Does martian soil release reactive halogens to the atmosphere?

Detailed statistical examination of Cl, Br, and S distributions, in martian soil profiles at Gusev Crater and Meridiani Planum, indicates decreasing Br abundance and weakening Br–S association towards the surface. All three elements decrease towards the surface in the order Cl < S < Br. Furthermore, Br variability decouples from potential cations such as Mg at the surface relative to the subsurface. These observations support a relative loss of surficial Br compared to S and Cl, all highly mobile elements in aqueous environments. We propose that Br may have converted preferentially to gas phases (e.g., BrO), driven either by UV photolysis or by chemical oxidants. Such volatilization pathways may in turn impart a global signature on Mars by acting as controls on oxidants such as ozone and perchlorates. S/Cl mass ratios vary with depth (∼4–5 in the subsurface; 1.8–3.6 on the surface) as well, with a strong correlation of S and Cl near the surface but more variable at depth, consistent with differential vertical mobility, but not volatilization of Cl. Elevated S/Cl in subsurface soil also suggests that the ratio may be higher in bulk soil – a key repository of martian geologic and climatic records – than previously thought.     

Measuring the sizes, shapes, surface features and rotations of Solar System objects with interferometry

We consider the application of interferometry to measuring the sizes and shapes of small bodies in the Solar System that cannot be spatially resolved by today’s single-dish telescopes. Assuming ellipsoidal shapes, we provide a formalism to derive the shape parameters from visibility measurements along three different baseline orientations. Our results indicate that interferometers can measure the size of an object to better than 15% uncertainty if the limb-darkening is unknown. Assuming a Minnaert scattering model, one can theoretically derive the limb-darkening parameters from simultaneous measurements of visibilities at several different projected baseline lengths to improve the size and shape determination to an accuracy of a few percent. The best size measurement can be reached when one axis of the object’s projected disk is aligned with one baseline orientation, and the measurement of cross-sectional area is independent of baseline orientation. We construct a 3-D shape model for the dwarf planet Haumea and use it to synthesize interferometric data sets. Using the Haumea model, we demonstrate that when photometric light curve, visibility light curve, and visibility phase center displacement are combined, the rotational period and sense of rotation can all be derived, and the rotational pole can be estimated. Because of its elongated shape and the dark red spot, the rotation of Haumea causes its optical photocenter to move in a loop on the sky. Our simulations show that this loop has an extend of about 80 μas without the dark red spot, and about 200 μas with it. Such movements are easily detectable by space-based astrometric interferometer designed e.g. for planet detection. As an example, we consider the possible contributions to the study of small bodies in the Solar System by the Space Interferometry Mission. We show that such a mission could make substantial contributions in characterizing the fundamental physical properties of the brightest Kuiper Belt Objects and Centaurs as well as a large number of main belt asteroids. We compile a list of Kuiper Belt Objects and Centaurs that are potentially scientifically interesting and observable by such missions.     

Monte Carlo simulation of pair creation using petawatt lasers

Irradiating high-Z targets such as gold with ultra-intense lasers creates electron-positron pairs. In particular, the positron density in the plasma created by this procedure is higher than that obtained via other laboratory-based methods, with theoretical maximum densities exceeding 10¹⁸ cm⁻³. All of the significantly contributing processes are well-known and hence we can study this phenomenon using Monte Carlo simulation. We focus on the latter part of this procedure, the passage of high-energy electrons through the target creating pairs. In particular, we discuss the usefulness of CERN’s GEANT4 Monte Carlo code in simulating this process. Once this code is successfully calibrated, we will use it to perform parameter studies, and design future targets to optimize the positron yield.     

Modification of Jupiter’s stratosphere three weeks after the 2009 impact

Infrared spectroscopy sensitive to thermal emission from Jupiter’s stratosphere reveals effects persisting 23 days after the impact of a body in late July 2009. Measurements obtained on 2009 August 11 UT at the impact latitude of 56°S (planetocentric), using the Goddard Heterodyne Instrument for Planetary Wind and Composition mounted on the NASA Infrared Telescope Facility, reveal increased ethane abundance and the effects of aerosol opacity. An interval of reduced thermal continuum emission at 11.744 μm is measured ∼60-80° towards planetary east of the impact site, estimated to be at 305° longitude (System III). Retrieved stratospheric ethane mole fraction in the near vicinity of the impact site is enhanced by up to ∼60% relative to quiescent regions at this latitude. Thermal continuum emission at the impact site, and somewhat west of it, is significantly enhanced in the same spectra that retrieve enhanced ethane mole fraction. Assuming that the enhanced continuum brightness near the impact site results from thermalized aerosol debris blocking contribution from the continuum formed in the upper troposphere and indicating the local temperature, then continuum emission by a haze layer can be approximated by an opaque surface inserted at the 45-60 mbar pressure level in the stratosphere in an unperturbed thermal profile, setting an upper limit on the pressure and therefore a lower limit on the altitude of the top of the impact debris at this time. The reduced continuum brightness east of the impact site can be modeled by an opaque surface near the cold tropopause, which is consistent with a lower altitude of ejecta/impactor-formed opacity. The physical extent of the observed region of reduced continuum implies a minimum average velocity of 21 m/s transporting material prograde (planetary east) from the impact.     

Analysis of MESSENGER Gamma-Ray Spectrometer data from the Mercury flybys

During its three flybys of Mercury, the MESSENGER spacecraft made the first detection of gamma-ray emission from the planet's surface. With a closest approach distance of ∼200 km, the flybys provided an opportunity to measure elemental abundances of Mercury's near-equatorial regions, which will not be visited at low altitude during MESSENGER's orbital mission phase. Despite being limited by low planetary photon flux, sufficient counts were accumulated during the first two flybys to estimate bounds on abundances for some elements having relatively strong gamma-ray spectral peaks, including Si, Fe, Ti, K, and Th. Only for Si is the standard deviation σ sufficiently small to conclude that this element was detected with 99% confidence. Iron and potassium are detected at the 2−σ (95% confidence) level, whereas only upper bounds on Ti and Th can be determined. Relative to a Si abundance assumed to be 18 weight percent (wt%), 2−σ upper bounds have been estimated as 9.7 wt% for Fe, 7.0 wt% for Ti, 0.087 wt% for K, and 2.2 ppm for Th. The relatively low upper bound on K rules out some previously suggested models for surface composition for the regions sampled. Upper bounds on Fe/Si and Ti/Si ratios are generally consistent with Ti and Fe abundances estimated from the analysis of measurements by the MESSENGER Neutron Spectrometer during the flybys but are also permissive of much lower concentrations.     

Eminescu impact structure: Insight into the transition from complex crater to peak-ring basin on Mercury

Peak-ring basins represent an impact-crater morphology that is transitional between complex craters with central peaks and large multi-ring basins. Therefore, they can provide insight into the scale dependence of the impact process. Here the transition with increasing crater diameter from complex craters to peak-ring basins on Mercury is assessed through a detailed analysis of Eminescu, a geologically recent and well-preserved peak-ring basin. Eminescu has a diameter (∼125 km) close to the minimum for such crater forms and is thus representative of the transition. Impact crater size-frequency distributions and faint rays indicate that Eminescu is Kuiperian in age, geologically younger than most other basins on Mercury. Geologic mapping of basin interior units indicates a distinction between smooth plains and peak-ring units. Our mapping and crater retention ages favor plains formation by impact melt rather than post-impact volcanism, but a volcanic origin for the plains cannot be excluded if the time interval between basin formation and volcanic emplacement was less than the uncertainty in relative ages. The high-albedo peak ring of Eminescu is composed of bright crater-floor deposits (BCFDs, a distinct crustal unit seen elsewhere on Mercury) exposed by the impact. We use our observations to assess predictions of peak-ring formation models. We interpret the characteristics of Eminescu as consistent with basin formation models in which a melt cavity forms during the impact formation of craters at the transition to peak ring morphologies. We suggest that the smooth plains were emplaced via impact melt expulsion from the central melt cavity during uplift of a peak ring composed of BCFD-type material. In this scenario the ringed cluster of peaks resulted from the early development of the melt cavity, which modified the central uplift zone.     

Electron transport and precipitation at Mercury during the MESSENGER flybys: Implications for electron-stimulated desorption

To examine electron transport, energization, and precipitation in Mercury's magnetosphere, a hybrid simulation study has been carried out that follows electron trajectories within the global magnetospheric electric and magnetic field configuration of Mercury. We report analysis for two solar-wind parameter conditions corresponding to the first two MESSENGER Mercury flybys on January 14, 2008, and October 6, 2008, which occurred for similar solar wind speed and density but contrasting interplanetary magnetic field (IMF) directions. During the first flyby the IMF had a northward component, while during the second flyby the IMF was southward. Electron trajectories are traced in the fields of global hybrid simulations for the two flybys. Some solar wind electrons follow complex trajectories at or near where dayside reconnection occurs and enter the magnetosphere at these locations. The entry locations depend on the IMF orientation (north or south). As the electrons move through the entry regions they can be energized as they execute non-adiabatic (demagnetized) motion. Some electrons become magnetically trapped and drift around the planet with energies on the order of 1–10 keV. The highest energy of electrons anywhere in the magnetosphere is about 25 keV, consistent with the absence of high-energy (>35 keV) electrons observed during either MESSENGER flyby. Once within the magnetosphere, a fraction of the electrons precipitates at the planetary surface with fluxes on the order of 10⁹ cm⁻² s⁻¹ and with energies of hundreds of eV. This finding has important implications for the viability of electron-stimulated desorption (ESD) as a mechanism for contributing to the formation of the exosphere and heavy ion cloud around Mercury. From laboratory estimates of ESD ion yields, a calculated ion production rate due to ESD at Mercury is found to be on par with ion sputtering yields.     

Biogeochemical Coring and Preservation Method for Unconsolidated Soil Samples

Developing an accurate conceptual site model (CSM) is an important process before a decision can be made regarding effective remedial actions. A critical aspect of an accurate CSM is thoroughly understanding the biogeochemistry occurring at the site in the area of concern. To collect media samples that accurately preserve the in situ biogeochemistry, a new Rotosonic core barrel and core preservation protocol was developed. The new biogeochemical core barrel (BCB) successfully isolated and preserved the in situ biogeochemical conditions of the soil core and minimized the soil core's exposure pathways to air. The BCB's success was achieved by a modified Rotosonic core barrel, a specialized drive shoe, an internal BCB core barrel piston, hydraulic extrusion of the soil core into a stainless core tube with an internal piston, and specialized core tube sealing, handling, and subsampling methods. Detailed subsampling of 65-foot (nominally 20 m) soil core in 2-inch (nominally 51 mm) increments within a specialized anaerobic glovebox confirmed the presence of five biogeochemical redox transition zones within the soil core. The BCB also allowed for split soil core samples for detailed mineralogical and live microbiological studies. Success of the BCB method is further evidenced by the presence of the highly redox-sensitive surface bound iron sulfide mineral mackinawite. The BCB allowed detailed analysis of the soil core including Fe and S concentration gradients, oxidation–reduction potential gradients, volatile organic compound analysis, and live microbiological assessments.     

An analysis of open-basin lake deposits on Mars: Evidence for the nature of associated lacustrine deposits and post-lacustrine modification processes

A large number of candidate open-basin lakes (low-lying regions with both inlet valleys and an outlet valley) have been identified and mapped on Mars and are fed by valley network systems that were active near the Noachian–Hesperian boundary. The nature of processes that modified the open-basin lake interiors subsequent to lacustrine activity, and how frequently sedimentary deposits related to lacustrine activity remain exposed, has not been extensively examined. An analysis of 226 open-basin lakes was undertaken to identify evidence for: (1) exposed deposits of possible lacustrine origin and (2) post-lacustrine-activity processes that may have modified or resurfaced open-basin lakes. Spectroscopic data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) instrument were analyzed over identified exposed open-basin lake deposits to assess the mineralogy of these deposits. Particular attention was paid to the possible detection of any component of aqueous alteration minerals (e.g. phyllosilicates, hydrated silica, zeolites) or evaporites (e.g. carbonates, sulfates, chlorides) associated with these exposed deposits. The aim of this paper is to act as a broad survey and cataloguing of the types of lacustrine and post-lacustrine deposits that are present within these 226 paleolake basins. Results of the morphologic classification indicate that 79 open-basin lakes (～35% of the population) contain exposed deposits of possible lacustrine origin, identified on the basis of fan/delta deposits, layered deposits and/or exposed floor material of apparent lacustrine origin. Additionally, all 226 open-basin lakes examined appear to have been at least partially resurfaced subsequent to their formation by several processes, including volcanism, glacial and periglacial activity, impact cratering and aeolian activity. Results from the analysis of CRISM data show that only 10 (～29% of the 34 deposits with CRISM coverage) of the exposed open-basin lake deposits contain positively identified aqueous alteration minerals, with one deposit also containing evaporites. The identified hydrated and evaporite minerals include Fe/Mg-smectite, kaolinite, hydrated silica and carbonate, with Fe/Mg-smectite the most commonly identified mineral. These results indicate that hydrated and evaporite minerals are not as commonly associated with lacustrine deposits on Mars as they are on Earth. This suggests in situ alteration and mineral precipitation, a common source of such minerals in terrestrial lakes, was not a major process occurring in these paleo-lacustrine systems, and that the observed minerals are likely to be present as transported material within the lacustrine deposits. The lack of widespread in situ alteration also suggests that either the water chemistry in these paleolake systems was not conducive to aqueous alteration and mineral precipitation, or that the open-basin lake systems were relatively short-lived.