Partial melting of H6 ordinary chondrite Kernouvé: Constraints on the effects of reducing conditions on oxidized compositions

Abstract— Partial melting experiments at temperatures of 950–1300 °C were conducted on the H6 chondrite Kernouvé under reducing conditions using CO‐CO₂ gas mixing and graphite‐buffered sealed silica tubes to examine the effect of reducing conditions during melting of starting materials that are more oxidized relative to the oxygen fugacity conditions of the experiments. The experiments produced a range of mineralogical and compositional changes. Olivine exhibits significant reduction to compositions of Fa_2–5 at temperatures of 1300 °C. In contrast, orthopyroxene exhibits only slight reduction until the highest temperatures. Chromite is sometimes consumed by intruding sulfides, and displays increasingly magnesian compositions ranging as low as Fe/Fe + Mg of 0.1 at a constant Cr/Cr + Al ratio. The compositional changes with increasing temperature reflect a complex set of reactions, including oxidation‐reduction. One application of these experiments address whether primitive achondrites could have formed from ordinary chondrite‐like precursors by partial melting under reducing conditions. While changes observed in olivine and troilite compositions might support such an idea, differences in oxygen isotopic composition, Cr/Cr + Al in chromite, orthopyroxene compositions, and thermodynamic evidence against reduction during melting of primitive achondrites (Benedix et al. 2005) firmly refute such an idea.     

The problems with acoustics on a small planet

In recent years increased attention has been paid to the potential uses of acoustics for extraterrestrial exploration. This paper concerns two aspects which should be taken into account when transposing terrestrial experience with acoustics to smaller worlds. These are, specifically, the effect on the acoustics of the variation of gravity with depth, and the curvature of the world's surface. A case resembling Europa is used quantitatively to illustrate these effects, indicating significant errors if these factors are neglected.     

Observations of the north polar water ice annulus on Mars using THEMIS and TES

The Martian seasonal CO₂ ice caps advance and retreat each year. In the spring, as the CO₂ cap gradually retreats, it leaves behind an extensive defrosting zone from the solid CO₂ cap to the location where all CO₂ frost has sublimated. We have been studying this phenomenon in the north polar region using data from the THermal EMission Imaging System (THEMIS), a visible and infra-red (IR) camera on the Mars Odyssey spacecraft, and the Thermal Emission Spectrometer (TES) on Mars Global Surveyor. Recently, we discovered that some THEMIS images of the CO₂ defrosting zone contain evidence for a distinct defrosting phenomenon: some areas just south of the CO₂ cap edge are too bright in visible wavelengths to be defrosted terrain, but too warm in the IR to be CO₂ ice. We hypothesize that we are seeing evidence for a seasonal annulus of water ice (frost) that recedes with the seasonal CO₂ cap, as predicted by previous workers. In this paper, we describe our observations with THEMIS and compare them to simultaneous observations by TES and OMEGA. All three instruments find that this phenomenon is distinct from the CO₂ cap and most likely composed of water ice. We also find strong evidence that the annulus widens as it recedes. Finally, we show that this annulus can be detected in the raw THEMIS data as it is collected, enabling future long-term onboard monitoring.     

Interaction-induced star formation in a complete sample of 105 nearby star-forming galaxies

We investigate the clustering properties of a complete sample of 10⁵ star-forming galaxies drawn from the data release 4 (DR4) of the Sloan Digital Sky Survey. On scales less than 100 kpc, the amplitude of the correlation function exhibits a strong dependence on the specific star formation rate (SSFR) of the galaxy. We interpret this as the signature of enhanced star formation induced by tidal interactions. We then explore how the average star formation rate (SFR) in a galaxy is enhanced as the projected separation r _p between the galaxy and its companions decreases. We find that the enhancement strongly depends on r _p, but very weakly on the relative luminosity of the companions. The enhancement is also stronger in low-mass galaxies than in high-mass galaxies. In order to explore whether a tidal interaction is not only sufficient, but also necessary to trigger enhanced star formation in a galaxy, we compute background subtracted neighbour counts for the galaxies in our sample. The average number of close neighbours around galaxies with low to average values of SFR/ M _* is close to zero. At the highest SSFRs, however, more than 40 per cent of the galaxies in our sample have a companion within a projected radius of 100 kpc. Visual inspection of the highest SFR/ M _* galaxies without companions reveals that more than 50 per cent of these are clear interacting or merging systems. We conclude that tidal interactions are the dominant trigger of enhanced star formation in the most strongly star-forming systems. Finally, we find clear evidence that tidal interactions not only lead to enhanced star formation in galaxies, but also cause structural changes such as an increase in concentration.     

Evaluating hydrologic effects of spatial and temporal patterns of forest canopy change using numerical modelling

Although hydrologic responses to land cover changes are often studied using a paired watershed approach, it is not feasible to assess the hydrological effects of many different patterns of land cover alteration by empirical studies alone. An alternative is to use well validated, spatially explicit, physically based numerical models to estimate watershed storage and flux dynamics. The objectives of this study were to assess the sensitivity of watershed flow regimes to several spatial and temporal patterns of forest harvest and recovery in a snow‐dominated mountain watershed. The Distributed Hydrology Soil‐Vegetation Model (DHSVM) was parameterized using 1998–2007 climate data for the 28‐km² Mica Creek Experimental Watershed (MCEW), a headwater catchment in the inland Pacific Northwest. The modelling experiment indicated that clear‐cutting the entire watershed would increase runoff volume by 79% and 5^th percentile flows by 68%. Hydrologic recovery resulting from forest regeneration after clear‐cut harvesting is expected to take up to 25 years to return to baseline conditions, and 50 years to fully recover to preharvest conditions. A more realistic harvesting scenario where the watershed was gradually harvested in a series of clear‐cut blocks allowing for subsequent regeneration to occur was also assessed. This approach reduced the magnitude of hydrologic alteration. Analysis of several other scenarios, defined by aspect, elevation, and distance to the stream network, revealed that flow regime was more sensitive to the amount of alteration rather than pattern and landscape position of disturbance. Copyright © 2015 John Wiley & Sons, Ltd.     

How much physical complexity is needed to model flood inundation?

Two‐dimensional flood inundation models are widely used tools for flood hazard mapping and an essential component of statutory flood risk management guidelines in many countries. Yet, we still do not know how much physical complexity a flood inundation model needs for a given problem. Here, three two‐dimensional explicit hydraulic models, which can be broadly defined as simulating diffusive, inertial or shallow water waves, have been benchmarked using test cases from a recent Environment Agency for England and Wales study, where results from industry models are also available. To ensure consistency, the three models were written in the same code and share subroutines for all but the momentum (flow) and time‐stepping calculations. The diffusive type model required much longer simulation times than the other models, whilst the inertia model was the quickest. For flows that vary gradually in time, differences in simulated velocities and depths due to physical complexity were within 10% of the simulations from a range of industry models. Therefore, for flows that vary gradually in time, it appears unnecessary to solve the full two‐dimensional shallow water equations. As expected, however, the simpler models were unable to simulate supercritical flows accurately. Finally, implications of the results for future model benchmarking studies are discussed in light of a number of subtle factors that were found to cause significant differences in simulations relative to the choice of model. Copyright © 2011 John Wiley & Sons, Ltd.     

Millennial-scale variations in hydrography and biogeochemistry in the Eastern Equatorial Pacific over the last 100 kyr

In this study, we use records of nitrogen isotope ratios (δ¹⁵N), UK’37 temperature estimates, organic carbon and opal percentages from high-resolution sediment cores located in the eastern equatorial Pacific (EEP) to explore the mechanisms linking millennial-scale changes in low-latitude sea surface temperature, water column denitrification and surface productivity to the timing of northern or southern polar climate during the last 100,000 yr. Our results support a hypothesis that the Southern Hemisphere, and its connection to the low latitudes via shallow subsurface ocean circulation, has a primary influence on the biogeochemistry of the EEP. In addition, our results suggest that, during the last glacial stage, denitrification rates fluctuated on millennial timescales in response to water-column ventilation rather than upstream oxidant demand in intermediate-depth waters.However, due to the poor age constraints available for Marine Isotopic Stage (MIS) 3, the EEP sedimentary data presented here could support two conflicting mechanisms, one driven by enhanced intermediate overturning circulation in the Southern Ocean during Heinrich Events/Antarctic Warm Events, implying that subsurface flow rates control thermocline ventilation, and a second one consistent with more sluggish intermediate circulation during Antarctic Warm Events and giving a central role to the temperature control on oxygen solubility in Southern Ocean surface waters.     

Relative contributions of stream concentration,stream discharge and shoreline load to base cation trends in Red Chalk and Harp lakes,south‐central Ontario,Canada

We evaluated the importance and contributions of changes in stream base cation concentration, stream discharge and lake shoreline load to changes in base cation concentrations in two small inland lakes in south‐central Ontario. The shoreline load from ungauged drainage areas was calculated with a mass balance equation. An evaluation method based on the partial Mann–Kendall test quantified the relative contributions of these three explanatory drivers to the observed trends in lake concentration of Ca, K, Mg and Na. Over a 29‐year period (1978–2006) at Red Chalk and Harp lakes, declines in stream concentration and discharge were correlated with the declines in lake concentrations of all base cations (except for Na in Harp Lake), with contributions of 21–81% from stream concentration and 12–58% from discharge, whereas the shoreline load had little contribution to observed trends. The observed unusual increase in Na concentration at Harp Lake was correlated with the increase in stream Na concentration and additional load from road salts, with the shoreline load contributing a substantial 37%. These results may be applicable to numerous inland lakes with similar site conditions, including lakes found on the Canadian Shield. Copyright © 2015 John Wiley & Sons, Ltd.     

Amount and reactivity of dissolved organic matter export are affected by land cover change from old-growth to second-growth forests in headwater ecosystems

Headwater forest ecosystems of the western USA generate a large portion of the dissolved organic matter (DOM) transported in streams across North America. Land cover changes that alter forest structure and species composition affect the quantity and composition of DOM transferred to aquatic ecosystems. Clear-cut harvesting affects ~1% of the forest area of North America annually, leaving most western forests in varying stages of regrowth and the total area of old-growth forest is decreasing. The consequences of this widespread management practice on watershed carbon cycling remain unknown. We investigated the role of land cover change, because of clear-cut harvesting, from mixed-species old-growth to lodgepole pine-dominated second-growth forest on the character and reactivity of hillslope DOM exports. We evaluated inputs of DOM from litter leachates and export of DOM collected at the base of trenched hillslopes during a 3-year period (2016–2018) at the Fraser Experimental Forest in north-central Colorado, USA. Dissolved organic carbon and total dissolved nitrogen were higher in lateral subsurface flow draining old- versus second-growth forest. Fluorescence spectroscopy showed that the DOM exported from the old-growth forest was more heterogeneous and aromatic and that proteinaceous, microbially processed DOM components were more prevalent in the second-growth forest. Biological oxygen demand assays revealed much lower microbial metabolism of DOM in litter leachate and subsurface exports from the old-growth forest relative to second growth. Old-growth and second-growth forests are co-mingled in managed ecosystems, and our findings demonstrate that land cover change from a mixture of conifer species to lodgepole pine dominance influences DOM inputs that can increase the reactivity of DOM transferred from terrestrial to aquatic ecosystems.     

A 100 ka record of fluvial activity in the Fitzroy River Basin,tropical northeastern Australia

This study reports the nature and timing of Quaternary fluvial activity in the Fitzroy River basin, which drains a diverse 143,000 km² area in northeastern Queensland, before discharging into the Great Barrier Reef Marine Park. The catchment consists of an extensive array of channel and floodplain types that we show have undergone large-scale fluvial adjustment in-channel planform, geometry and sinuosity. Optically stimulated luminescence (OSL) dating of quartz sediments from fifteen (3–18 m) floodplain cores throughout the basin indicates several discrete phases of active bedload activity: at ～105–85 ka in Marine Isotope Stage (MIS) 5, at ～50–40 ka (MIS 3), and at ～30–10 ka (MIS 3/2). The overall timing of late Quaternary fluvial activity correlates well with previous accounts from across Australia with rivers being primarily active during interstadials. Fluvial activity, however, does not appear to have been synchronous throughout the basin’s major sub-catchments. Fluvial activity throughout MIS 2 (i.e. across the Last Glacial Maximum) in the meandering channels of the Fitzroy correlates well with regional data in tropical northeastern Queensland, and casts new light on the river response to reduced rainfall and vegetation cover suggested by regional palaeoclimate indicators. Moreover, the absence of a strong Holocene signal is at odds with previous accounts from elsewhere throughout Australia. The latitudinal position of the Fitzroy across the Tropic of Capricorn places this catchment at a key location for elucidating the main hydrological drivers of Quaternary fluvial activity in northeastern Australia, and especially for determining tropical moisture sources feeding into the headwaters of Cooper Creek, a major river system of the continental interior.