatial attributes and isolated local features. Our results highlight the role of overlapping factors on solute export from headwater catchments.     

High-resolution historical records from Pettaquamscutt River basin sediments: 1. Pb and varve chronologies validate record of Cs released by the Chernobyl accident

Cesium-137 derived from the explosion of the Chernobyl reactor in 1986 was preserved in anoxic sediments from a coastal environment in southern Rhode Island. Although the radioactive plume was detected in surface air samples at several locations in the United States, this is the first known record of a Chernobyl ¹³⁷Cs peak in sediments from North America. The inventory of Chernobyl ¹³⁷Cs that was preserved in the Pettaquamscutt River is small compared to European counterparts and should only be detectable for the next 15-20 yr. However, the presence of two ¹³⁷Cs peaks (1963 and 1987) identifies a well-dated segment of the sediment column that could be exploited in understanding the decomposition and preservation of terrestrial and aquatic organic matter. Different methods for calculating the ²¹⁰Pb chronology were also evaluated in this study and checked against independent varve counting. The end result is a detailed chronology of a site well suited for reconstruction of historical records of environmental change.     

A geographical information system to facilitate military housing management

Abstract

The Department of the Army must provide its personnel with acceptable housing at minimum cost within the vicinity of military installations. To achieve these housing objectives, the Army often has to enter into agreements for the long-term leasing of existing housing. A decision-support system, called HANS, has been developed to project the number of leases that must be arranged.

This paper describes a geographical information system (GIS) enhancement that helps Army managers to locate the lease properties and display characteristics of the properties. It also overviews the benefits, challenges, and limitations of the enhanced system.     

Soil moisture and rainfall intensity thresholds for runoff generation in southwestern Wisconsin agricultural watersheds

The goal of this study was to improve understanding of the factors that influence runoff generation during non‐frozen ground periods in small agricultural watersheds in southwestern Wisconsin where the landscapes are controlled by dolostone bedrock in order to provide agricultural producers with a manure management tool. Six small watersheds (ranging from 6 to 17 ha) within two southwestern Wisconsin farm sites (Discovery Farms Program (DFP) and Pioneer Farm (PF)) were instrumented, and surface runoff was continuously monitored from 2004 to 2007. The soils in all watersheds were formed in deep (~1 m) loessial sites. A direct‐plant management strategy and corn‐soybean crop rotation were utilized within watersheds at DFP. A conventional tillage system (chisel plow in the fall followed by soil finisher in the spring) and a corn‐oat‐alfalfa crop rotation were utilized within watersheds at PF. At PF, the amount of precipitation leaving the landscape as surface runoff (1.8%) was two times greater compared to DFP (0.9%), indicating that the direct‐plant management system was better at retaining precipitation than the chisel plow/soil finisher system. Using breakpoint regression analysis, a non‐linear response in runoff generation with antecedent soil moisture (ASM) was observed with a threshold ASM of 0.39 cm³cm^?3 (approximately 80% of total porosity) for all six watersheds. Below this threshold, runoff coefficients were near zero. Above this threshold, runoff coefficients increased with ASM. A non‐linear response in runoff generation with maximum 30 min rainfall intensity (I30) was also observed, and threshold I30 values increased as ASM decreased and as crop cover increased. Copyright © 2012 John Wiley & Sons, Ltd.     

Variations in sediment sources and yields in the Finger Lakes and Catskills regions of New York

The proportional contributions of stream bank and surface sources to fine sediment loads in watersheds in New York State were quantified with uncertainty analysis. Eroding streamside glacial drift, including glaciolacustrine deposits, were examined to help explain variations in the proportional contributions made by bank erosion. Sediment sources were quantified by comparing concentrations of the bomb‐derived radionuclide ¹³⁷Cs in fluvial sediment with sediment from potential source areas such as agricultural soils, forest soils and stream banks. To compare sediment sources in streams containing abundant deposits of fine‐grained glacial drift with watersheds that lacked moderate or extensive streamside deposits, samples were taken from 15 watersheds in the region. The mean contribution of bank erosion to sediment loads in the six streams with glaciolacustrine deposits was 60% (range 46–76%). The proportional contribution of bank erosion was also important in one stream lacking glaciolacustrine deposits (57%) but was less important in the remainder, with contributions ranging from 0 to 46%. Data from this study on the varying contributions of bank erosion and data from past studies of sediment yield in 15 watersheds of New York State suggest that eroding streamside glacial deposits dominate sediment yield in many watersheds. In other watersheds, past impacts to streams, such as channelization, have also resulted in high levels of bank erosion. Copyright © 2007 John Wiley & Sons, Ltd.     

Spinel-bearing,Al-rich chondrules in two chondrite finds from Roosevelt County,New Mexico: Indicators of nebular and parent body processes

Abstract— Two rare, spinel-bearing, Al-rich chondrules have been identified in new chondrite finds from Roosevelt County, New Mexico—RC 071 (L4) and RC 072 (L5). These chondrules have unusual mineralogies, dominated by highly and asymmetrically zoned, Al-Cr-rich spinels. Two alternatives exist to explain the origin of this zoning—fractional crystallization or metamorphism. It appears that fractional crystallization formed the zoning of the trivalent cations (Al, Cr) and caused a localized depletion in chromites around the large Al-Cr-rich spinels. The origin of the zoning of the divalent cations (Fe, Mg, Zn) is less certain. Diffusive exchange and partitioning of Fe and Mg between olivine and spinel during parent body metamorphism can explain the asymmetric zoning of these elements. Unfortunately, appropriate studies of natural and experimental systems to evaluate the formation of zoning of the divalent cations by fractional crystallization have not yet been conducted. The bulk compositions of the chondrules suggest affinities with the Na-Al-Cr-rich chondrules, as would be expected from the abundance of Al-Cr-rich spinels. Melting of rare and unusual precursors produced the compositions of Na-Al-Cr-rich chondrules, possibly including a spinel-rich precursor enriched in Cr₂O₃ and ZnO. The two chondrules we studied have larger modal abundances of Al-Cr-rich spinels than reported in other Na-Al-Cr-rich chondrules of similar composition, and Al-rich chondrules even more enriched in spinel are reported in the literature. These differences indicate that factors other than bulk composition control the mineralogy of the chondrules. The most important of these factors are the temperature to which the molten chondrule was heated and the cooling rate during crystallization. These two chondrules cooled rapidly from near the liquidus, as indicated by the zoning, occurrence and sizes of spinels, radiating chondrule textures and localized chromite depletions. The range of mineralogies in other Al-rich chondrules of similar composition reflect a range of peak temperatures and cooling rates. We see no reason to believe that this range is fundamentally different from the range of thermal histories experienced by “normal” Fe-Mg-rich chondrules.     

Spectra of extremely reduced assemblages: Implications for Mercury

Abstract— We investigate the possibility that Mercury's crust is very reduced with FeO concentrations of less than ?0.1 wt%. We believe that such a surface could have a composition of enstatite, plagioclase, diopside, and sulfide, similar to the mineral assemblages found in aubritic meteorites. To test this hypothesis, we investigated the spectra of aubrites and their constituent minerals as analogs for the surface of Mercury. We found that some sulfides have distinctive absorption features in their spectra shortwards of ?0.6 μm that may be apparent in the spectrum of such an object. Determination of the surface composition of Mercury using orbital x‐ray spectroscopy should easily distinguish between a lunar highlands and enstatite basalt composition since these materials have significant differences in concentrations of Al, Mg, S, and Fe. The strongest argument against Mercury having an enstatite basalt composition is its extreme spectral redness. Significant reddening of the surface of an object (such as Mercury) is believed to require reduction of FeO to nanophase iron, thus requiring a few percent FeO in the material prior to alteration.     

Simulating stochastically excited oscillations: The mode lifetime of ξ Hya

The discovery of solar-like oscillations in the giant star ξ Hya (G7 III) was reported by Frandsen et al. (2002). Their frequency analysis was very limited due to alias problems in the data set (caused by single-site observations). The extent to which the aliasing affected their analysis was unclear due to the unknown damping time of the stellar oscillation modes. In this paper we describe a simulator created to generate time series of stochastically excited oscillations, which takes as input an arbitrary window function and includes both white and non-white noise. We also outline a new method to compare a large number of simulated time series with an observed time series to determine the damping time, amplitude, and limited information on the degree of the stochastically excited modes. For ξ Hya we find the most likely amplitude to be ∼ 2 m s⁻¹, in good agreement with theory (Houdek and Gough, 2002), and the most likely damping time to be ∼ 2 days, which is much shorter than the theoretical value of 15–20 days calculated by Houdek and Gough (2002).